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US4694052A Expired / Lapsed US ⏱️ 0.0 years remaining

Radiation-curable coating composition

Assignee: Mitsui Toatsu Chemicals Inc
•
Filing: 1985-06-25
•
Granted: 1987-09-15
•
Expires: 2005-06-25
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Abstract

Abstract Disclosed herein is a coating composition which contains a urethane-modified (meth)acrylate compound and a mono(meth)acrylate and is curable upon its exposure to radiation. Also disclosed herein is a coating, especially, a primary coating for an optical fiber, which coating or cladding is composes of a cured material obtained by curing the composition through its exposure to radiation.

Inventors

  • 👤 Sumio Hirose
  • 👤 Isao Naruse
  • 👤 Akio Matsuyama

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 10:25
CPC Classifications
C; C08; C08F; C08F220/00; C08F220/02; C08F220/10; C08F220/26; C08F299/00; C08F299/02; C08F299/06; C08F299/065; C08F299/04; C08F299/0485; C08F299/0492

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 159 words
Radiation-curable coating composition, which comprises: (A) a urethane-modified (meth)acrylate compound which has been prepared by reacting (a) a polyisocyanate compound containing two or more isocyanate groups per molecule, (b) a polyhydroxy compound containing two or more hydroxyl groups per molecule and (c) an unsaturated monohydroxy compound in amounts of 1.1 to 2.0 equivalents of the compound (a) and 0.1 to 1.2 equivalents of the compound (c), both per equivalent of the compound (b); and (B) a mono(meth)acrylate of the following general formula (I): ##STR3## wherein R 1 means ##STR4## R 2 denotes a hydrogen atom or methyl group, X is --CH 2 --CH 2 -- or ##STR5## l stands for an integer of 1 to 6, m means an integer of 3 to 5, n is an integer of 1 to 6, and l=n is 2 to 8, the amounts of the compounds (A) and (B) being 20 to 60 weight percent and 80 to 40 weight percent, respectively.
Claim 2
Dependent Claim 159 words
Radiation-curable coating composition, which comprises: (A) a urethane-modified (meth)acrylate compound which has been prepared by reacting (a) a polyisocyanate compound containing two or more isocyanate groups per molecule, (b) a polyhydroxy compound containing two or more hydroxyl groups per molecule and (c) an unsaturated monohydroxy compound in amounts of 1.1 to 2.0 equivalents of the compound (a) and 0.1 to 1.2 equivalents of the compound (c), both per equivalent of the compound (b); and (B) a mono(meth)acrylate of the following general formula (I): ##STR3## wherein R 1 means ##STR4## R 2 denotes a hydrogen atom or methyl group, X is --CH 2 --CH 2 -- or ##STR5## l stands for an integer of 1 to 6, m means an integer of 3 to 5, n is an integer of 1 to 6, and l=n is 2 to 8, the amounts of the compounds (A) and (B) being 20 to 60 weight percent and 80 to 40 weight percent, respectively.
Claim 3
Dependent Claim 22 words
The radiation curable coating composition as claimed in claim 1 wherein polyoxy compound (b) has a molecular weight of 700 or higher.
Claim 4
Dependent Claim 35 words
The radiation curable coating composition as claimed in claim 1 wherein the amounts of the compounds (a) and (c) are, respectively, 1.2 to 1.8 and 0.2 to 1.0 equivalent per equivalent of the compound (b).

References Cited (Backward Citations)

US2454756A Cited
US3265768A Cited
US3600290A Cited
GB1407813A Cited
US4284731A Cited
US4525258A Cited
JPS58213767A Cited
US4446286A Cited
US4514037A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-09-14 1991-03-16 1991-09-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-09-14 1995-03-16 1995-09-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-09-14 1999-03-16 1999-09-15 $7700.00 Window Closed / Lapsed

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