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Anisotropic heat-curable acrylic terminated monomers

Assignee: CNA Holdings LLC
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Filing: 1985-06-24
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Granted: 1987-07-28
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Expires: 2005-06-24
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Abstract

Abstract A novel heat-curable acrylic-terminated monomer is provided which exhibits an optically anisotropic melt phase at a temperature which enables it to undergo melt processing in the formation of molded articles, etc. Subsequent to melt processing articles prepared from the monomer are capable of being cured to produce a thermoset self-reinforced composite which is soft and flexible relative to prior art monomers. The monomer may, for example, consist essentially of the reaction product of a methacrylic-substituted phenol and terephthalic acid.

Inventors

  • 👤 Robert W. Stackman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 21:01
CPC Classifications
C; C07; C07C; C07C69/00; C07C69/76; C07C69/80; C07C69/82

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 136 words
Heat-curable acrylic-terminated monomer capable of forming an anisotropic melt phase of the formula: ##STR16## wherein Ar is a divalent radical comprising at least one aromatic ring, Ar 1 is a divalent radical selected from the group consisting of phenylene, naphthalene, biphenylene and mixtures thereof, R is selected from the group consisting of an alkylene group having from one to four carbon atoms and an oxyalkylene group having from one to four carbon atoms, and R 1 is selected from the group consisting of hydrogen and methyl, wherein hydrogen atoms present on the aromatic rings in said divalent radicals Ar and Ar 1 may be replaced by substitution selected from the group consisting of an alkyl group having one to four carbon atoms, an alkoxy group having one to four carbon atoms, halogen, phenyl, and mixtures thereof.
Claim 2
Dependent Claim 136 words
Heat-curable acrylic-terminated monomer capable of forming an anisotropic melt phase of the formula: ##STR16## wherein Ar is a divalent radical comprising at least one aromatic ring, Ar 1 is a divalent radical selected from the group consisting of phenylene, naphthalene, biphenylene and mixtures thereof, R is selected from the group consisting of an alkylene group having from one to four carbon atoms and an oxyalkylene group having from one to four carbon atoms, and R 1 is selected from the group consisting of hydrogen and methyl, wherein hydrogen atoms present on the aromatic rings in said divalent radicals Ar and Ar 1 may be replaced by substitution selected from the group consisting of an alkyl group having one to four carbon atoms, an alkoxy group having one to four carbon atoms, halogen, phenyl, and mixtures thereof.
Claim 3
Dependent Claim 17 words
A heat-curable monomer according to claim 1 wherein Ar is selected from the group consisting of ##STR17##
Claim 4
Dependent Claim 11 words
A heat-curable monomer according to claim 1 wherein Ar is ##STR18##
Claim 5
Dependent Claim 11 words
A heat-curable monomer according to claim 1 wherein Ar is ##STR19##
Claim 6
Dependent Claim 11 words
A heat-curable monomer according to claim 1 wherein Ar is ##STR20##
Claim 7
Dependent Claim 11 words
A heat-curable monomer according to claim 1 wherein Ar is ##STR21##
Claim 8
Dependent Claim 11 words
A heat-curable monomer according to claim 1 wherein Ar is ##STR22##
Claim 9
Dependent Claim 11 words
A heat-curable monomer according to claim 1 wherein Ar is ##STR23##
Claim 10
Dependent Claim 12 words
A heat-curable monomer according to claim 1 wherein Ar 1 is ##STR24##
Claim 11
Dependent Claim 11 words
A heat-curable monomer according to claim 1 wherein R is ethylene.
Claim 12
Dependent Claim 11 words
A heat-curable monomer according to claim 1 wherein R is oxyethylene.
Claim 13
Dependent Claim 12 words
A heat-curable monomer according to claim 1 wherein R 1 is hydrogen.
Claim 14
Dependent Claim 12 words
A heat-curable monomer according to claim 1 wherein R 1 is methyl.
Claim 15
Dependent Claim 1 words
Terephthaloyl-bis-methacryloyloxyethylenephenolate.
Claim 16
Dependent Claim 1 words
Terephthaloyl-bis-methacryloyloxyethylenephenolate.
Claim 17
Dependent Claim 1 words
Terephthaloyl-bis-methacryloylethylenephenolate.
Claim 18
Dependent Claim 1 words
Terephthaloyl-bis-methacryloylethylenephenolate.
Claim 19
Dependent Claim 1 words
Terephthaloyl-bis-acryloyloxyethylenephenolate.
Claim 20
Dependent Claim 1 words
Terephthaloyl-bis-acryloyloxyethylenephenolate.
Claim 21
Dependent Claim 1 words
Terephthaloyl-bis-acryloylethylenephenolate.
Claim 22
Dependent Claim 1 words
Terephthaloyl-bis-acryloylethylenephenolate.

References Cited (Backward Citations)

US3336360A Cited
US4068082A Cited
US3770811A Cited
US4144283A Cited
US4283551A Cited
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US4440945A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-07-27 1991-01-26 1991-07-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-07-27 1995-01-26 1995-07-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-07-27 1999-01-26 1999-07-28 $7700.00 Window Closed / Lapsed

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