US4713518A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Electronic device manufacturing methods
Assignee: Semiconductor Energy Laboratory Co Ltd
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Filing: 1985-06-03
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Granted: 1987-12-15
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Expires: 2005-06-03
Abstract
Abstract In a method of making an electronic device having at least a transparent conductive layer, which includes at least a step of forming a transparent conductive layer member and a step of forming a transparent conductive layer by patterning the transparent conductive layer member using a spot-shaped or linear laser beam or beams, each of which has a short wavelength of 400 nm or less and optical energy greater than the optical energy band gap of the transparent conductive layer.
Inventors
- 👤 Shunpei Yamazaki
- 👤 Kenji Itoh
- 👤 Susumu Nagayama
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 16:58
CPC Classifications
H; H10; H10F; H10F77/00; H10F77/10; H10F77/16; H10F77/169; H10F77/1692; H10F19/00; H10F19/30; H10F19/31; H10F19/33; H10F77/20; H10F77/244; H10P; H10P50/00; H05; H05K; H05K3/00; H05K3/02; H05K3/027; Y; Y02; Y02E; Y02E10/00; Y02E10/50; Y10; Y10S; Y10S438/00; Y10S438/94
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
200 words
A method for the manufacture of an electronic device which is provided with at least a transparent conductive layer, comprising the steps of: forming a transparent conductive layer on a transparent substrate having a surface of an insulator selected from the group consisting of organic and inorganic insulators, or on a non-single-crystal semi-conductor layer member, wherein the transparent conductive layer member has a thickness of two μm or less and consists principally of a sublimable metallic compound selected from the group consisting of oxides and nitrides, and wherein the non-single-crystal semi-conductor layer member consists principally of a sublimable semi-conductor which includes a dangling bond neutralizer selected from the group consisting of hydrogen and halogen; and exposing the transparent conductive layer member to irradiation by one or more pulsed laser beams which are squeezed in only one direction after expansion in cross-section and have a wavelength of 400 nm or less and optical energy greater than the optical energy band gap of the transparent conductive layer member, thereby forming the transparent conductive layer which has a thickness of 2 μm or less and consists principally of the sublimable metallic oxide or nitride on the substrate or the non-single-crystal semi-conductor layer member.
Claim 2
Independent Claim
200 words
A method for the manufacture of an electronic device which is provided with at least a transparent conductive layer, comprising the steps of: forming a transparent conductive layer on a transparent substrate having a surface of an insulator selected from the group consisting of organic and inorganic insulators, or on a non-single-crystal semi-conductor layer member, wherein the transparent conductive layer member has a thickness of two μm or less and consists principally of a sublimable metallic compound selected from the group consisting of oxides and nitrides, and wherein the non-single-crystal semi-conductor layer member consists principally of a sublimable semi-conductor which includes a dangling bond neutralizer selected from the group consisting of hydrogen and halogen; and exposing the transparent conductive layer member to irradiation by one or more pulsed laser beams which are squeezed in only one direction after expansion in cross-section and have a wavelength of 400 nm or less and optical energy greater than the optical energy band gap of the transparent conductive layer member, thereby forming the transparent conductive layer which has a thickness of 2 μm or less and consists principally of the sublimable metallic oxide or nitride on the substrate or the non-single-crystal semi-conductor layer member.
Claim 3
Independent Claim
188 words
A method for the manufacture of an electronic device which is provided with at least a non-transparent conductive layer, comprising the steps of: forming a non-transparent conductive layer member on a substrate having a surface of an insulator selected from the group consisting of organic and inorganic insulators, or on a non-single-crystal semi-conductor layer member, wherein the non-transparent conductive layer consists principally of a metal selected from the group consisting of sublimable and non-sublimable metals, and wherein the non-single-crystal semi-conductor layer member consists principally of a sublimable semi-conductor which includes a dangling bond neutralizer selected from the group consisting of hydrogen and halogen; and exposing the non-transparent conductive layer member to irradiation one or more pulsed laser beams which are squeezed in only one direction after expansion in cross-section and have a wave length of 400 nm or less and optical energy greater than the optical energy band gap of the transparent conductive layer member, thereby forming the non-transparent conductive layer which has a thickness of 2 μm or less and consists principally of the sublimable or non-sublimable metal on the substrate or the non-single-crystal semi-conductor layer member.
