Post-coupled mono-succinimide lubricating oil dispersant and viton seal additives

Claim 2

A lubricating oil composition comprising a major portion of a lubricating oil and a minor dispersant amount of a reaction product prepared by a process which comprises: (a) reacting an amine with an alkenyl succinic acid anhydride to form a mono-alkenyl succinimide; (b) reacting said mono-alkenyl succinimide with an excess of an aldehyde to form an imine of said monoalkenyl succinimide; (c) adding a phenol to said imine, thereby forming a Mannich phenol coupled mono-alkenyl succinimide; (d) acylating said mono-alkenyl succinimide with glycolic acid or oxalic acid to form a glycolated Mannich phenol coupled mono-alkenyl succinimide; and (e) recovering the acylated, Mannich phenol coupled mono-alkenyl succinimide.

Claim 3

The lubricating oil composition of claim 1, wherein said amine is represented by the formula ##STR5## where R' is H or a hydrocabon selected from the group consisting of alkyl, alkalyl, cycloalkyl, aryl, alkaryl, alkenyl and alkynyl group; R" is a hydrocarbon selected from the same group as R' except that R" contains one less H; a is an integer of about 1 to about 6; and n is 0 or 1.

Claim 4

The lubricating oil composition of claim 1, wherein said amine is selected from the group consisting of ethylenediamine, propylenediamine, diethylenetriamine, triethylenetetramine, tetraethylenepentamine and pentaethylenehexamine.

Claim 5

The lubricating oil composition of claim 1, wherein said amine is tetraethylenepentamine.

Claim 6

The lubricating oil composition of claim 1, wherein said amine is pentaethylenehexamine.

Claim 7

The lubricating oil composition of claim 1, wherein said amine is triethylenetetramine.

Claim 8

The lubricating oil composition of claim 1, wherein said succinimide is acylated with glycolic acid.

Claim 9

The lubricating oil composition of claim 1, wherein said aldehyde is selected from the group consisting of formaldehyde, paraformaldehyde, ethanal, propanal and butanal.

Claim 10

The lubricating oil composition of claim 8, wherein said aldehyde is paraformaldehyde.

Claim 11

The lubricating oil composition of claim 1, wherein said phenol is selected from the group consisting of phenol, bisphenol A, resorcinol, and beta-naphthol.

Claim 12

The lubricating oil composition of claim 1, wherein said phenol is phenol.

Claim 13

The lubricating oil composition of claim 11, wherein said phenol is 4-nonylphenol.

Claim 14

The lubricating oil composition of claim 1, wherein said reaction product is an acylated Mannich phenol coupled glycamide mon-alkenyl succinimide ##STR6## where R is polyisobutenyl and x is an integer of 1 to 6.

Claim 15

A lubricating oil composition comprising a major portion of a lubricating oil and minor dispersant amount of a reaction product prepared by a process which comprises: (a) reacting an alkenyl succinic acid anhydride with a polyethylene amine ##STR7## wherein R' is H or a hydrocabon selected from the group consisting of alkyl, alalkyl, cycloalkyl, aryl, alkaryl, alkenyl and alkynyl group; R" is a hydrocarbon selected from the same group as R' except that R" contains one less H; a is an integer of about 1 to about 6 and n is 0 or 1, to form a mono-alkenyl succinimide ##STR8## where R is polyisobutenyl and x is an integer of 1 to 6; (b) reacting said mono-alkenyl succinimide with an excess of formaldehyde to form an imine of said monoalkenyl succinimide ##STR9## (c) adding an phenol to said imine thereby forming a Mannich phenol coupled mono-alkenyl succinimide ##STR10## (d) acylating said mono-alkenyl succinimide with glycolic acid to form a glycolated Mannich phenol coupled glycamide mono-alkenyl succinimide ##STR11## (e) recovering the acylated, Mannich pehnol coupled mono-alkenyl succinimide.

Claim 16

A lubricating oil composition comprising a major portion of a lubricating oil and minor dispersant amount of a reaction product prepared by a process which comprises: (a) reacting an alkenyl succinic acid anhydride with a polyethylene amine ##STR7## wherein R' is H or a hydrocabon selected from the group consisting of alkyl, alalkyl, cycloalkyl, aryl, alkaryl, alkenyl and alkynyl group; R" is a hydrocarbon selected from the same group as R' except that R" contains one less H; a is an integer of about 1 to about 6 and n is 0 or 1, to form a mono-alkenyl succinimide ##STR8## where R is polyisobutenyl and x is an integer of 1 to 6; (b) reacting said mono-alkenyl succinimide with an excess of formaldehyde to form an imine of said monoalkenyl succinimide ##STR9## (c) adding an phenol to said imine thereby forming a Mannich phenol coupled mono-alkenyl succinimide ##STR10## (d) acylating said mono-alkenyl succinimide with glycolic acid to form a glycolated Mannich phenol coupled glycamide mono-alkenyl succinimide ##STR11## (e) recovering the acylated, Mannich pehnol coupled mono-alkenyl succinimide.