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US4710397A Expired / Lapsed US ⏱️ 0.0 years remaining

Photoelectric conversion device and its manufacturing method

Assignee: Semiconductor Energy Laboratory Co Ltd
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Filing: 1984-06-13
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Granted: 1987-12-01
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Expires: 2004-06-13
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Abstract

Abstract A method for the manufacture of a semiconductor photoelectric conversion device in which a plurality n of semiconductor elements U 1 to U n are sequentially formed side by side on a substrate and connected in series one after another. The element U i (i=1, 1, substrate, a non-single-crystal semiconductor laminate member Q i on the electrode E i and a second electrode F i on the laminate member Q i . The electrode F j+1 of the element U j+1 (j=1, 2, . . . (n-1)) is connected via coupling portion K j to the first electrode E j . After the formation of a first conductive layer on the substrate, the electrode E 1 to E n are provided by forming grooves G 1 to G n-1 in the first conductive layer through use of a first laser beam. A non-single-crystal semiconductor laminate layer is formed to cover the electrodes E 1 to E n and the grooves G 1 to G n-1 , after which grooves O 1 to O n-1 are cut in the laminate layer through use of a second laser beam, forming the laminate members Q 1 to Q n . The coupling portions K 1 to K n-1 are provided by forming a second conductive layer which covers the laminate members Q 1 to Q n and the grooves O 1 to O n-1 . The electrodes F 1 to F n are provided by forming isolating portions H 1 to H n-1 in the second conductive layer through use of a third laser beam. The distances between the inner edges of the grooves G j and O j and between the inner edges of the groove O j and the isolating portion H j are greater than but close to the thickness of the laminate member Q j .

Inventors

  • 👤 Shunpei Yamazaki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 08:09
CPC Classifications
H; H10; H10F; H10F99/00; H10F39/00; H10F39/10; H10F39/107; H10F10/00; H10F10/10; H10F10/17; H10F19/00; H10F19/30; H10F19/31; H10F19/35; H10F77/00; H10F77/10; H10F77/16; H10F77/169; H10F77/1692; Y; Y02; Y02E; Y02E10/00; Y02E10/50; Y02E10/548; Y10; Y10S; Y10S438/00; Y10S438/94