Claim 4
Independent Claim
188 words
A method for the manufacture of an electronic device which is provided with at least a non-transparent conductive layer, comprising the steps of: forming a non-transparent conductive layer member on a substrate having a surface of an insulator selected from the group consisting of organic and inorganic insulators, or on a non-single-crystal semi-conductor layer member, wherein the non-transparent conductive layer consists principally of a metal selected from the group consisting of sublimable and non-sublimable metals, and wherein the non-single-crystal semi-conductor layer member consists principally of a sublimable semi-conductor which includes a dangling bond neutralizer selected from the group consisting of hydrogen and halogen; and exposing the non-transparent conductive layer member to irradiation one or more pulsed laser beams which are squeezed in only one direction after expansion in cross-section and have a wave length of 400 nm or less and optical energy greater than the optical energy band gap of the transparent conductive layer member, thereby forming the non-transparent conductive layer which has a thickness of 2 μm or less and consists principally of the sublimable or non-sublimable metal on the substrate or the non-single-crystal semi-conductor layer member.
Claim 5
Independent Claim
278 words
A method for the manufacture of an electronic device which is provided with at least a first laminate member of transparent and non-transparent conductive layers, comprising the steps of: forming a second laminate member of transparent and non-transparent conductive layer member on a substrate having a surface of an insulator selected from the group consisting of organic and inorganic insulators or on a non-single-crystal semi-conductor layer member, wherein the transparent conductive layer of the second laminate member consists principally of a sublimable metallic compound selected from the group consisting of oxides and nitrides wherein the second laminate member has a thickness of 2 μm or less, wherein the nontransparent conductive layer of the second laminate member consists principally of a metal selected from the group consisting of sublimable metals and non-sublimable metals, wherein the non-single-crystal semi-conductor layer member consists principally of a sublimable semiconductor which includes a dangling bond neutralizer selected from the group consisting of hydrogen and halogen; and exposing the second laminate member to irradiation by one or more pulses laser beams which are squeezed in only one direction after expansion in cross-section and have a wave length of 400 nm or less and optical energy greater than the optical energy band gap of the transparent and non-transparent layers of the second laminate member, thereby forming the first laminate member which has a thickness of 2 μm or less, wherein the transparent conductive layer of the first laminate member consists principally of the sublimable metallic oxide or nitride, and wherein the non-transparent conductive layer for the first laminate member consists principally of the sublimable or nonsublimable metal on the substrate or the non-single-crystal semi-conductive layer member.
Claim 6
Independent Claim
278 words
A method for the manufacture of an electronic device which is provided with at least a first laminate member of transparent and non-transparent conductive layers, comprising the steps of: forming a second laminate member of transparent and non-transparent conductive layer member on a substrate having a surface of an insulator selected from the group consisting of organic and inorganic insulators or on a non-single-crystal semi-conductor layer member, wherein the transparent conductive layer of the second laminate member consists principally of a sublimable metallic compound selected from the group consisting of oxides and nitrides wherein the second laminate member has a thickness of 2 μm or less, wherein the nontransparent conductive layer of the second laminate member consists principally of a metal selected from the group consisting of sublimable metals and non-sublimable metals, wherein the non-single-crystal semi-conductor layer member consists principally of a sublimable semiconductor which includes a dangling bond neutralizer selected from the group consisting of hydrogen and halogen; and exposing the second laminate member to irradiation by one or more pulses laser beams which are squeezed in only one direction after expansion in cross-section and have a wave length of 400 nm or less and optical energy greater than the optical energy band gap of the transparent and non-transparent layers of the second laminate member, thereby forming the first laminate member which has a thickness of 2 μm or less, wherein the transparent conductive layer of the first laminate member consists principally of the sublimable metallic oxide or nitride, and wherein the non-transparent conductive layer for the first laminate member consists principally of the sublimable or nonsublimable metal on the substrate or the non-single-crystal semi-conductive layer member.
Claim 7
Independent Claim
236 words
A method for the manufacture of an electronic device which is provided with at least a non-single-crystal semiconductor layer, comprising the steps of: forming a non-single-crystal semiconductor layer member on a transparent or non-transparent conductive layer or on a laminate member of transparent and non-transparent conductive layers, wherein the non-single-crystal semiconductor layer has a thickness of 2μm or less, wherein the non-single-crystal semiconductor layer consists principally of a sublimable semiconductor which includes dangling bond neutralizer selected from the group consisting of hydrogen and halogen, wherein the transparent conductive layer of the second laminate member consists principally of a sublimable metallic compound selected from the group consisting of oxides and nitrides, wherein the second laminate member has a thickness of two μm or less, and wherein the non-transparent conductive layer of the second laminate member consists principally of a metal selected from the group consisting of sublimable metals and non-sublimable metals; and exposing the non-single-crystal semiconductor layer member to irradiation by one or more pulsed laser beams which are squeezed in only one direction after expansion in cross-section and have a wave length of 400 nm or less and optical energy greater than the optical energy band gap of the non-single-crystal semiconductive layer member, thereby forming the non-single-crystal semiconductor layer which has a thickness of 2 μm or less and consists principally of the sublimable semi-conductor on the transparent or non-transparent conductive layer or the laminate member.
