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US4696865A Expired / Lapsed US ⏱️ 0.0 years remaining

Hollow copolyamide article

Assignee: Hoover Universal Inc
•
Filing: 1984-04-20
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Granted: 1987-09-29
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Expires: 2004-04-20
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Abstract

Abstract A new article of manufacture in the form of a hollow, shaped, blow molded article formed of a composition comprising a copolyamide of hexamethylene terephthalamide and hexamethylene isophthalamide, the ratio of terephthalic acid to isophthalic acid used in forming the copolyamide being between about 1.0 to about 1.9. Such article may be formed from a precursor in the form of a hollow, shaped, tubular preform formed of such copolyamide composition.

Inventors

  • 👤 John C. Richardson
  • 👤 Morris Salame

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 15:10
CPC Classifications
B; B29; B29C; B29C49/00; B29C49/0005; C; C08; C08G; C08G69/00; C08G69/02; C08G69/26; C08G69/265; Y; Y10; Y10T; Y10T428/00; Y10T428/13; Y10T428/1352; Y10T428/1379; Y10T428/31504; Y10T428/31725

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 90 words
A new article of manufacture comprising a hollow, shaped, blow molded article formed of a composition comprising a copolyamide of hexamethylene terephthalamide and hexamethylene isophthalamide, the ratio of terephthalic acid to isophthalic acid used in forming the copolyamide being between about 1.0 to about 1.9, said article having the following barrier properties: oxygen permeability no greater than ##EQU7## measured at 23° C., 50% relative humidity; water permeability no greater than ##EQU8## measured at 30° C., and hydrocarbon permeability as measured using heptane no greater than ##EQU9## measured at 23° C.
Claim 2
Dependent Claim 90 words
A new article of manufacture comprising a hollow, shaped, blow molded article formed of a composition comprising a copolyamide of hexamethylene terephthalamide and hexamethylene isophthalamide, the ratio of terephthalic acid to isophthalic acid used in forming the copolyamide being between about 1.0 to about 1.9, said article having the following barrier properties: oxygen permeability no greater than ##EQU7## measured at 23° C., 50% relative humidity; water permeability no greater than ##EQU8## measured at 30° C., and hydrocarbon permeability as measured using heptane no greater than ##EQU9## measured at 23° C.
Claim 3
Dependent Claim 13 words
The article of claim 1 wherein said ratio is between 1 to 1.5.
Claim 4
Dependent Claim 13 words
The article of claims 1, or 2 in the form of a container.
Claim 5
Dependent Claim 21 words
The article of claim 3 wherein a wall portion thereof has a crystallinity level of between about 20 to about 70%.
Claim 6
Dependent Claim 13 words
The article of claim 4 having been molded from a freely pendant parison.
Claim 7
Dependent Claim 11 words
The article of claim 5 in the form of a bottle.
Claim 8
Dependent Claim 88 words
A new article of manufacture comprising a hollow, shaped, tubular preform of a composition comprising a copolyamide of hexamethylene terephthalamide and hexamethylene isophthalamide, the ratio of terephthalic acid to isophthalic acid used in forming the copolyamide being between about 1.0 to about 1.9, said article having the following barrier properties: oxygen permeability no greater than ##EQU10## measured at 23° C., 50% relative humidity, water permeability no greater than ##EQU11## measured at 30° C., and hydrocarbon permeability as measured using heptane no greater than ##EQU12## measured at 23° C.
Claim 9
Dependent Claim 88 words
A new article of manufacture comprising a hollow, shaped, tubular preform of a composition comprising a copolyamide of hexamethylene terephthalamide and hexamethylene isophthalamide, the ratio of terephthalic acid to isophthalic acid used in forming the copolyamide being between about 1.0 to about 1.9, said article having the following barrier properties: oxygen permeability no greater than ##EQU10## measured at 23° C., 50% relative humidity, water permeability no greater than ##EQU11## measured at 30° C., and hydrocarbon permeability as measured using heptane no greater than ##EQU12## measured at 23° C.
Claim 10
Dependent Claim 13 words
The preform of claim 7 wherein said ratio is between 1 to 1.5.
Claim 11
Dependent Claim 13 words
The preform of claim 7, or 8 having been formed by injection molding.
Claim 12
Dependent Claim 52 words
A new article of manufacture comprising a hollow, shaped, blow molded article formed of capped copolyamide which has been polymerized in the solid state, said copolyamide comprising hexamethylene terephthalamide and hexamethylene isophthalamide, the ratio of terephthalic acid to isophthalic acid used in forming the copolyamide being between about 1.0 to about 1.9.
Claim 13
Dependent Claim 52 words
A new article of manufacture comprising a hollow, shaped, blow molded article formed of capped copolyamide which has been polymerized in the solid state, said copolyamide comprising hexamethylene terephthalamide and hexamethylene isophthalamide, the ratio of terephthalic acid to isophthalic acid used in forming the copolyamide being between about 1.0 to about 1.9.
Claim 14
Dependent Claim 20 words
The article of claim 10 wherein the copolyamide has an inherent viscosity of at least about 15. grams per deciliter.
Claim 15
Dependent Claim 48 words
The article of claim 10 having the following barrier properties: oxygen permeability no greater than ##EQU13## measured at 23° C., 50% relative humidity; water permeability no greater than ##EQU14## measured at 30° C. and hydrocarbon permeability as measured using heptane no greater than ##EQU15## measured at 23° C.

References Cited (Backward Citations)

US3597400A Cited
US3549601A Cited
US4022756A Cited
JPS5250A Cited
US4261473A Cited
US4288478A Cited
US4255560A Cited
JPS6355A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-09-28 1991-03-30 1991-09-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-09-28 1995-03-30 1995-09-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-09-28 1999-03-30 1999-09-29 $7700.00 Window Closed / Lapsed

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