Low molecular weight polyphenylene ether compositions

Claim 2

A thermoplastic composition which, after molding, has good impact resistance, said composition comprising: (a) a low molecular weight polyphenylene ether resin, said resin having an intrinsic viscosity of less than about 0.4 dl/g when measured in solution in chloroform at 30° C.; (b) an elastomeric block copolymer of the A-B-A 1 type, wherein terminal blocks A and A 1 are the same or different and are polymerized vinyl aromatic hydrocarbons and center block B is a polymerized conjugated diene, the molecular weight of B being higher than the combined molecular weights of A and A 1 ; and (c) a plasticizer.

Claim 3

The composition of claim 1 wherein the polyphenylene ether resin (a) has an intrinsic viscosity of from about 0.1 to about 0.33 dl/g when measured in solution in chloroform at 30° C.

Claim 4

The composition of claim 1 wherein the polyphenylene ether resin is selected from compounds of the formula ##STR5## wherein the oxygen ether atom of one unit is connected to the benzene nucleus of the next adjoining unit, n is a positive integer and it at least 50, and each Q is a monovalent substituent selected from the group consisting of hydrogen, halogen, hydrocarbon radicals free of a tertiary alpha-carbon atoms, halohydrocarbon radicals having at least two carbon atoms between the halogen atom and the phenyl nucleus, hydrocarbonoxy radicals, and halohydrocarbonoxy radicals having at least two carbon atoms between the halogen atom and the phenyl nucleus.

Claim 5

The composition of claim 3 wherein each Q is an alkyl radical having from 1 to 4 carbon atoms.

Claim 6

The composition of claim 3 wherein said polyphenylene ether is poly(2,6-dimethyl-1,4-phenylene) ether.

Claim 7

The composition of claim 1 wherein in A-B-A 1 block copolymer (b), each of terminal blocks A and A 1 has an average molecular weight of from about 2,000 to about 100,000 and center block B has an average molecular weight of from about 25,000 to about 1,000,000.

Claim 8

The composition of claim 1 wherein in the A-B-A 1 block copolymer (b), the vinyl aromatic hydrocarbons of terminal blocks A and A 1 are selected from the group consisting of styrene, α-methyl styrene, vinyltoluene, vinyl xylene, and vinyl naphthalene and the conjugated diene of center block B is selected from the group consisting of butadiene, isoprene, 1,3-pentadiene, and 2,3-dimethylbutadiene.

Claim 9

The composition of claim 1 which comprises from about 75 to about 99 parts by weight of polyphenylene ether resin (a), from about 1 to about 25 parts by weight of A-B-A 1 block copolymer (b), and from about 10 to about 70 parts by weight of plasticizer.

Claim 10

The composition of claim 1 wherein said composition includes a reinforcing amount of an inorganic reinforcing filler.

Claim 11

The composition of claim 9 wherein said composition includes from 10 to 80% by weight of fibrous glass filaments, based on the total weight of the composition.

Claim 12

The composition of claim 1 wherein said composition includes a flame-retardant amount of a flame-retardant additive.

Claim 13

The composition of claim 11 wherein said flame-retardant additive is a halogenated organic compound, a halogenated organic compound in admixture with an antimony compound, elemental phosphorus, a phosphorus compound, compounds containing phosphorus-nitrogen bonds, or a mixture of two or more of the foregoing.

Claim 14

A thermoplastic composition which, after molding, has good impact resistance, said composition comprising: (a) from about 75 to about 99 parts by weight of a low molecular weight polyphenylene ether resin, said resin having an intrinsic viscosity of less than about 0.4 dl/g when measured in solution in chloroform at 30° C.; (b) from about 1 to about 25 parts by weight of an elastomeric block copolymer of the A-B-A 1 type, wherein terminal blocks A and A 1 are the same or different and are polymerized vinyl aromatic hydrocarbons and center block B is a polymerized conjugated diene, the molecular weight of B being higher than the combined molecular weights of A and A 1 ; and (c) from about 10 to about 70 parts by weight of plasticizer.

Claim 15

A thermoplastic composition which, after molding, has good impact resistance, said composition comprising: (a) from about 75 to about 99 parts by weight of a low molecular weight polyphenylene ether resin, said resin having an intrinsic viscosity of less than about 0.4 dl/g when measured in solution in chloroform at 30° C.; (b) from about 1 to about 25 parts by weight of an elastomeric block copolymer of the A-B-A 1 type, wherein terminal blocks A and A 1 are the same or different and are polymerized vinyl aromatic hydrocarbons and center block B is a polymerized conjugated diene, the molecular weight of B being higher than the combined molecular weights of A and A 1 ; and (c) from about 10 to about 70 parts by weight of plasticizer.

