Patent US4713795A successfully refreshed from Google Patents.
US4713795A
Expired / Lapsed
US
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Optical switch, especially for information storage and retrieval
Assignee: Forschungszentrum Jülich
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Filing: 1985-10-29
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Granted: 1987-12-15
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Expires: 2005-10-29
Abstract
Abstract Nitroprusside single crystals having the formula M n [Fe(CN) 5 ]nH 2 O, where M is a metal that forms a nitroprusside is found to have the property, when cooled to a temperature in the range between 160° K. and 250° K., of convertability into a long-duration metastable state by irradiation with coherent blue-green light and to return to the original state when irradiated with red light. Barium nitroprusside Ba[Fe(CN) 5 ]2H 2 O can be switched rapidly from one state to the other without requiring cooling below about 200° K. and lends itself particularly well to making single crystal memories for writing with a blue-green laser beam and reading with a red laser beam, with the readout being picked up by a photodetector diode array, on which the radiation from the nitroprusside crystal is focused. The incident laser beams are pulsed and the photodetector is turned off during pulsing. Movable laser mirrors are used to direct the laser beams to locations on the surface of the crystal in a manner controlled by an address program.
Inventors
- 👤 Theo Woike
- 👤 Wolfgang Krasser
- 👤 Siegfried Haussuhl
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 18:31
CPC Classifications
G; G11; G11B; G11B7/00; G11B7/24; G11B7/241; G11B7/242; G11B7/243; G03; G03C; G03C1/00; G03C1/64; G11C; G11C7/00; G11C7/005; G11B2007/24302; G11B2007/24306; G11B2007/24318; G11B2007/2432; G11B2007/24322; G11B2007/24328
Claims Analysis
Total Claims: 25
Claim 1
Independent Claim
210 words
Optical switch capable of use for information storage, utilizing a medium capable of being converted from an original state to a metastable state by a radiative pumping by intensive light having a first wavelength (λ 1 ) and capable of being returned to said original state by intensive light having a second wavelength (λ 2 ), comprising a source of light of said first and second wavelengths, said storage medium, means for directing radiation of said first and second wavelengths for localized incidence on said medium and photodetector means for measuring radiation coming from said medium, said medium being a nitroprusside single crystal of the formula M m [Fe(CN) 5 NO]nH 2 O, wherein M is a metal capable of forming a nitroprusside salt, m is a valence-determined number determined by the valence of the metal M and the -2 valence of the nitroprusside group [Fe(CN) 5 NO] and n is an integer in range 0, 1, 2, 3 . . . 10, said first light wavelength being in the range between 400 and 530 mn, said second light wavelength being in the range from 600 to 680 nm, and means being provided for cooling said single crystal at a temperature in the range between 140° K. and 210° K.
Claim 2
Dependent Claim
210 words
Optical switch capable of use for information storage, utilizing a medium capable of being converted from an original state to a metastable state by a radiative pumping by intensive light having a first wavelength (λ 1 ) and capable of being returned to said original state by intensive light having a second wavelength (λ 2 ), comprising a source of light of said first and second wavelengths, said storage medium, means for directing radiation of said first and second wavelengths for localized incidence on said medium and photodetector means for measuring radiation coming from said medium, said medium being a nitroprusside single crystal of the formula M m [Fe(CN) 5 NO]nH 2 O, wherein M is a metal capable of forming a nitroprusside salt, m is a valence-determined number determined by the valence of the metal M and the -2 valence of the nitroprusside group [Fe(CN) 5 NO] and n is an integer in range 0, 1, 2, 3 . . . 10, said first light wavelength being in the range between 400 and 530 mn, said second light wavelength being in the range from 600 to 680 nm, and means being provided for cooling said single crystal at a temperature in the range between 140° K. and 210° K.
Claim 3
Dependent Claim
31 words
Optical switch according to claim 1, in which the material of said single crystal is selected from the group consisting of nitroprussides of alkali metals and nitroprussides of alkaline earth metals.
Claim 4
Dependent Claim
39 words
Optical switch according to claim 2, in which said first light wavelength is a wavelength in the range between 430 and 510 nm, and said second light wavelength is a wavelength in the range between 600 and 660 nm.
