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US4704438A
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Novel styrene copolymer
Assignee: Tonen General Sekiyu KK
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Filing: 1987-04-06
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Granted: 1987-11-03
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Expires: 2007-04-06
Abstract
Abstract A novel styrene copolymer having a functional group, i.e. silyl group on the para-position of the aromatic ring, useful as a functional polymer, is provided. An effective process for the production thereof comprises contacting a random or block copolymer of p-methylstyrene and α-methylstyrene with an organolithium compound to lithiate partly the p-methyl group in the copolymer and then reacting the lithiated copolymer with a silicon compound represented by the general formula (R 1 )(R 2 )(R 3 )SiX wherein R 1 , R 2 and R 3 are, same or different, alkyl groups with 1 to 6 carbon atoms or alkenyl groups with 2 to 6 carbon atoms, at least one of R 1 , R 2 and R 3 being an alkenyl group, and X is a halogen atom.
Inventors
- 👤 Tadashi Niwa
- 👤 Masayuki Kato
- 👤 Yoshio Taguchi
- 👤 Chihiro Imai
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 19:06
CPC Classifications
C; C08; C08F; C08F8/00; C08F8/42
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
89 words
A styrene copolymer comprising, in combination, the following recurring units (A), (B) and (C): wherein R 1 , R 2 and R 3 are, same or different, alkyl groups having 1 to 6 carbon atoms or alkenyl groups having 2 to 6 carbon atoms, at least one of R 1 , R 2 and R 3 being an alkenyl group, and the proportions of the recurring units (A), (B) and (C) are respectively 1 to 70 mol %, 1 to 97 mol % and 2 to 98 mol %.
Claim 2
Dependent Claim
89 words
A styrene copolymer comprising, in combination, the following recurring units (A), (B) and (C): wherein R 1 , R 2 and R 3 are, same or different, alkyl groups having 1 to 6 carbon atoms or alkenyl groups having 2 to 6 carbon atoms, at least one of R 1 , R 2 and R 3 being an alkenyl group, and the proportions of the recurring units (A), (B) and (C) are respectively 1 to 70 mol %, 1 to 97 mol % and 2 to 98 mol %.
Claim 3
Dependent Claim
25 words
The styrene copolymer as claimed in claim 1, wherein the alkyl groups are selected from the group consisting of methyl, ethyl, n-propyl and n-butyl groups.
Claim 4
Dependent Claim
26 words
The styrene copolymer as claimed in claim 1, wherein the alkenyl groups are selected from the group consisting of vinyl, allyl, propenyl, isopropenyl and butenyl groups.
Claim 5
Dependent Claim
20 words
The styrene copolymer as claimed in claim 1, wherein the recurring units (A), (B) and (C) form a random linkage.
Claim 6
Dependent Claim
32 words
The styrene copolymer as claimed in claim 1, wherein the recurring units (A) and (B) form a random linkage and the recurring units (C) form a block linkage with the random linkage.
Claim 7
Dependent Claim
39 words
The styrene copolymer as claimed in claim 1, which further has a weight average molecular weight of several thousands to several millions and a molecular weight distribution of weight average molecular weight/number average molecular weight of at most 2.
Claim 8
Dependent Claim
28 words
The styrene copolymer as claimed in claim 1, wherein the recurring units (A), (B) and (C) are respectively 32.0 mol %, 18.0 mol % and 50.0 mol %.
Claim 9
Dependent Claim
31 words
The styrene copolymer as claimed in claim 1, wherein the proportion of the recurring units (A), (B) and (C) are respectively 37.9 mol %, 37.1 mol % and 25.0 mol %.
Claim 10
Dependent Claim
31 words
The styrene copolymer as claimed in claim 1, wherein the proportions of the recurring units (A), (B) and (C) are respectively 15.5 mol %, 9.5 mol % and 75.0 mol %.
Claim 11
Dependent Claim
31 words
The styrene copolymer as claimed in claim 1, wherein the proportions of the recurring units (A), (B) and (C) are respectively 34.0 mol %, 16.0 mol % and 50.0 mol %.
Claim 12
Dependent Claim
115 words
A process for the production of a styrene copolymer as claimed in claim 1, which comprises bringing a random or block copolymer of p-methylstyrene and α-methylstyrene into contact with an organolithium compound to lithiate partly the p-methyl groups in the copolymer and then reacting the lithiated copolymer with a silicon compound represented by the general formula (R 1 )(R 2 )(R 3 )SiX wherein R 1 , R 2 and R 3 are, same or different, alkyl groups having 1 to 6 carbon atoms or alkenyl groups having 2 to 6 carbon atoms, at least one of R 1 , R 2 and R 3 being an alkenyl group, and X is a halogen atom.
Claim 13
Dependent Claim
26 words
The process as claimed in claim 11, wherein the random or block copolymer is prepared by subjecting p-methylstyrene and α-methylstyrene to a radical or living polymerization.
Claim 14
Dependent Claim
20 words
The process as claimed in claim 12, wherein the living polymerization is carried out in the presence of an initiator.
Claim 15
Dependent Claim
29 words
The process as claimed in claim 11, wherein the organolithium compound is selected from the group consisting of methyllithium, ethyllithium, n-butyllithium, sec-butyllithium, tert-butyllithium, n-pentyllithium, tert-pentyllithium, hexyllithium, octyllithium and dodecyllithium.
Claim 16
Dependent Claim
28 words
The process as claimed in claim 11, wherein the contact with an organolithium compound is carried out in the presence of a solvent inert to the organolithium compound.
Claim 17
Dependent Claim
31 words
The process as claimed in claim 15, wherein the solvent is selected from the group consisting of hexane, heptane, octane, cyclohexane, benzene, toluene, xylene, diethyl ether, dibutyl ether, tetrahydrofuran and dioxane.
References Cited (Backward Citations)
US2642415A
Cited
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