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US4101497A Expired / Lapsed US ⏱️ 0.0 years remaining

Sealant-primer coating

Assignee: United States Department of the Navy
•
Filing: 1976-12-03
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Granted: 1978-07-18
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Expires: 1996-12-03
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Abstract

Abstract A coating which is both a flexible sealant and a corrosion-inhibitive primer which can be used to protect the exterior skin and fastener patterns of high performance aircraft at low temperatures. The coating includes corrosion inhibitive pigmentation, resins, a curing agent, and a solvent blend permitting spray application of the coating. The two resins included in the coating are a reaction product of an epichlorohydrin and bisphenol A plus a polyurethane elastomer which is a reaction product of an aromatic isocyanate and a polyether glycol. The curing agent is a blocked diamine, i.e., a ketimine. The ketimine can be prepared by reacting a carbonyl compound and an aromatic diamine. Water is produced in this reaction. The reaction is reversible, so that as the ketimine absorbs atmospheric moisture, the aromatic diamine is released and in turn cures or cross-links the resins. The mixture of pigmentation, resins, ketimine, and solvent blend is a sprayable material that can be readily applied to surfaces using conventional spray equipment. After application, as the diamine is released, the coating is cured to a tough weather-resistant film. When utilized to protect exterior surfaces, a durable exterior coating can then be applied over the flexible sealant-primer to obtain a two-coat, all weather protective paint system.

Inventors

  • 👤 Everett Charves
  • 👤 David F. Pulley
  • 👤 Arthur O. Stander

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 19:28
CPC Classifications
C; C09; C09D; C09D163/00; C09D175/00; C09D175/04; C09D175/08

Claims Analysis

Total Claims: 2
Claim 1
Independent Claim 194 words
A method for preparing a protective coating composition, comprising: forming a first component by mixing, in parts by weight, ______________________________________ epoxy resin having an epoxide equivalent between 185 and 196, viscosity between 110 and 160 poises, and density between 9.6 and 9.8 lbs./gal. at 68° F 291 strontium chromate 1701 titanium dioxide 319 magnesium silicate 788 diatomaceous silica 414 leveling agent 135 methyl n-butyl ketone, urethane grade 3386 ______________________________________ forming a second component by mixing, in parts by weight, ______________________________________ ketimine curing agent 1680 methyl ethyl ketone, urethane grade 2754 ______________________________________ forming a third component by mixing, in parts by weight, ______________________________________ aromatic polyurethane resin having a 100% modulus of 400 psi at 100° C and an available isocyanate content of 2.8% 1740 polyurethane resin having a 100% modulus of 1100 psi at 100° C and an available isocyanate content of 4.1% 873 xylene, urethane grade 1214 butyl acetate, urethane grade 699 toluene, urethane grade 634 ______________________________________ wherein said polyurethane resins are selected from the group consisting of a compound having the formula ##STR8## and a compound having the formula ##STR9## and combining said first, second and third components in equal parts by volume.
Claim 2
Independent Claim 194 words
A method for preparing a protective coating composition, comprising: forming a first component by mixing, in parts by weight, ______________________________________ epoxy resin having an epoxide equivalent between 185 and 196, viscosity between 110 and 160 poises, and density between 9.6 and 9.8 lbs./gal. at 68° F 291 strontium chromate 1701 titanium dioxide 319 magnesium silicate 788 diatomaceous silica 414 leveling agent 135 methyl n-butyl ketone, urethane grade 3386 ______________________________________ forming a second component by mixing, in parts by weight, ______________________________________ ketimine curing agent 1680 methyl ethyl ketone, urethane grade 2754 ______________________________________ forming a third component by mixing, in parts by weight, ______________________________________ aromatic polyurethane resin having a 100% modulus of 400 psi at 100° C and an available isocyanate content of 2.8% 1740 polyurethane resin having a 100% modulus of 1100 psi at 100° C and an available isocyanate content of 4.1% 873 xylene, urethane grade 1214 butyl acetate, urethane grade 699 toluene, urethane grade 634 ______________________________________ wherein said polyurethane resins are selected from the group consisting of a compound having the formula ##STR8## and a compound having the formula ##STR9## and combining said first, second and third components in equal parts by volume.

References Cited (Backward Citations)

US3267078A Cited
US3445436A Cited
US3525779A Cited
US3574127A Cited
US3565972A Cited
US3652485A Cited
US3748292A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-07-17 1982-01-16 1982-07-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-07-17 1986-01-16 1986-07-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-07-17 1990-01-16 1990-07-18 $7700.00 Window Closed / Lapsed

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