Patent US5042504A successfully refreshed from Google Patents.
US4135043A
Expired / Lapsed
US
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Process for preparing polymers in powder form
Assignee: BASF SE
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Filing: 1977-08-01
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Granted: 1979-01-16
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Expires: 1997-08-01
Abstract
Abstract Polymers in powder form are manufactured by polymerizing water-soluble ethylenically unsaturated monomers, which form hydrophilic polymers, in a powder bed of polymers of water-soluble ethylenically unsaturated compounds in the presence of polymerization initiators and water as an auxiliary liquid, the water being entirely or partially removed from the polymerization zone by evaporation during the polymerization.
Inventors
- 👤 Bernd Kast
- 👤 Joachim Stedefeder
- 👤 Axel Sanner
- 👤 Hans-Uwe Schenck
- 👤 Richard Thoma
- 👤 Hermann Fischer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 20:26
CPC Classifications
C; C08; C08F; C08F291/00; Y; Y10; Y10S; Y10S526/00; Y10S526/909
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
139 words
A process for the manufacture of a hydrophilic polymer in powder form from one or more water-soluble ethylenically unsaturated compounds which form the hydrophilic polymer, which process comprises: dissolving or emulsifying the ethylenically unsaturated monomer(s) in water to form an aqueous solution or emulsion containing from 30 to 90% by weight of monomer, based on the solution or emulsion; introducing the aqueous solution or emulsion into a polymerization zone by spraying; and polymerizing the monomer(s) in said polymerization zone at a temperature of from about 20° to 150° C. in a powder bed of a hydrophilic polymer and/or an inert inorganic material in powder form in the presence of an effective amount of a polymerization initiator and water as an auxilliary liquid, wherein the water is entirely or partially removed from the polymerization zone by evaporation during the polymerization.
Claim 2
Dependent Claim
139 words
A process for the manufacture of a hydrophilic polymer in powder form from one or more water-soluble ethylenically unsaturated compounds which form the hydrophilic polymer, which process comprises: dissolving or emulsifying the ethylenically unsaturated monomer(s) in water to form an aqueous solution or emulsion containing from 30 to 90% by weight of monomer, based on the solution or emulsion; introducing the aqueous solution or emulsion into a polymerization zone by spraying; and polymerizing the monomer(s) in said polymerization zone at a temperature of from about 20° to 150° C. in a powder bed of a hydrophilic polymer and/or an inert inorganic material in powder form in the presence of an effective amount of a polymerization initiator and water as an auxilliary liquid, wherein the water is entirely or partially removed from the polymerization zone by evaporation during the polymerization.
Claim 3
Dependent Claim
35 words
A process as set forth in claim 1, in which an aqueous solution or emulsion of the ethylenically unsaturated compound(s), which has already been heated to the polymerization temperature, is introduced into the polymerization zone.
Claim 4
Dependent Claim
57 words
A process as set forth in claim 1, in which an aqueous solution or emulsion of the ethylenically unsaturated compound(s), which has already been heated to the polymerization temperature, is mixed with an aqueous solution of a polymerization initiator, which has also been heated to the polymerization temperature, and the mixture is introduced into the polymerization zone.
Claim 5
Dependent Claim
42 words
A process as set forth in claim 1, wherein from 5 to 40% by weight of the ethylenically unsaturated compounds is made up of material which is insoluble or sparingly soluble in water, the remainder being material soluble or swellable in water.
Claim 6
Dependent Claim
31 words
A process as set forth in claim 1, in which the ethylenically unsaturated compound(s) comprises one or more ethylenically unsaturated carboxylic acids of 3 to 5 carbon atoms or derivatives thereof.
Claim 7
Dependent Claim
19 words
A process as set forth in claim 1, in which the ethylenically unsaturated compounds comprise acrylic acid and acrylamide.
Claim 8
Dependent Claim
21 words
A process as set forth in claim 1, in which the or each ethylenically unsaturated compound used forms a hydrophilic homopolymer.
Claim 9
Dependent Claim
24 words
A process as set forth in claim 1, wherein the powder bed initially consists of the hydrophilic polymer to be manufactured, in powder form.
Claim 10
Dependent Claim
26 words
A process as set forth in claim 1, wherein the particle size of the powder in the initial powder bed is from 0.1 to 5 mm.
Claim 11
Dependent Claim
26 words
A process as set forth in claim 1, wherein sufficient water is evaporated during the polymerization to remove at least 50% of the heat of polymerization.
References Cited (Backward Citations)
US2789099A
Cited
US2806018A
Cited
US2956046A
Cited
US2976263A
Cited
US3278506A
Cited
US3875130A
Cited
US3919140A
Cited
US3814742A
Cited
US3975341A
Cited
US4037040A
Cited
US4032701A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-01-15 | 1982-07-17 | 1983-01-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-01-15 | 1986-07-17 | 1987-01-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-01-15 | 1990-07-17 | 1991-01-16 | $7700.00 | Window Closed / Lapsed |