Claim 16

The composition of claim 13 wherein said polyphenylene ether resin is poly(2,6-dimethyl-1,4-phenylene) ether.

Claim 17

A thermoplastic composition which, after molding, has good impact resistance, said composition comprising: (a) from about 75 to about 99 parts by weight of a low molecular weight polyphenylene ether resin, said resin having an intrinsic viscosity of less than about 0.4 dl/g when measured in solution in chloroform at 30° C.; (b) from about 1 to about 25 parts by weight of an elastomeric block copolymer of the A-B-A 1 type, wherein terminal blocks A and A 1 are the same or different and are polymerized vinyl aromatic hydrocarbons and center block B is a polymerized conjugated diene, the molecular weight of B being higher than the combined molecular weights of A and A 1 ; (c) from about 10 to about 70 parts by weight of plasticizer; and (d) a reinforcing amount of an inorganic reinforcing filler.

Claim 18

A thermoplastic composition which, after molding, has good impact resistance, said composition comprising: (a) from about 75 to about 99 parts by weight of a low molecular weight polyphenylene ether resin, said resin having an intrinsic viscosity of less than about 0.4 dl/g when measured in solution in chloroform at 30° C.; (b) from about 1 to about 25 parts by weight of an elastomeric block copolymer of the A-B-A 1 type, wherein terminal blocks A and A 1 are the same or different and are polymerized vinyl aromatic hydrocarbons and center block B is a polymerized conjugated diene, the molecular weight of B being higher than the combined molecular weights of A and A 1 ; (c) from about 10 to about 70 parts by weight of plasticizer; and (d) a reinforcing amount of an inorganic reinforcing filler.

Claim 19

The composition of claim 15 wherein said polyphenylene ether resin is poly(2,6-dimethyl-1,4-phenylene) ether.

Claim 20

The composition of claim 15 wherein said reinforcing filler comprises from 10 to 80% of fibrous glass filaments, based on the total weight of the composition.

Claim 21

A thermoplastic composition which, after molding, has good impact resistance, said composition comprising: (a) from about 75 to about 99 parts by weight of a low molecular weight polyphenylene ether resin, said resin having an intrinsic viscosity of less than about 0.4 dl/g when measured in solution in chloroform at 30° C.; (b) from about 1 to about 25 parts by weight of an elastomeric block copolymer of the A-B-A 1 type, wherein terminal blocks A and A 1 are the same or different and are polymerized vinyl aromatic hydrocarbons and center block B is a polymerized conjugated diene, the molecular weight of B being higher than the combined molecular weights of A and A 1 ; and (c) from about 10 to about 70 parts by weight of plasticizer; and (d) a flame-retardant amount of a flame-retardant additive.

Claim 22

A thermoplastic composition which, after molding, has good impact resistance, said composition comprising: (a) from about 75 to about 99 parts by weight of a low molecular weight polyphenylene ether resin, said resin having an intrinsic viscosity of less than about 0.4 dl/g when measured in solution in chloroform at 30° C.; (b) from about 1 to about 25 parts by weight of an elastomeric block copolymer of the A-B-A 1 type, wherein terminal blocks A and A 1 are the same or different and are polymerized vinyl aromatic hydrocarbons and center block B is a polymerized conjugated diene, the molecular weight of B being higher than the combined molecular weights of A and A 1 ; and (c) from about 10 to about 70 parts by weight of plasticizer; and (d) a flame-retardant amount of a flame-retardant additive.

Claim 23

The composition of claim 18 wherein said flame-retardant additive is a halogenated organic compound, a halogenated organic compound in admixture with an antimony compound, elemental phosphorus, a phosphorus compound, compounds containing phosphorus-nitrogen bonds, or a mixture of two or more of the foregoing.

Claim 24

The composition of claim 18 wherein said flame-retardant additive comprises a mixture of an organic bromine-containing compound with antimony oxide.

Claim 25

The composition of claim 18 wherein said flame-retardant additive is triphenylphosphate.

Claim 26

The composition of claim 18 wherein said flame-retardant additive is comprised of a mixture of triaryl phosphates wherein one or more aryl groups are substituted by one or more isopropyl groups.