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US4698388A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for modifying the surface of polymer materials

Assignee: NOF Corp
•
Filing: 1986-02-18
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Granted: 1987-10-06
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Expires: 2006-02-18
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Abstract

Abstract The surface of a polymer material is modified by adding to the material a block copolymer. The block copolymer has a hydrophilic polymer portion and a polymer portion which is compatible with the polymer material to be modified. The block copolymer can be easily synthesized in the presence of a polymeric peroxide and can easily and permanently modify the surface of the polymer material.

Inventors

  • 👤 Hiroshi Ohmura
  • 👤 Yoshihiro Oshibe
  • 👤 Masaharu Nakayama
  • 👤 Takashi Yamamoto

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 22:39
CPC Classifications
C; C08; C08L; C08L53/00; C08F; C08F293/00; C08L101/00; C08L23/00; C08L23/02; C08L2555/00; C08L2555/40; Y; Y10; Y10S; Y10S260/00; Y10S260/15; Y10S260/17; Y10S260/18; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31536

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 217 words
A method for modifying the surface of a natural polymer material, comprising adding a block copolymer consisting of a polymer portion compatible with the natural polymer material and a hydrophilic polymer portion to the natural polymer material, said block copolymer having been produced through the following first and second steps, in the first step, either a vinyl monomer which forms a hydrophilic polymer, or a vinyl monomer which forms a polymer compatible with the polymer material, is polymerized in the presence of a polymeric peroxide as a polymerization initiator to produce a peroxy bond containing polymer, and in the second step, either a vinyl monomer which forms a hydrophilic polymer, or a vinyl monomer which forms a polymer compatible with the natural polymer material, both the vinyl monomers being used in such a manner that, when a hydrophilic polymer is produced in the first step, a vinyl monomer which forms a polymer compatible with the natural polymer material is used in the second step, and when a polymer compatible with the natural polymer material is produced in the first step, a vinyl monomer which forms a hydrophilic polymer is used in the second step, is polymerized in the presence of a polymerization initiator of the peroxy bond- or azo bond-containing natural polymer obtained in the first step.
Claim 2
Independent Claim 217 words
A method for modifying the surface of a natural polymer material, comprising adding a block copolymer consisting of a polymer portion compatible with the natural polymer material and a hydrophilic polymer portion to the natural polymer material, said block copolymer having been produced through the following first and second steps, in the first step, either a vinyl monomer which forms a hydrophilic polymer, or a vinyl monomer which forms a polymer compatible with the polymer material, is polymerized in the presence of a polymeric peroxide as a polymerization initiator to produce a peroxy bond containing polymer, and in the second step, either a vinyl monomer which forms a hydrophilic polymer, or a vinyl monomer which forms a polymer compatible with the natural polymer material, both the vinyl monomers being used in such a manner that, when a hydrophilic polymer is produced in the first step, a vinyl monomer which forms a polymer compatible with the natural polymer material is used in the second step, and when a polymer compatible with the natural polymer material is produced in the first step, a vinyl monomer which forms a hydrophilic polymer is used in the second step, is polymerized in the presence of a polymerization initiator of the peroxy bond- or azo bond-containing natural polymer obtained in the first step.
Claim 3
Dependent Claim 16 words
A method according to claim 1, wherein said natural polymer material is resin, fiber or rubber.
Claim 4
Dependent Claim 20 words
A method according to claim 1, wherein said natural polymer material is resin, natural rubber, cotton, linen, wool or silk.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-10-05 1991-04-06 1991-10-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-10-05 1995-04-06 1995-10-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-10-05 1999-04-06 1999-10-06 $7700.00 Window Closed / Lapsed

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