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EP0102158A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Method of producing fibre-reinforced composition

Assignee: Imperial Chemical Industries Ltd
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Filing: 1983-07-11
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Granted: —
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Expires: 2003-07-11
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Abstract

Abstract A process of producing a fibre-reinforced composition comprising drawing a plurality of continuous filaments through a melt comprising a mixture of a thermoplastic polymer and a plasticiser for the polymer in the weight ratio between 1:4 and 99:1 of polymer to plasticiser, preferably in the weight ratio 1:1 to 19:1, the plasticiser being thermally stable at least up to the temperature of the melt and having volatility characteristics such that the plasticiser is not substantially volatilised from the composition below the melt temperature of the thermoplastic polymer but has a sufficiently low volatility at the temperature of the melt to plasticise the polymer in the melt and give a melt of reduced viscosity compared with the melt viscosity of the polymer alone. The process enables improved fibre wetting and/or easier processing to be achieved in comparison with a process in which no plasticiser is used. Higher molecular weight polymer may also be used than when plasticiser is absent.

Inventors

  • 👤 Frederic Neil Cogswell
  • 👤 Eric Nield
  • 👤 Philip Anthony Staniland

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-30 16:46
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/04; C08J3/00; C08J3/18; C08K; C08K5/00; C08K5/0008; C08K5/0016

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 94 words
A process of producing a fibre-reinforced composition comprising drawing a plurality of continuous filaments through a melt comprising a mixture of a thermoplastic polymer and a plasticiser for the polymer in the weight ratio between 1:4 and 99:1 of polymer to plasticiser, the plasticiser being thermally stable at least up to the temperature of the melt and having volatility characteristics such that the plasticiser is not substantially volatilised from the composition below the melt temperature of the composition, said plasticiser reducing the viscosity of the melt in comparsion with that of the polymer alone.
Claim 2
Dependent Claim 94 words
A process of producing a fibre-reinforced composition comprising drawing a plurality of continuous filaments through a melt comprising a mixture of a thermoplastic polymer and a plasticiser for the polymer in the weight ratio between 1:4 and 99:1 of polymer to plasticiser, the plasticiser being thermally stable at least up to the temperature of the melt and having volatility characteristics such that the plasticiser is not substantially volatilised from the composition below the melt temperature of the composition, said plasticiser reducing the viscosity of the melt in comparsion with that of the polymer alone.
Claim 3
Dependent Claim 37 words
A process according to claim 1 wherein the melt viscosity of the polymer in the absence of the plasticiser is at least 100 Ns/m 2 at zero shear rate measured below the decomposition temperature of the polymer.
Claim 4
Dependent Claim 37 words
A process according to either of claim 1 or claim 2 in which the polymer/plasticiser melt is contained within a melt bath provided with at least one spreader surface over which the plurality of filaments are pulled.
Claim 5
Dependent Claim 93 words
A process according to either of claims 1 or 2 in which the plurality of continuous filaments is formed into a band of contiguous filaments which are pulled over a spreader surface to form a nip between the band and the spreader surface and a molten mixture of polymer and plasticiser is provided at the nip, impregnation of the band formed by the contiguous filaments being effected by tensioning the continuous band so that positive pressure is applied on the polymer melt by the band as it is pulled over the spreader surface.
Claim 6
Dependent Claim 34 words
A process according to claim 4 in which the polymer melt is maintained in a molten state during impregnation by supplying at least part of the heat required to at least one spreader surface.
Claim 7
Dependent Claim 32 words
A process according to claim 4 in which the polymer melt is maintained in a molten state during impregnation by supplying at least part of the heat required directly to the filaments.
Claim 8
Dependent Claim 59 words
A process according to any one of the preceding claims in which the thermoplastic polymer is an aromatic polymer and comprises a polymer of repeat unit of the general formula: -Ar-X-where Ar is selected from mono or polycyclic aromatic radicals and X is selected from at least one of 0, S, 50 2 , O.CO, O.CO.O, CO, -NHCO- and
Claim 11
Dependent Claim 31 words
A process according to claim 7 in which the aromatic polymer is selected from polysulphones, polyethersulphones, polyetherketones, polyetheretherketones, polyarylene oxides, polyarylene sulphides, aromatic polyamides, aromatic polyesters, aromatic polycarbonates, and aromatic polyetherimides.
Claim 12
Dependent Claim 29 words
A process according to any one of the preceding claims in which the polymer is a polyetherketone or polyetheretherketone and the plasticiser is an aromatic sulphone or aromatic ketone.
Claim 13
Dependent Claim 15 words
A fibre-reinforced structure produced according to the process of any one of the preceding claims.

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