Patent US4716239A successfully refreshed from Google Patents.
US4716239A
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Nickel composition soluble in hydrocarbons
Assignee: IFP Energies nouvelles
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Filing: 1984-11-28
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Granted: 1987-12-29
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Expires: 2004-11-28
Abstract
Abstract New nickel composition having substantial solubility in hydrocarbons and prepared by reacting at least one inorganic divalent compound, at least one halogenoacetic acid and at least one ester of the formula R 1 COO R 2 wherein R 1 is hydrogen or hydrocarbyl and R 2 is hydrocarbyl. The resultant composition can be used in admixture with a hydrocarbylaluminum halide as catalyst for olefin dimerization.
Inventors
- 👤 Gerard Provin
- 👤 Alain Forestiere
- 👤 Dominique Commereuc
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 22:02
CPC Classifications
C; C07; C07C; C07C53/00; C07C53/15; C07C53/16
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
51 words
A nickel liquid reaction product composition, soluble in hydrocarbons, obtained by the process comprising reacting: a divalent nickel inorganic compound; a halogenoacetic acid; and an ester of the general formula R 1 COOR 2 , wherein R 1 is hydrogen or C 1-4 -alkyl and R 2 is a hydrocarbyl radical.
Claim 2
Dependent Claim
51 words
A nickel liquid reaction product composition, soluble in hydrocarbons, obtained by the process comprising reacting: a divalent nickel inorganic compound; a halogenoacetic acid; and an ester of the general formula R 1 COOR 2 , wherein R 1 is hydrogen or C 1-4 -alkyl and R 2 is a hydrocarbyl radical.
Claim 3
Dependent Claim
42 words
A composition according to claim 1, whose manufacture comprises the use of halogenoacetic acid in a proportion of 0.1-2 moles per nickel atom of the inorganic compound and ester in a proportion of 0.1-10 liters per nickel atom of the inorganic compound.
Claim 4
Dependent Claim
35 words
A composition according to claim 1, whose manufacture comprises the use of halogenoacetic acid in a proportion of 0.5-1.5 mole and ester is a proportion of 0.2-2 liters per nickel atom of the inorganic compound.
Claim 5
Dependent Claim
22 words
A composition according to claim 1, whose manufacture comprises, as the nickel inorganic compound, a carbonate, bicarbonate, basic carbonate, oxide or hydroxide.
Claim 6
Dependent Claim
18 words
A composition according to claim 1, whose manufacture comprises, as the nickel inorganic compound, a nickel basic carbonate.
Claim 7
Dependent Claim
14 words
A composition according to claim 1, whose manufacture comprises, as halogenoacetic acid, trifluoroacetic acid.
Claim 8
Dependent Claim
32 words
A composition according to claim 1, whose manufacture further comprises the reaction of a non-halogenated carboxylic acid having at least 3 carbon atoms, in a proportion of 0.1-0.9 mole per nickel atom.
Claim 9
Dependent Claim
13 words
A composition according to claim 1, wherein R 2 is C 1-5 -alkyl.
Claim 10
Dependent Claim
15 words
A composition according to claim 1, wherein R 1 is hydrogen or C 1-3 -alkyl.
Claim 11
Dependent Claim
25 words
A composition according to claim 8, wherein the ester is methyl acetate, methyl formate, n-butyl acetate, isobutyl acetate, methyl propionate, isopropyl formate or ethyl butyrate.
Claim 12
Dependent Claim
24 words
A composition according to claim 1, wherein the halogenoacetic acid is monochloroacetic acid, monofluoroacetic acid, dichloroacetic acid, trichloroacetic acid, difluoroacetic acid or trifluoroacetic acid.
Claim 13
Dependent Claim
54 words
A process for the production of nickel liquid reaction product compositions, soluble in hydrocarbons, comprising reacting together: a divalent nickel inorganic compound; a halogenoacetic acid; and an ester of the formula R 1 COOR 2 , wherein R 1 is hydrogen or a C 1-4 -hydrocarbyl radical and R 2 is a hydrocarbyl radical.
Claim 14
Dependent Claim
54 words
A process for the production of nickel liquid reaction product compositions, soluble in hydrocarbons, comprising reacting together: a divalent nickel inorganic compound; a halogenoacetic acid; and an ester of the formula R 1 COOR 2 , wherein R 1 is hydrogen or a C 1-4 -hydrocarbyl radical and R 2 is a hydrocarbyl radical.
Claim 15
Dependent Claim
41 words
A process according to claim 12, comprising reacting the halogenoacetic acid in a proportion of 0.1-2 moles per nickel atom of the inorganic compound and reacting the ester in a proportion of 0.1-10 liters per nickel atom of the inorganic compound.
Claim 16
Dependent Claim
24 words
A process according to claim 13, wherein the halogenoacetic acid comprises monochloroacetic acid, monofluoroacetic acid, dichloroacetic acid, trichloroacetic acid, difluoroacetic acid or trifluoroacetic acid.
Claim 17
Dependent Claim
28 words
A process according to claim 12, further comprising reacting a non-halogenated carboxylic acid having at least three carbon atoms, in a proportion of 0.1-0.9 mole per nickel atom.
Claim 18
Dependent Claim
20 words
A process according to claim 12, wherein the ester is methylacetate, methylformate, n-butyl acetate, isobutyl acetate, methylpropionate, isopropylformate or ethylbutyrate.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-12-28 | 1991-06-29 | 1991-12-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-12-28 | 1995-06-29 | 1995-12-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-12-28 | 1999-06-29 | 1999-12-29 | $7700.00 | Window Closed / Lapsed |