Flame retardant polyphenylene ether composition containing polybrominated diphenyoxybenzene and antimony oxide

Claim 2

A flame retardant thermoplastic composition comprising (a) a polyphenylene ether resin; (b) a rubber modified, high impact polystyrene resin; (c) a polybrominated 1,4-diphenoxybenzene in an amount which improves the flame retardancy of the combination of (a) and (b); and (d) antimony oxide in an amount which synergistically enhances the flame retardancy of the combination of (a), (b) and (c).

Claim 3

The composition of claim 1, in which component (a) is present in an amount from about 10 to about 90 parts by weight and component (b) is present in an amount from about 90 to about 10 parts by weight, based on 100 parts by weight of (a) and (b) combined.

Claim 4

The composition of claim 2, in which component (c) is present in an amount from about 6 to about 18 parts by weight and component (d) is present in an amount from about 2 to about 6 parts by weight, for each 100 parts by weight of (a) and (b) combined.

Claim 5

The composition of claim 1, in which the polyphenylene ether is a homopolymer or copolymer containing structural units of the formula ##STR7## in which for each of these units independently each Q 1 is hydrogen, halogen, primary or secondary lower alkyl having up to seven carbon atoms, phenyl, haloalkyl or aminoalkyl wherein at least two carbon atoms separate the halogen or nitrogen atom from the benzene ring, hydrocarbonoxy, or halohydrocarbonoxy wherein at least two carbon atoms separate the halogen and oxygen atoms; and each Q 2 is independently hydrogen, halogen, primary or secondary lower alkyl, phenyl, haloalkyl, hydrocarbonoxy or halohydrocarbonoxy as defined for Q 1 .

Claim 6

The composition of claim 1, in which the polyphenylene ether is poly(2,6-dimethyl-1,4-phenylene ether).

Claim 7

The composition of claim 5, in which the poly(2,6-dimethyl-1,4-phenylene ether) has an intrinsic viscosity of about 0.4 to 0.5 deciliters per gram in choroform at 25° C.

Claim 8

The composition of claim 1, in which the polyphenylene ether is poly(2,6-dimethyl-co-2,3,6-trimethyl-1,4-phenylene ether).

Claim 9

The composition of claim 1, in which component (c) has the formula ##STR8## in which n, p and r represent the average number of bromine atoms on the rings and are integers from 3 to the maximum number of replaceable hydrogen atoms on each ring.

Claim 10

The composition of claim 1, in which component (c) has the formula ##STR9##

Claim 11

The composition of claim 1, which includes one or more additional ingredients selected from the group consisting of plasticizers, mold release agents, melt viscosity reducers, colorants, stabilizers, antioxidants, mineral fillers, glass reinforcements, titanium oxides and lubricants.

Claim 12

The composition of claim 1, which includes an impact strength improving amount of a polymeric impact improver.

Claim 13

The composition of claim 11, in which the polymeric impact improver is a styrene-butadiene-styrene block copolymer or hydrogenated derivative thereof.

Claim 14

An article molded from the composition of claim 1.