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Cholesteric liquid crystal copolyesters

Assignee: NIPPON COMPANY Ltd A CORP OF JAPAN
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Filing: 1986-08-28
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Granted: 1987-10-06
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Expires: 2006-08-28
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Abstract

Abstract A process for preparing a cholesteric liquid crystal copolyester consisting essentially of structural units represented by the following formula (A), (B), (C) and (D): <IMAGE> (A) OCH2CH2O (B) <IMAGE> (C) <IMAGE> (D) which is optically active characterized in that a polyethylene terephthalate oligomer having a (B)/(A) mole ratio in the range of 1.1 to 1.8, p-acetoxybenzoic acid and 3-methyladipic acid are reacted to prepare the final cholesteric liquid crystal copolyester having an inherent viscosity of at least 0.4 dl/g.

Inventors

  • 👤 Tomohiro Toya
  • 👤 Hajime Hara
  • 👤 Shigeki Iida
  • 👤 Tetsuo Satoh

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 19:45
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/60; C09; C09K; C09K19/00; C09K19/04; C09K19/38; C09K19/3804; C09K19/3809

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 72 words
A process for preparing a cholesteric liquid crystal copolyester consisting essentially of structural units represented by the following formula (A), (B), (C) and (D): ##STR3## which is optically active characterized in that a polyethylene terephthalate oligomer having a (B)/(A) mole ratio in the range of 1.1 to 1.8, p-acetoxybenzoic acid and 3-methyladipic acid are reacted to prepare the final cholesteric liquid crystal copolyester having an inherent viscosity of at least 0.4 dl/g.
Claim 2
Dependent Claim 72 words
A process for preparing a cholesteric liquid crystal copolyester consisting essentially of structural units represented by the following formula (A), (B), (C) and (D): ##STR3## which is optically active characterized in that a polyethylene terephthalate oligomer having a (B)/(A) mole ratio in the range of 1.1 to 1.8, p-acetoxybenzoic acid and 3-methyladipic acid are reacted to prepare the final cholesteric liquid crystal copolyester having an inherent viscosity of at least 0.4 dl/g.
Claim 3
Dependent Claim 26 words
A process as set forth in claim 1, wherein the (B)/(A) mole ratio of the polyethylene terephthalate oligomer is in the range of 1.2 to 1.5.
Claim 4
Dependent Claim 33 words
A process as set forth in claim 1, wherein said copolyester comprises 20-80 mole% of structural unit (C), 1-20 mole% of structural unit (D), and the balance of structural units (A) and (B).
Claim 5
Dependent Claim 33 words
A process as set forth in claim 1, wherein said copolyester comprises 30-70 mole% of structural unit (C), 2-15 mole% of structural unit (D), and the balance of structural units (A) and (B).
Claim 6
Dependent Claim 29 words
A process as set forth in claim 1, wherein the reaction is carried out in a molten condition at a temperature in the range of 200° to 350° C.

References Cited (Backward Citations)

US4146702A Cited
US4242496A Cited
US4621129A Cited
US4652626A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-10-05 1991-04-06 1991-10-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-10-05 1995-04-06 1995-10-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-10-05 1999-04-06 1999-10-06 $7700.00 Window Closed / Lapsed

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