Method for reclaiming heat-damaged catalysts

Claim 1

A method for reclaiming an unbound catalyst that because of heat damage has lost at least 10% of its activity for cracking normal hexane, said catalyst comprising a zeolite having a Constraint Index of 1 to about 12 and a silica-to-alumina ratio of about 20:1 to less than about 500:1, said damaged catalyst being further characterized by a measurable increase in hexane cracking activity when base exchanged at about 80° C. with an ammonium salt followed by conversion to the hydrogen form, said method consisting essentially of: contacting said heat-damaged catalyst with liquid water at a temperature of about 80° C. to about 370° C. for about 1 to 100 hours, said combination of temperature and time being effective to augment said measurable increase in hexane cracking activity by at least about 5 alpha units; and, converting said contacted catalyst to the ammonium form by ion exchange with an ammonium salt at a temperature of about 50° C. to about 100° C.

Claim 9

A method for reclaiming an unbound catalyst that because of heat damage has lost catalytic activity for converting an organic compound, said catalyst comprising a zeolite having a Constraint Index of 1 to about 12 and a silica-to-alumina ratio of about 20:1 to less than about 500:1, which method consists essentially of: contacting said heat-damaged catalyst with liquid water at a temperature of about 80° C. to about 370° C. for about 1 to 100 hours, said combination of temperature and time being effective to augment said catalytic activity; and converting said contacted catalyst to the ammonium form by ion exchange with an ammonium salt at a temperature of about 50° C. to about 100° C. and calcining said ammonium zeolite; and, recovering a catalyst with greater activity for converting said organic compound than is obtained by said contacting step alone or by said conversion to the ammonium form in the absence of said contacting step.