Claim 8
Independent Claim
236 words
A method for the manufacture of an electronic device which is provided with at least a non-single-crystal semiconductor layer, comprising the steps of: forming a non-single-crystal semiconductor layer member on a transparent or non-transparent conductive layer or on a laminate member of transparent and non-transparent conductive layers, wherein the non-single-crystal semiconductor layer has a thickness of 2μm or less, wherein the non-single-crystal semiconductor layer consists principally of a sublimable semiconductor which includes dangling bond neutralizer selected from the group consisting of hydrogen and halogen, wherein the transparent conductive layer of the second laminate member consists principally of a sublimable metallic compound selected from the group consisting of oxides and nitrides, wherein the second laminate member has a thickness of two μm or less, and wherein the non-transparent conductive layer of the second laminate member consists principally of a metal selected from the group consisting of sublimable metals and non-sublimable metals; and exposing the non-single-crystal semiconductor layer member to irradiation by one or more pulsed laser beams which are squeezed in only one direction after expansion in cross-section and have a wave length of 400 nm or less and optical energy greater than the optical energy band gap of the non-single-crystal semiconductive layer member, thereby forming the non-single-crystal semiconductor layer which has a thickness of 2 μm or less and consists principally of the sublimable semi-conductor on the transparent or non-transparent conductive layer or the laminate member.
Claim 9
Dependent Claim
67 words
The manufacturing method according to claims 1, 2, 3 or 4 wherein the linear-shaped pulsed laser beam or beams are excimer laser beams having a wavelength of about 193 nm (ArF), about 248 nm (KrF), about 308 nm (XeCl), or about 315 nm (XeF), argon laser beams having a wavelength of about 363 or about 351 nm, or nitrogen laser beams having a wavelength of 337 nm.
Claim 10
Dependent Claim
27 words
The manufacturing method according to claims 1, 2, 3 or 4 wherein the linear-shaped pulsed laser beam or beams have a width of 50 nano-second or less.
Claim 11
Dependent Claim
24 words
The manufacturing method according to claim 1, 2, 3 or 4 wherein the linear-shaped pulsed laser beam irradiation is effected in a low-pressure atmosphere.
Claim 12
Dependent Claim
22 words
The manufacturing method according to claim 7 wherein the low-pressure atmosphere has a degree of vacuum of 10 -5 torr or less.
Claim 13
Dependent Claim
49 words
The manufacturing method according to claims 1, 2, 3 or 4 wherein the linear-shaped pulsed laser beam or beams are obtained by once diverging linear-shaped pulsed laser beam from a pulsed laser beam source and then applying the diverged beam to a cylindrical lens or lenses to converge it.
Claim 14
Dependent Claim
33 words
The manufacturing method according to claim 9 wherein the linear-shaped pulsed laser beam source is an excimer pulsed laser beam source, argon linear-shaped pulsed laser beam source, or nitrogen pulsed laser beam source.
Claim 15
Dependent Claim
26 words
The manufacturing method according to claim 9 wherein the linear-shaped pulsed laser beam is 3 to 60 μm wide in cross section on the layer member.
Claim 16
Dependent Claim
57 words
The method as defined by claim 1 or 3 in which said sublimable metallic oxide is selected from the group consisting of Sn O 2 , In 2 O 3 , and ITO (Indium-Tin Oxide), and in which said sublimable metallic nitride is selected from the group consisting of SbN, InN and Sn 3 N 4 .
Claim 17
Independent Claim
48 words
The method as defined by claims 1, 2, 3 or 4 in which said sublimable semi-conductor material is selected from the group consisting of Si, Si x Ge 1-x (where 0<x<0.5), Si x C 1-x (where 0<x<1), Si 3 N 4-x (where 0<x<2), and SiO 2-x (where 0<x<1).
Claim 18
Independent Claim
44 words
The method as defined by claims 2 or 3 in which said sublimable metal is selected from the group consisting of Cr, Cr-Cu alloy, and Cr-N alloy and in which said non-sublimable metal is selected from the group consisting of Al, Cu and Ag.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-12-14 | 1991-06-15 | 1991-12-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-12-14 | 1995-06-15 | 1995-12-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-12-14 | 1999-06-15 | 1999-12-15 | $7700.00 | Window Closed / Lapsed |