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US4719169A Expired / Lapsed US ⏱️ 0.0 years remaining

Protective coating for images

Assignee: CNA Holdings LLC
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Filing: 1986-04-18
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Granted: 1988-01-12
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Expires: 2006-04-18
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Abstract

Abstract The invention provides a method for protecting an image which comprises providing a colored image on a substrate and either: A. Applying an antiblocking layer to a release surface of a temporary support; bonding a thermoplastic adhesive layer to said antiblocking layer; laminating said applied support to said colored image via said adhesive; and peeling away said temporary support from said antiblocking layer; or B. applying a thermoplastic adhesive layer to a release surface of a first temporary support; applying an antiblocking layer onto a release surface of a second temporary support, laminating said adhesive onto said colored image and peeling away said first temporary support; and laminating said antiblocking layer onto said adhesive layer and peeling away said second temporary support; wherein said adhesive layer is substantially nontacky at room temperature, is laminated at temperatures between about 60° C. and 90° C., and comprises one or more thermoplastic polymers or copolymers; and wherein said antiblocking layer comprises one or more organic polymers or copolymers, which layer does not cohesively block at about 50° C. or less.

Inventors

  • 👤 Stephan J. W. Platzer
  • 👤 Mehmet U. Yener
  • 👤 Stanley F. Wanat

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 10:14
CPC Classifications
G; G03; G03F; G03F3/00; G03F3/10; Y; Y10; Y10S; Y10S430/00; Y10S430/151; Y10S430/162; Y10T; Y10T428/00; Y10T428/14; Y10T428/1452; Y10T428/24; Y10T428/24802; Y10T428/24843; Y10T428/24851; Y10T428/2486

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 242 words
A method for protecting an image with a thin, substantially non-blocking protective layer which comprises providing a colored image on a substrate and either: A. Applying an antiblocking coating to a release surface of a temporary support; bonding a thermoplastic adhesive layer to said antiblocking coating; laminating said applied support to said colored image via said adhesive; and peeling away said temporary support from said antiblocking coating; or B. applying a thermoplastic adhesive layer to a release surface of a first temporary support; applying an antiblocking coating onto a release surface of a second temporary support, laminating said adhesive onto said colored image and peeling away said first temporary support; and laminating said antiblocking coating onto said adhesive layuer and peeling away said second temporary support; wherein said adhesive layer is transparent, colorless and substantially nontacky at room temperature, is laminated with pressure such that the adhesive is directly on the surface of the image and the anti-blocking coating is on the other surface of the adhesive, at temperatures between about 60° C. and 90° C.; and comprises in a major portion one or more thermoplastic polymers or copolymers capable of forming a flexible film; and wherein said antiblocking coating is transparent, colorless and comprises one or more organic polymers or copolymers, which coating does not cohesively block at about 50° C. or less; and wherein said lamination is conducted at a temperature of from about 60° C. to about 90° C.
Claim 2
Independent Claim 242 words
A method for protecting an image with a thin, substantially non-blocking protective layer which comprises providing a colored image on a substrate and either: A. Applying an antiblocking coating to a release surface of a temporary support; bonding a thermoplastic adhesive layer to said antiblocking coating; laminating said applied support to said colored image via said adhesive; and peeling away said temporary support from said antiblocking coating; or B. applying a thermoplastic adhesive layer to a release surface of a first temporary support; applying an antiblocking coating onto a release surface of a second temporary support, laminating said adhesive onto said colored image and peeling away said first temporary support; and laminating said antiblocking coating onto said adhesive layuer and peeling away said second temporary support; wherein said adhesive layer is transparent, colorless and substantially nontacky at room temperature, is laminated with pressure such that the adhesive is directly on the surface of the image and the anti-blocking coating is on the other surface of the adhesive, at temperatures between about 60° C. and 90° C.; and comprises in a major portion one or more thermoplastic polymers or copolymers capable of forming a flexible film; and wherein said antiblocking coating is transparent, colorless and comprises one or more organic polymers or copolymers, which coating does not cohesively block at about 50° C. or less; and wherein said lamination is conducted at a temperature of from about 60° C. to about 90° C.
Claim 3
Dependent Claim 17 words
The method of claim 1 wherein the temporary support or supports of claim 1 comprise polyethylene terephthalate.
Claim 4
Dependent Claim 20 words
The method of claim 1 wherein the surface of the temporary support adjacent said antiblocking coating has a matte texture.
Claim 5
Dependent Claim 20 words
The method of claim 1 wherein the surface of the temporary support adjacent said antiblocking coating has a glossy texture.
Claim 6
Dependent Claim 20 words
The method of claim 1 wherein said adhesive coating has a thickness of from about 0.5 to about 30 μm.
Claim 7
Dependent Claim 20 words
The method of claim 1 wherein said antiblocking coating has a thickness of from about 0.2 to about 50 μm.
Claim 8
Dependent Claim 21 words
The method of claim 1 wherein said polymer(s) in the antiblocking coating has a Tg of about 60° C. or more.
Claim 9
Dependent Claim 21 words
The method of claim 1 wherein said polymer(s) in the antiblocking coating has a Tg of about 70° C. or more.
Claim 10
Dependent Claim 21 words
The method of claim 1 wherein said polymer in the antiblocking coating has a Tg of about 100° C. or more.
Claim 11
Dependent Claim 25 words
The method of claim 1 wherein said thermoplastic polymer(s) in the adhesive coating has a Tg of from about 20° C. to about 60° C.
Claim 12
Dependent Claim 25 words
The method of claim 1 wherein said thermoplastic polymer(s) in the adhesive coating has a Tg of from about 25° C. to about 55° C.
Claim 13
Dependent Claim 36 words
The method of claim 1 wherein said adhesive coating comprises one or more materials selected from the group consisting of polyvinyl acetals, polyvinyl acetates, polyvinyl acrylates, cellulose nitrate, polyvinyl chloride/polyvinyl acetate copolymers, novolaks and epoxy resins.
Claim 14
Dependent Claim 32 words
The method of claim 1 wherein said antiblocking coating comprises one or more compounds selected from the group consisting of styrene-maleic anhydride copolymers, polyvinyl acetals, polyvinyl acrylates, and polyvinyl acetate/polyvinyl chloride copolymers.
Claim 15
Dependent Claim 22 words
The method of claim 1 wherein said lamination is conducted at a temperature of from about 75° C. to about 85° C.
Claim 16
Dependent Claim 19 words
The method of claim 1 wherein said antiblocking coating does not cohesively block at about 70° C. or less.
Claim 17
Dependent Claim 20 words
The method of claim 1 wherein said adhesive coating has a thickness of from about 1 to about 20 μm.
Claim 18
Dependent Claim 20 words
The method of claim 1 wherein said adhesive coating has a thickness of from about 5 to about 15 μm.
Claim 19
Dependent Claim 20 words
The method of claim 1 wherein said antiblocking coating has a thickness of from about 1 to about 10 μm.
Claim 20
Dependent Claim 20 words
The method of claim 1 wherein said antiblocking coating has a thickness of from about 2 to about 3 μm.

References Cited (Backward Citations)

US3721557A Cited
US4077830A Cited
US4294641A Cited
US4376159A Cited
US4366223A Cited
US4303718A Cited
US4522881A Cited
US4489154A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-01-11 1991-07-13 1992-01-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-01-11 1995-07-13 1996-01-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-01-11 1999-07-13 2000-01-12 $7700.00 Window Closed / Lapsed

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