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US4708997A Expired / Lapsed US ⏱️ 0.0 years remaining

Suspending agent for the suspension polymerization of water-soluble monomers

Assignee: Dow Chemical Co
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Filing: 1986-03-14
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Granted: 1987-11-24
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Expires: 2006-03-14
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Abstract

Abstract A suspending agent useful in a water-in-oil suspension polymerization process comprises a fumed silica particulate having a hydrophobic character and a hydrophobic polymer. The suspending agent is useful in providing uniformly sized aqueous fluid absorbent polymer beads.

Inventors

  • 👤 Frederick W. Stanley, Jr.
  • 👤 Jack C. Lamphere
  • 👤 Yohannes Chonde

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 18:20
CPC Classifications
C; C08; C08F; C08F2/00; C08F2/32

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 78 words
A process for the suspension polymerization of water-soluble monomers comprising: (1) providing an aqueous phase comprising water and at least one water-soluble monomer, (2) providing an oil phase comprising an inert hydrophobic liquid and a suspending agent comprising (a) hydrophobic fumed silicon dioxide, and (b) a copolymer of acrylic acid and lauryl methacrylate, and (3) contacting the aqueous phase and the oil phase under conditions such that a water-in-oil suspension of polymer comprising polymerized water-soluble monomer is provided.
Claim 2
Dependent Claim 78 words
A process for the suspension polymerization of water-soluble monomers comprising: (1) providing an aqueous phase comprising water and at least one water-soluble monomer, (2) providing an oil phase comprising an inert hydrophobic liquid and a suspending agent comprising (a) hydrophobic fumed silicon dioxide, and (b) a copolymer of acrylic acid and lauryl methacrylate, and (3) contacting the aqueous phase and the oil phase under conditions such that a water-in-oil suspension of polymer comprising polymerized water-soluble monomer is provided.
Claim 3
Dependent Claim 18 words
The process of claim 1 wherein said water-soluble monomers are polymerized in the presence of a crosslinking agent.
Claim 4
Dependent Claim 15 words
The process of claim 2 wherein said crosslinking agent is provided in said aqueous phase.
Claim 5
Dependent Claim 15 words
The process of claim 2 wherein said crosslinking agent is provided in said oil phase.
Claim 6
Dependent Claim 19 words
The process of claim 2 wherein said crosslinking agent is provided in said aqueous phase and said oil phase.
Claim 7
Dependent Claim 30 words
The process of claim 1 wherein the amount of suspending agent ranges from about 0.05 to about 10 weight percent relative to the amount of water-soluble monomer which is polymerized.
Claim 8
Dependent Claim 15 words
The process of claim 1 wherein said aqueous phase is dispesed in said oil phase.

References Cited (Backward Citations)

US2982749A Cited
US4135043A Cited
US4420586A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-11-23 1991-05-25 1991-11-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-11-23 1995-05-25 1995-11-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-11-23 1999-05-25 1999-11-24 $7700.00 Window Closed / Lapsed

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