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US4552431A Expired / Lapsed US ⏱️ 0.0 years remaining

Optical fibers with plastic core and polymer cladding

Assignee: Commissariat à l'Énergie Atomique et Aux Énergies Alternatives
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Filing: 1983-09-01
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Granted: 1985-11-12
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Expires: 2003-09-01
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Abstract

Abstract Described are optical fibers having a core of plastic material, such as polystyrene, and a polymer covering of vinyl acetate or a fluorine-containing derivative of vinyl acetate, and a process for producing the same by drawing a bar of the same materials.

Inventors

  • 👤 Louis-Rene Allemand
  • 👤 Jean Calvet
  • 👤 Jean-Claude Cavan
  • 👤 Jean-Claude Thevenin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 21:59
CPC Classifications
G; G02; G02B; G02B6/00; G02B6/02; G02B6/02033; G02B6/02038; G01; G01T; G01T1/00; G01T1/16; G01T1/20; G01T1/203; G02B1/00; G02B1/04; G02B1/045; G02B1/046; G02B1/048

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 53 words
Plastic optical fibers comprising a core formed by a polymer of a compound having the formula: ##STR3## in which Y is hydrogen or alkyl; and a cladding consisting essentially of a polymer selected from the group consisting of at least one vinyl acetate polymer and at least one fluorinated derivative of vinyl acetate.
Claim 2
Dependent Claim 53 words
Plastic optical fibers comprising a core formed by a polymer of a compound having the formula: ##STR3## in which Y is hydrogen or alkyl; and a cladding consisting essentially of a polymer selected from the group consisting of at least one vinyl acetate polymer and at least one fluorinated derivative of vinyl acetate.
Claim 3
Dependent Claim 13 words
Optical fibers according to claim 1, wherein said fluorinated derivative is vinyl trifluoroacetate.
Claim 4
Dependent Claim 11 words
Optical fibers according to claim 1 wherein said core is polystyrene.
Claim 5
Dependent Claim 13 words
Optical fibers according to claim 1, wherein said fibers are index gradient fibers.
Claim 6
Dependent Claim 21 words
Optical fibers according to claim 1 having scintillation or fluorescence properties, wherein said core contains a scintillating or fluorescent doping agent.
Claim 7
Dependent Claim 24 words
Optical fibers according to claim 5, wherein said doping agents are selected from the group consisting of 2-(4-tert-butylphenyl)-5-(4-biphenylyl)-1,3,4-oxadiazole (butyl PBD) and 1,4-di-[2-(4-methyl-5-phenyloxazolyl)]-benzene (dimethyl POPOP).
Claim 8
Dependent Claim 31 words
Plastic optical fibers comprising a core and a cladding, said cladding consisting essentially of a polymer selected from the group consisting of vinyl acetate and a fluorinated derivative of vinyl acetate.
Claim 9
Dependent Claim 31 words
Plastic optical fibers comprising a core and a cladding, said cladding consisting essentially of a polymer selected from the group consisting of vinyl acetate and a fluorinated derivative of vinyl acetate.
Claim 10
Dependent Claim 21 words
Optical fibers according to claim 7 having scintillation or fluorescence properties, wherein said core contains a scintillating or fluorescent doping agent.
Claim 11
Dependent Claim 24 words
Optical fibers according to claim 8, wherein said doping agent is selected from the group consisting of 2-(4-tert-butylphenyl)-5-(4-biphenylyl)-1,3,4-oxadiazole (butyl PBD) and 1,4-di-[2-(4-methyl-5-phenyloxazolyl)]-benzene (dimethyl POPOP).
Claim 12
Dependent Claim 62 words
A process for the production of plastic optical fibers having a core and a cladding, comprising performing a bar of plastic core material and coating the same with a cladding material consisting essentially of a polymer selected from the group consisting of at least one vinylacetate polymer and at least one fluorinated derivative of vinylacetate, and drawing by gravity, the so-coated preform.
Claim 13
Dependent Claim 62 words
A process for the production of plastic optical fibers having a core and a cladding, comprising performing a bar of plastic core material and coating the same with a cladding material consisting essentially of a polymer selected from the group consisting of at least one vinylacetate polymer and at least one fluorinated derivative of vinylacetate, and drawing by gravity, the so-coated preform.
Claim 14
Dependent Claim 20 words
A process according to claim 10, wherein said preform is drawn during passage through an oven, without any mechanical contact.
Claim 15
Dependent Claim 35 words
A process according to claim 10, wherein the cladding material is formed by two polymers having different viscosities in order to adapt the resulting viscosity of the cladding material to that of said core material.
Claim 16
Dependent Claim 18 words
A process according to claim 10, wherein the core bar is produced by polymerization followed by heat treatment.
Claim 17
Dependent Claim 29 words
A process according to claim 13, for optical fibers having scintillation or fluorescence properties, wherein prior to polymerization, scintillating or fluorescent doping agents are incorporated into said core material.
Claim 18
Dependent Claim 12 words
A process according to claim 10, wherein said core material is polystyrene.

References Cited (Backward Citations)

US3472921A Cited
US3920313A Cited
US3999834A Cited
JPS5518881A Cited
US4274709A Cited
US4458986A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-11-11 1989-05-13 1989-11-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-11-11 1993-05-13 1993-11-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-11-11 1997-05-13 1997-11-12 $7700.00 Window Closed / Lapsed

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