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US4713283A Expired / Lapsed US ⏱️ 0.0 years remaining

Reinforced composite structures

Assignee: Cytec Technology Corp
•
Filing: 1985-01-15
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Granted: 1987-12-15
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Expires: 2005-01-15
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Abstract

Abstract A reinforced composite structure comprising parallel, aligned continuous filaments extending along the maximum dimension of the structure, said fibres being bonded together with a thermoplastic matrix polymer which intimately contacts substantially the whole of the surface of the filaments characterized in that the reinforcement of the structure comprises at least 30% by volume of filamentary reinforcing material and from 1% up to 30% by volume, preferably from 5 to 15% by volume of particulate filler. The preferred process for producing the product use a mixture of polymer, filler and melt plasticizer for the polymer to effect impregnation of the continuous fibres with the melt plasticizer subsequently being volatilized at a temperature at which the polymer is molten.

Inventors

  • 👤 Frederic N. Cogswell
  • 👤 Umakant Measuria

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 15:38
CPC Classifications
B; B29; B29C; B29C70/00; B29C70/02; B29C70/021; B29C70/025; C; C08; C08J; C08J5/00; C08J5/04; C08K; C08K13/00; C08K13/04; C08K7/00; C08K7/02; B29K; B29K2105/00; B29K2105/06; B29K2105/08; B29K2105/10; B29K2105/101; B29K2995/00; B29K2995/0037; B29K2995/0077; Y; Y10; Y10S; Y10S428/00; Y10S428/902; Y10T; Y10T428/00; Y10T428/249921; Y10T428/249924; Y10T428/24994; Y10T428/249942; Y10T428/249945; Y10T428/249946; Y10T428/249947; Y10T428/25; Y10T428/251; Y10T428/30

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 98 words
A reinforced composite structure comprising parallel, aligned continuous filaments extending along the maximum dimension of the structure, said filaments being present in a thermoplastic matrix polymer which intimately contacts substantially the whole of the surface of the filaments characterised in that the reinforcement of the structure comprises at least 30% by volume of filamentary reinforcing material and from 1% up to 30% by volume of particulate filler and that said intimate contact between matrix polymer and the surface of the filaments is achieved by the use of a molten mixture of thermoplastic polymer and plasticiser for the polymer.
Claim 2
Dependent Claim 98 words
A reinforced composite structure comprising parallel, aligned continuous filaments extending along the maximum dimension of the structure, said filaments being present in a thermoplastic matrix polymer which intimately contacts substantially the whole of the surface of the filaments characterised in that the reinforcement of the structure comprises at least 30% by volume of filamentary reinforcing material and from 1% up to 30% by volume of particulate filler and that said intimate contact between matrix polymer and the surface of the filaments is achieved by the use of a molten mixture of thermoplastic polymer and plasticiser for the polymer.
Claim 3
Dependent Claim 21 words
A reinforced composite structure according to claim 1 wherein the concentration of particulate filler is between 5 and 15% by volume.
Claim 4
Dependent Claim 26 words
A reinforced composite according to either of claims 1 or 2 in which the particulate filler is selected from talc, mica, wollastinite, metal powders and graphite.
Claim 5
Dependent Claim 22 words
A reinforced composite according to claim 1 wherein the reinforcing fibre is selected from glass, carbon and high modulus synthetic polymer fibres.
Claim 6
Dependent Claim 115 words
A process of producing a reinforced thermoplastic polymer composite structure containing at least 30% by volume of continuous reinforcing filaments impregnated with thermoplastic polymer comprising: introducing a plurality of continuous filaments into a polymer melt to produce an impregnated structure characterised in that the melt comprises a mixture of a thermoplastic polymer, a particulate filler and a plasticiser for the polymer in the weight ratio between 1:4 and 99:1 of polymer to plasticiser, cooling the impregnated structure and optionally removing the plasticiser before or after the cooling step, the plasticiser being thermally stable at least up to the temperature of the melt wherein the volumetric concentration of the particulate filler is from 1 to 30%.
Claim 7
Dependent Claim 115 words
A process of producing a reinforced thermoplastic polymer composite structure containing at least 30% by volume of continuous reinforcing filaments impregnated with thermoplastic polymer comprising: introducing a plurality of continuous filaments into a polymer melt to produce an impregnated structure characterised in that the melt comprises a mixture of a thermoplastic polymer, a particulate filler and a plasticiser for the polymer in the weight ratio between 1:4 and 99:1 of polymer to plasticiser, cooling the impregnated structure and optionally removing the plasticiser before or after the cooling step, the plasticiser being thermally stable at least up to the temperature of the melt wherein the volumetric concentration of the particulate filler is from 1 to 30%.
Claim 8
Dependent Claim 32 words
A process according to claim 5 wherein the plasticiser is volatilised at a temperature at which the polymer is molten, after the continuous filaments have been introduced into the plasticised polymer melt.
Claim 9
Dependent Claim 26 words
A process according to either of claims 5 or 6 in which the weight ratio of polymer to plasticiser is in the range 1:3 to 19:1.
Claim 10
Dependent Claim 26 words
A process according to claim 5 in which the thermoplastic polymer is a thermoplastic having a tensile yield stress of at least 70 MN/m 2 .
Claim 11
Dependent Claim 47 words
A process according to claim 5 wherein the thermoplastic polymer has a tensile yield strength of less than 70 MN/m 2 prior to the impregnation stage but is treated so as to increase the tensile yield stress to greater than 70 MN/m 2 after the impregnation stage.

References Cited (Backward Citations)

US3461094A Cited
FR2463159A1 Cited
EP0056703B1 Cited
EP0102159A2 Cited
EP0102158A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-12-14 1991-06-15 1991-12-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-12-14 1995-06-15 1995-12-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-12-14 1999-06-15 1999-12-15 $7700.00 Window Closed / Lapsed

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