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Molding compositions for optically readable information-storage media

Assignee: Roehm GmbH Darmstadt
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Filing: 1984-10-16
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Granted: 1987-07-14
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Expires: 2004-10-16
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Abstract

Abstract Copolymers, adaptable for use as molding compositions for optically readable data storage media, said copolymers being free of aromatic groups and comprising; (A) 5 to 95 percent by weight of at least one ester of the formula ##STR1## wherein R 1 is an unsubstituted or alkyl substituted alicycle having from 5 to 19 carbon atoms, a homopolymer of such an ester having a Vicat softening temperature above 80° C.; (B) 90 to 5 percent by weight of at least one ester of the formula ##STR2## wherein R 2 is hydrogen or methyl and R 3 is a linear or branched aliphatic group having from 2 to 22 carbon atoms, a homopolymer of such an ester having a Vicat softening temperature below 90° C.; (C) 0 to 50 percent by weight of methyl methacrylate; and (D) 0 to 20 percent by weight of an oprotic monomer having a polar group.

Inventors

  • 👤 Ralf Liebler
  • 👤 Klaus Albrecht

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 21:33
CPC Classifications
C; C08; C08F; C08F220/00; C08F220/02; C08F220/10; C08F220/12; C08F220/16; C08F220/18; G; G11; G11B; G11B7/00; G11B7/24; G11B7/241; G11B7/252; G11B7/253

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 256 words
A copolymer, adaptable to use as a molding composition for making optically readable data storage media, said copolymer being free of aromatic groups and comprising (A) from 20 to 70 percent by weight of at least one ester of the formula ##STR9## wherein R 1 is derived from an alcohol, R 1 OH, which is cyclohexanol, an alkyl-substituted cyclohexanol wherein each alkyl has up to 12 carbon atoms, a cyclohexylalkanol, or a bicyclic or tricyclic alcohol, with the proviso that a homopolymer of such an ester have a Vicat softening temperature (in conformity with DIN 53460) above 80° C.; (B) from 10 to 60 percent by weight of at least one ester of the formula ##STR10## wherein R 2 is hydrogen or methyl and R 3 is a linear or branched aliphatic group having from 2 to 22 carbon atoms, with the proviso that a homopolymer of such an ester have a Vicat softening temperature (in conformity with DIN 53460) below 90° C.; (C) from 20 to 40 percent by weight of methyl methacrylate; and (D) from 0 to 20 percent of at least one aprotic monomer having a polar group X, of the formula ##STR11## wherein R 4 is hydrogen or methyl and X is --CN or --Y--A--Z, wherein Y is ##STR12## wherein R 5 is alkyl having from 1 to 6 atoms, A is a hydrocarbon chain having from 1 to 8 carbon atoms, and Z is ##STR13## wherein R 6 is (C 1 -C 3 )-alkyl or phenyl, or wherein A--Z is ##STR14##
Claim 2
Dependent Claim 256 words
A copolymer, adaptable to use as a molding composition for making optically readable data storage media, said copolymer being free of aromatic groups and comprising (A) from 20 to 70 percent by weight of at least one ester of the formula ##STR9## wherein R 1 is derived from an alcohol, R 1 OH, which is cyclohexanol, an alkyl-substituted cyclohexanol wherein each alkyl has up to 12 carbon atoms, a cyclohexylalkanol, or a bicyclic or tricyclic alcohol, with the proviso that a homopolymer of such an ester have a Vicat softening temperature (in conformity with DIN 53460) above 80° C.; (B) from 10 to 60 percent by weight of at least one ester of the formula ##STR10## wherein R 2 is hydrogen or methyl and R 3 is a linear or branched aliphatic group having from 2 to 22 carbon atoms, with the proviso that a homopolymer of such an ester have a Vicat softening temperature (in conformity with DIN 53460) below 90° C.; (C) from 20 to 40 percent by weight of methyl methacrylate; and (D) from 0 to 20 percent of at least one aprotic monomer having a polar group X, of the formula ##STR11## wherein R 4 is hydrogen or methyl and X is --CN or --Y--A--Z, wherein Y is ##STR12## wherein R 5 is alkyl having from 1 to 6 atoms, A is a hydrocarbon chain having from 1 to 8 carbon atoms, and Z is ##STR13## wherein R 6 is (C 1 -C 3 )-alkyl or phenyl, or wherein A--Z is ##STR14##
Claim 3
Dependent Claim 14 words
A copolymer as in claim 1 wherein R 1 OH is a terpenoid alcohol.
Claim 4
Dependent Claim 12 words
A copolymer as in claim 2 wherein R 1 OH is isoborneol.
Claim 5
Dependent Claim 18 words
A copolymer as in claim 1 wherein R 1 OH is a tricyclic alcohol of the formula ##STR15##
Claim 6
Dependent Claim 12 words
A copolymer as in claim 1 wherein R 1 OH is 3,3,5-trimethylcyclohexyanol.
Claim 7
Dependent Claim 18 words
A copolymer as in claim 1 wherein R 3 is alkyl having from 2 to 8 carbon atoms.
Claim 8
Dependent Claim 20 words
A copolymer as in claim 6 wherein R 3 is ethyl, propyl, isopropyl, butyl, isobutyl, 3-methylbutyl, neopentyl, 2-ethylbutyl, or 2-ethylhexyl.
Claim 9
Dependent Claim 26 words
A copolymer as in claim 1 wherein said monomers (D) are selected from the group consisting of acrylonitrile, methacrylonitrile, glycidyl methacrylate, chloroethyl acrylate, and chloroethyl methacrylate.
Claim 10
Dependent Claim 22 words
A copolymer as in claim 1 wherein said copolymer has an average molecular weight ranging from 5×10 4 to 3×10 5 .
Claim 11
Dependent Claim 22 words
A copolymer as in claim 1 wherein said copolymer has a Vicat softening temperature (in conformity with DIN 53460) above 80° C.
Claim 12
Dependent Claim 35 words
A copolymer as in claim 1 wherein said copolymer has a modulus of elasticity (in conformity with DIN 53457) greater than 2,500 N/mm 2 and an elongation at rupture (DIN 53455) greater than 2 percent.
Claim 13
Dependent Claim 25 words
A copolymer as in claim 1 wherein the moisture absorption of the copolymer (in conformity with DIN 53495) does not exceed 0.7 percent by weight.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-07-13 1991-01-12 1991-07-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-07-13 1995-01-12 1995-07-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-07-13 1999-01-12 1999-07-14 $7700.00 Window Closed / Lapsed

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