Abstract There are disclosed a novel copolymer comprising having recurring unit represented by the formula: <IMAGE> (I) wherein Y represents a phenylene group or a naphthylene group, with a recurring number of k and a recurring unit represented by the formula: <IMAGE> (II) wherein Ar represents a divalent aryl group, with a recurring number of l, a value of k/(k+l) is 0.5 to 0.97 and having a reduced viscosity [ eta sp/c] of 0.3 dl/g or higher as measured in p-chlorophenol solution at a concentration of 0.2 g/dl at 60 DEG C., and a process for producing the novel copolymer comprising the steps of: (a) reacting dihalogenobenzonitrile represented by the following formula: <IMAGE> (III) wherein X represents a halogen atom, an alkali metal salt of hydroquinone or dihydroxynaphthalene represented by the following formula: MO-Y-OM (IV) wherein Y represents a phenylene group or a naphthylene group and M represents an alkali metal, and an alkali metal salt of a divalent phenol represented by the formula: MO-AR-OM (V) wherein in Ar represents a divalent aryl group and M represents an alkali metal, in the presence of a solvent, and (B) treating the obtained reaction product with water or an alcohol.
A process for producing a cyanoaryl ether copolymer which comprises the steps of: (A) reacting dihalogenobenzonitrile represented by the following formula: ##STR23## wherein X represents a halogen atom, an alkali metal salt of a hydroquinone or a dihydroxynaphthalene represented by the formula: MO--Y--OM (IV) wherein M represents an alkali metal and Y represents a phenylene group or a naphthylene group, and an alkali metal salt of a divalent phenol represented by the following formula: MO--Ar--OM (V) wherein M represents an alkali metal and Ar is different from Y and represents a divalent group selected from the group consisting of: ##STR24## with the amount of the compound represented by the formula (IV) to the total amount of the compounds represented by the formulae (IV) and (V) being 0.5 to 0.97 in terms of molar ratio, provided that when one of Y and Ar represents the phenylene group and the other represents the naphthylene group, the amount of the compound represented by the formula (IV) to the total amount of the compounds represented by the formulae (IV) and (V) being 0.03 to 0.97, and the moles of the compound represented by the formula (III) being equal to or slightly in excess of the total moles of the compounds represented by the formulae (IV) and (V), in the presence of a solvent and at 100° to 350° C., and (B) treating the obtained reaction product with water or an alcohol; said copolymer has a reduced viscosity [η sp/c ] of 0.3 dl/g or higher as measured in p-chlorophenol solution at a concentration of 0.2 g/dl at 60° C. and comprises a recurring unit represented by the formula: ##STR25## wherein Y represents a phenylene group or a naphthylene group, and a recurring unit represented by the formula: ##STR26##
Claim 2
Dependent Claim
294 words
A process for producing a cyanoaryl ether copolymer which comprises the steps of: (A) reacting dihalogenobenzonitrile represented by the following formula: ##STR23## wherein X represents a halogen atom, an alkali metal salt of a hydroquinone or a dihydroxynaphthalene represented by the formula: MO--Y--OM (IV) wherein M represents an alkali metal and Y represents a phenylene group or a naphthylene group, and an alkali metal salt of a divalent phenol represented by the following formula: MO--Ar--OM (V) wherein M represents an alkali metal and Ar is different from Y and represents a divalent group selected from the group consisting of: ##STR24## with the amount of the compound represented by the formula (IV) to the total amount of the compounds represented by the formulae (IV) and (V) being 0.5 to 0.97 in terms of molar ratio, provided that when one of Y and Ar represents the phenylene group and the other represents the naphthylene group, the amount of the compound represented by the formula (IV) to the total amount of the compounds represented by the formulae (IV) and (V) being 0.03 to 0.97, and the moles of the compound represented by the formula (III) being equal to or slightly in excess of the total moles of the compounds represented by the formulae (IV) and (V), in the presence of a solvent and at 100° to 350° C., and (B) treating the obtained reaction product with water or an alcohol; said copolymer has a reduced viscosity [η sp/c ] of 0.3 dl/g or higher as measured in p-chlorophenol solution at a concentration of 0.2 g/dl at 60° C. and comprises a recurring unit represented by the formula: ##STR25## wherein Y represents a phenylene group or a naphthylene group, and a recurring unit represented by the formula: ##STR26##
Claim 3
Dependent Claim
50 words
The process of claim 1, wherein a monovalent phenol of the formula: ##STR27## wherein R represents a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, an aryl group, an aralkyl group or a cyano group is added and reacted as a molecular weight controller with the copolymer.