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US4687295A Expired / Lapsed US ⏱️ 0.0 years remaining

Optical fiber having polymethacrylate core and fluoro-copolymer cladding

Assignee: Central Glass Co Ltd
•
Filing: 1985-07-11
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Granted: 1987-08-18
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Expires: 2005-07-11
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Abstract

Abstract The invention relates to an optical fiber of the step-index type in which the core material is poly(methyl methacrylate) or a copolymer of methyl methacrylate with another methacrylate or an acrylate. A copolymer of vinylidene fluoride with hexafluoroacetone is employed as the cladding material which makes good adhesion to the polymethacrylate core. When the amount of hexafluoroacetone is 4-20 mole %, the copolymer is low in crystallinity, high in transparency, appropriately low in refrax index and higher than 100° C. in softening temperature, and can be extruded under the conditions suited to extrusion of poly(methyl methacrylate).

Inventors

  • 👤 Toshio Koishi
  • 👤 Isao Tanaka
  • 👤 Takashi Yasumura
  • 👤 Yukitoshi Nishikawa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 20:20
CPC Classifications
G; G02; G02B; G02B6/00; G02B6/02; G02B6/02033

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 45 words
An optical fiber comprising: a solid cylindrical core formed of a polymer at least a major constituent of which is methyl methacrylate; and a cladding layer which is in close contact with the core and is formed of a copolymer of vinylidene fluoride with hexafluoroacetone.
Claim 2
Dependent Claim 45 words
An optical fiber comprising: a solid cylindrical core formed of a polymer at least a major constituent of which is methyl methacrylate; and a cladding layer which is in close contact with the core and is formed of a copolymer of vinylidene fluoride with hexafluoroacetone.
Claim 3
Dependent Claim 27 words
An optical fiber according to claim 1, wherein the molar ratio of vinylidene fluoride to hexafluoroacetone in said copolymer is in the range from 96:4 to 80:20.
Claim 4
Dependent Claim 19 words
An optical fiber according to claim 2, wherein said molar ratio is in the range from 96:4 to 88:12.
Claim 5
Dependent Claim 20 words
An optical fiber according to claim 1, wherein said polymer as the core material is a homopolymer of methyl methacrylate.
Claim 6
Dependent Claim 50 words
An optical fiber according to claim 1, wherein said polymer as the core material is a copolymer of methyl methacrylate with a methacrylate or acrylate selected from the group consisting of ethyl methacrylate, n-propyl methacrylate, n-butyl methacrylate, 2-ethylexyl methacrylate, methyl acrylate, ethyl acrylate, n-propyl acrylate, n-butyl acrylate and 2-ethylhexyl acrylate.
Claim 7
Dependent Claim 23 words
An optical fiber according to claim 5, wherein methyl methacrylate occupies at least 70 mole % of said copolymer as the core material.

References Cited (Backward Citations)

GB1037498A Cited
US3993834A Cited
US4264129A Cited
US4381269A Cited
US4505543A Cited
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US4593974A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-08-17 1991-02-16 1991-08-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-08-17 1995-02-16 1995-08-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-08-17 1999-02-16 1999-08-18 $7700.00 Window Closed / Lapsed

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