Claim 5
Dependent Claim
30 words
Optical switch according to claim 3, in which said single crystal is in the form of a wafer having a thickness in the range between 0.05 mm and 0.25 mm.
Claim 6
Dependent Claim
61 words
Optical switch according to claim 3, in which said light source comprises a first laser (I) for emission of light at said first wavelength and a second laser (II) for emission of light at said second wavelength; and said means directing light from said first and second lasers to said single crystal comprise first (2) and second (3) movable laser mirrors.
Claim 7
Dependent Claim
61 words
Optical switch according to claim 4, in which said light source comprises a first laser (I) for emission of light at said first wavelength and a second laser (II) for emission of light at said second wavelength; and said means directing light from said first and second lasers to said single crystal comprise first (2) and second (3) movable laser mirrors.
Claim 8
Dependent Claim
13 words
Optical switch according to claim 5, in which said lasers are pulsed lasers.
Claim 9
Dependent Claim
13 words
Optical switch according to claim 6, in which said lasers are pulsed lasers.
Claim 10
Dependent Claim
23 words
Optical switch according to claim 3, in which the material of said single crystal is barium nitroprusside, Ba [Fe(CN) 5 NO]nH 2 O.
Claim 11
Dependent Claim
23 words
Optical switch according to claim 4, in which the material of said single crystal is barium nitroprusside, Ba [Fe(CN) 5 NO]nH 2 O.
Claim 12
Dependent Claim
22 words
Optical switch according to claim 5, in which the material of said single crystal is barium nitroprusside, Ba[Fe(CN) 5 NO]nH 2 O.
Claim 13
Dependent Claim
22 words
Optical switch according to claim 6, in which the material of said single crystal is barium nitroprusside, Ba[Fe(CN) 5 NO]nH 2 O.
Claim 14
Dependent Claim
22 words
Optical switch according to claim 7, in which the material of said single crystal is barium nitroprusside, Ba[Fe(CN) 5 NO]nH 2 O.
Claim 15
Dependent Claim
22 words
Optical switch according to claim 8, in which the material of said single crystal is barium nitroprusside, Ba[Fe(CN) 5 NO]nH 2 O.
Claim 16
Dependent Claim
30 words
Optical switch according to claim 9, in which said cooling means is provided for maintaining said single crystal at a temperature in the range between 190° K. and 205° K.
Claim 17
Dependent Claim
30 words
Optical switch according to claim 10, in which said cooling means is provided for maintaining said single crystal at a temperature in the range between 190° K. and 210° K.
Claim 18
Dependent Claim
30 words
Optical switch according to claim 11, in which said cooling means is provided for maintaining said single crystal at a temperature in the range between 190° K. and 210° K.
Claim 19
Dependent Claim
30 words
Optical switch according to claim 12, in which said cooling means is provided for maintaining said single crystal at a temperature in the range between 190° K. and 210° K.
Claim 20
Dependent Claim
30 words
Optical switch according to claim 13, in which said cooling means is provided for maintaining said single crystal at a temperature in the range between 190° K. and 210° K.
Claim 21
Dependent Claim
30 words
Optical switch according to claim 14, in which said cooling means is provided for maintaining said single crystal at a temperature in the range between 190° K. and 210° K.
Claim 22
Dependent Claim
43 words
Optical switch according to claim 2, in which said second wavelength is in the range between 665 and 680 nm and in which said cooling means is provided for maintaining said single crystal within the temperature range between 140° K. and 170° K.
Claim 23
Dependent Claim
30 words
Optical switch according to claim 21, in which said single crystal is in the form of a wafer having a thickness in the range between 0.05 mm and 0.25 mm.
Claim 24
Dependent Claim
26 words
Optical switch according to claim 21, in which the material of said single crystal is sodium nitroprusside, Na 2 [Fe(CN) 5 NO] 2 H 2 O.
Claim 25
Dependent Claim
26 words
Optical switch according to claim 22, in which the material of said single crystal is sodium nitroprusside, Na 2 [Fe(CN) 5 NO] 2 H 2 O.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-12-14 | 1991-06-15 | 1991-12-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-12-14 | 1995-06-15 | 1995-12-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-12-14 | 1999-06-15 | 1999-12-15 | $7700.00 | Window Closed / Lapsed |