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 521 words
A method of making a photoelectric conversion device in which a plurality n (when n is an integer greater than one) of semiconductor elements U 1 to U n are sequentially formed side by side by side on a substrate having an insulating surface and conneted in series one after another, the semiconductor element U i (i=1, 1, . . . n) comprising a first eletrode E i on the substrate, a non-single-crystal semiconductor laminate member Q i on the first electrode E i and a second electrode F i on the laminate member, the second electrode F j+1 of the semiconductor element U j+1 (j-1, 2, . . . (n-1)) being connected via coupling portion K j to the first electrode E j , comprising the steps of: forming a first conductive layer on the substrate; forming (n-1) sequentially arranged first grooves G 1 to G n-1 in the first conductive layer by using a first laser beam to form therein n sequentially arranged first electrodes E 1 to E n separated by the first grooves G 1 to G n-1 , respectively; forming on the substrate a non-single-crystal semiconductor laminate layer having formed therein at least one semiconductor junction and continuously extending onto the first electrode E 1 to E n and into the first grooves G 1 to G n-1 ; forming (n-1) sequentially arranged second grooves O 1 to O n-1 in the non-single-crystal semiconductor laminate layer by using a second laser beam to form therein n sequentially arranged non-single-crystal semiconductor laminate members Q 1 to Q n separated by the grooves O 1 to O n and extending on the first electrodes E 1 to E n , respectively, the second groove O j being opposite the electrode E j , the distance between first groove G j and the second groove O j being greater than the thickness of the non-single-crystal semiconductor laminate member Q j in the lateral direction; forming on the substrate a second conductive layer continuously extending on the non-single-crystal semiconductor laminate members Q 1 to Q n and into the grooves O 1 to O n-1 to provide coupling portions K 1 to K n-1 which are connected to the first electrodes E 1 to E n-1 through the grooves O 1 to O n-1 , respectively; and forming (n-1) sequentially arrranged isolating portions H 1 to H n-1 in at 1east the second conductive layer using third laser beam to form therein n sequentially arranged second electrodes F 1 to F n separated by the isolating portions H 1 to H n and opposing the first electrodes E 1 to E n through the non-single-crystal semiconductor laminate member Q j , the distance between the second groove O j and the isolating protion H j being greater than the thickness of the non-single-crystal semiconductor laminate member Q j in the same lateral direction in which the second groove O j is spaced apart from the first groove G j , the second electrode F j+1 being connected to the first electrode E j through the coupling portion K j .
Claim 2
Independent Claim 521 words
A method of making a photoelectric conversion device in which a plurality n (when n is an integer greater than one) of semiconductor elements U 1 to U n are sequentially formed side by side by side on a substrate having an insulating surface and conneted in series one after another, the semiconductor element U i (i=1, 1, . . . n) comprising a first eletrode E i on the substrate, a non-single-crystal semiconductor laminate member Q i on the first electrode E i and a second electrode F i on the laminate member, the second electrode F j+1 of the semiconductor element U j+1 (j-1, 2, . . . (n-1)) being connected via coupling portion K j to the first electrode E j , comprising the steps of: forming a first conductive layer on the substrate; forming (n-1) sequentially arranged first grooves G 1 to G n-1 in the first conductive layer by using a first laser beam to form therein n sequentially arranged first electrodes E 1 to E n separated by the first grooves G 1 to G n-1 , respectively; forming on the substrate a non-single-crystal semiconductor laminate layer having formed therein at least one semiconductor junction and continuously extending onto the first electrode E 1 to E n and into the first grooves G 1 to G n-1 ; forming (n-1) sequentially arranged second grooves O 1 to O n-1 in the non-single-crystal semiconductor laminate layer by using a second laser beam to form therein n sequentially arranged non-single-crystal semiconductor laminate members Q 1 to Q n separated by the grooves O 1 to O n and extending on the first electrodes E 1 to E n , respectively, the second groove O j being opposite the electrode E j , the distance between first groove G j and the second groove O j being greater than the thickness of the non-single-crystal semiconductor laminate member Q j in the lateral direction; forming on the substrate a second conductive layer continuously extending on the non-single-crystal semiconductor laminate members Q 1 to Q n and into the grooves O 1 to O n-1 to provide coupling portions K 1 to K n-1 which are connected to the first electrodes E 1 to E n-1 through the grooves O 1 to O n-1 , respectively; and forming (n-1) sequentially arrranged isolating portions H 1 to H n-1 in at 1east the second conductive layer using third laser beam to form therein n sequentially arranged second electrodes F 1 to F n separated by the isolating portions H 1 to H n and opposing the first electrodes E 1 to E n through the non-single-crystal semiconductor laminate member Q j , the distance between the second groove O j and the isolating protion H j being greater than the thickness of the non-single-crystal semiconductor laminate member Q j in the same lateral direction in which the second groove O j is spaced apart from the first groove G j , the second electrode F j+1 being connected to the first electrode E j through the coupling portion K j .
Claim 3
Dependent Claim 62 words
A method of making a photoelectric conversion device according to claim 1, wherein the second grooves O 1 to O n-1 are formed so that the second grooves O j extends across the first electrode E j in the direction of its thickness and that the coupling portion K j is connected with the side of the first electrode E j .
Claim 4
Dependent Claim 36 words
A method of making a photoelectric conversion device according to claim 1, wherein the formation of the first grooves G 1 to G n-1 by using the first laser beam is carried out in the air.
Claim 5
Dependent Claim 90 words
A method of making a photoelectric conversion device according to claim 3, wherein the formation of the first grooves G 1 to G n-1 by using the first laser beam is followed by etching using gas, such a s hydrogen fluoride fluoride (HF), hydrogen chloride (HCl) or Freon gas (CF 4 , CFH 3 , CClF 2 , or the like), or liquid, such as fluoric acid (HF), hydrochloric acid (HCl) or Freon liquid (C 2 F 3 Cl 4 , C 2 F 2 Cl 3 or the like).
Claim 6
Dependent Claim 36 words
A method of making a photoelectric conversion device according to claim 1, wherein the formation of the second grooves O 1 to O n-1 by using the second laser beam is carried out in the air.
Claim 7
Dependent Claim 88 words
A method of making a photoelectric conversion device according to claim 5, wherein the formation of the second grooves O 1 to O n-1 by using the second laser beam is followed by etching through using gas, such as hydrogen fluoride (HF), hydrogen chloride (HCl) or Freon gas (CF 4 , CHF 3 , CClF 2 or the like), or liquid, such as fluoric acid (FF), hydrochloric acid (HCl) or Freon liquid (C 2 F 3 Cl 4 , C 2 F 2 Cl 3 or the like).
Claim 8
Dependent Claim 36 words
A method of making a photoelectric conversion device according to claim 1, wherein the formation of the isolating portions H 1 to H n-1 by using the third laser beam is carried out in the air.
Claim 9
Dependent Claim 89 words
A method of making a photoelectric conversion device according to claim 1, wherein the formation of the isolating portions H 1 to H n-1 by using the third laser beam scanning is followed by etching through using gas, such as hydrogen fluoride (HF), hydrogen chloride (HCl) or Freon gas (CF 4 , CHF 3 , CClF 2 or the like), or liquid, such as fluoric acid (HF), hydrochloric acid (HCl) or Freon liquid (C 2 F 3 Cl 4 , C 2 F 2 Cl 3 or the like).
Claim 10
Dependent Claim 38 words
A method of making a photoelectric conversion device according to claim 1, wherein the formation of the isolating portions H 1 to H n-1 by using the third laser beam is carried out in the atmosphere of oxygen.
Claim 11
Dependent Claim 47 words
A method of making a photoelectric conversion device according to claim 1, wherein the isolating portions H 1 to H n-1 by using the third laser beam are formed so that the isolating portion H j may extend into the non-single-crystal semiconductor laminate member Q j .
Claim 12
Dependent Claim 64 words
A method of making a photoelectric conversion device according to claim 1, wherein the first grooves G 1 to G n-1 , the second grooves O 1 to O n-1 and the isolating portions H 1 to H n-1 by using respectively the first, second and third laser beams are formed by the aid of a computer while monitoring through a video camera device.

References Cited (Backward Citations)

US4042418A Cited
US4259433A Cited
US4262186A Cited
US4281208A Cited
JPS55108780A Cited
US4315096A Cited
US4456782A Cited
US4428110A Cited
JPS57163753A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-11-30 1991-06-01 1991-12-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-11-30 1995-06-01 1995-12-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-11-30 1999-06-01 1999-12-01 $7700.00 Window Closed / Lapsed

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