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US4687822A Expired / Lapsed US ⏱️ 0.0 years remaining

Acrylic resin composition for use in high solids paints

Assignee: Nippon Paint Co Ltd
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Filing: 1985-12-26
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Granted: 1987-08-18
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Expires: 2005-12-26
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Abstract

Abstract An acrylic resin composition for use in high solids paints which consists essentially of an acrylic copolymer having a number average molecular weight of 500 to 5000 and being prepared by subjecting a mixture of 30 to 88 weight % of an alkyl (meth)acrylate, 2 to 60 weight % of 2,4-diphenyl-4-methyl-1-pentene, 10 to 40 weight % of a hydroxy bearing ethylenically unsaturated monomer, 0 to 10 weight % of an ethylenic unsaturated acid and 0 to 30 weight % of other copolymerizable monomer(s) to a polymerization with one or more radical initiators. Such high solids paint containing such copolymers can produce coatings with excellent weather resistance, water resistance, scratch resistance and good appearance.

Inventors

  • 👤 Yoshio Eguchi
  • 👤 Atsushi Yamada

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 11:55
CPC Classifications
C; C08; C08F; C08F220/00; C08F220/02; C08F220/10; C08F220/12

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 215 words
An acrylic resin composition for use in high solids paints, which consists essentially of an acrylic copolymer having a number average molecular weight of 500 to 5000, prepared by subjecting the following mixture to polymerization: (A) 30 to 88 weight % of an alkyl (meth)acrylate, (B) 2 to 60 weight % of 2,4-diphenyl-4-methyl-1-pentene, (C) 10 to 40 weight % of a hydroxy bearing ethylenically unsaturated monomer selected from the group consisting of hydroxyethyl acrylate, hydroxyethyl methacrylate, hydroxypropyl acrylate, hydroxypropyl methacrylate, diethylene glycol acrylate, diethylene glycol methacrylate, hydroxybutyl methacrylate, and a member represented by either one of the following formulae: ##STR2## wherein n in formula II is 2 or more and n in formula III is 1 to 5, and wherein said R group represents hydrogen or a methyl group, (D) 0 to 10 weight % of an ethylenic unsaturated acid selected from the group consisting of acrylic acid and methacrylic acid, and (E) 0 to 30 weight % of another copolymerizable monomer selected from the group consisting of t-butyl styrene, α-methyl styrene, vinyl toluene, dimethyl aminoethyl acrylate, dimethyl aminoethyl methacrylate, diethyl aminoethyl acrylate, diethyl aminoethyl methacrylate, vinyl pyridine, acrylamide, N-methylol acrylamide, N-butoxyl methyl acrylamide, acrylonitrile; fumaric ester, itaconic ester, maleic ester, said polymerization being carried out in the presence of one or more radical initiators.
Claim 2
Dependent Claim 215 words
An acrylic resin composition for use in high solids paints, which consists essentially of an acrylic copolymer having a number average molecular weight of 500 to 5000, prepared by subjecting the following mixture to polymerization: (A) 30 to 88 weight % of an alkyl (meth)acrylate, (B) 2 to 60 weight % of 2,4-diphenyl-4-methyl-1-pentene, (C) 10 to 40 weight % of a hydroxy bearing ethylenically unsaturated monomer selected from the group consisting of hydroxyethyl acrylate, hydroxyethyl methacrylate, hydroxypropyl acrylate, hydroxypropyl methacrylate, diethylene glycol acrylate, diethylene glycol methacrylate, hydroxybutyl methacrylate, and a member represented by either one of the following formulae: ##STR2## wherein n in formula II is 2 or more and n in formula III is 1 to 5, and wherein said R group represents hydrogen or a methyl group, (D) 0 to 10 weight % of an ethylenic unsaturated acid selected from the group consisting of acrylic acid and methacrylic acid, and (E) 0 to 30 weight % of another copolymerizable monomer selected from the group consisting of t-butyl styrene, α-methyl styrene, vinyl toluene, dimethyl aminoethyl acrylate, dimethyl aminoethyl methacrylate, diethyl aminoethyl acrylate, diethyl aminoethyl methacrylate, vinyl pyridine, acrylamide, N-methylol acrylamide, N-butoxyl methyl acrylamide, acrylonitrile; fumaric ester, itaconic ester, maleic ester, said polymerization being carried out in the presence of one or more radical initiators.
Claim 3
Dependent Claim 18 words
The composition according to claim 1, wherein the weight % of 2,4-phenyl-4-methyl-1-pentene is 5 to 40 weight %.

References Cited (Backward Citations)

US2714621A Cited
US3042664A Cited
US3470126A Cited
US4165418A Cited
US3914196A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-08-17 1991-02-16 1991-08-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-08-17 1995-02-16 1995-08-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-08-17 1999-02-16 1999-08-18 $7700.00 Window Closed / Lapsed

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