Process for forming solid solutions

Claim 2

A process for forming a solid solution of two or more metals or metal oxides by ionic reaction and simultaneous precipitation from the reaction medium comprising the steps of: a. in a high intensity mixing apparatus, forming a microdispersion of (1) an aqueous liquid solution of the metal ions and (2) at least a stoichiometric amount relative to the dissolved metal ions of a fluid co-reactant which is soluble in the aqueous solvent for the metals to effect liquid phase reactions between the dissolved metal ions and the fluid co-reactant, the rates of which reactions are pH sensitive, and formation in the liquid phase of the metals, the rate of forming the microdispersion being faster than the ionic reactions: b. simultaneously adjusting the pH of the microdispersion as necessary to maintain the reaction between the metal ions and the coreactant at a rate faster than the rate of precipitation of metals from the reaction medium; c. maintaining the microdispersion for a time sufficient to effect simultaneous precipitation of the formed metals or metal oxides and formation of finely divided particles of a single solid solution of the metals having the proportions of the initial metal reactants and dispersion in the reaction medium of the finely divided solid solution particles; d. removing reaction medium containing the dispersed solid solution particles from the mixing apparatus; and e. separating the particles of solid solution of the metals or metal oxides from the removed reaction medium.

Claim 3

The process of claim 1 in which one component of the solid solution is silver metal and in step A, the liquid ionic solution is free of halides and the fluid co-reactant is a reductant and in step B the pH is maintained at a level of at least 11 by the addition of an hydroxide of an alkali or alkaline earth metal.

Claim 4

The process of claim 2 in which the solid solution is an alloy of silver and palladium.

Claim 5

The process of claim 2 in which the reductant is formaldehyde.

Claim 6

The process of claim 1 in which one component of the solid solution is palladium metal and in step A, the reactant fluid is a reductant and in step B, the pH is maintained at a level of at least 11 by the addition of an hydroxide of an alkali or alkaline earth metal.

Claim 7

The process of claim 5 in which the solid solution is an alloy of palladium and copper.

Claim 8

The process of claim 6 in which the reductant is hydrazine.

Claim 9

A process for forming a solid solution of two or more metal oxides by ionic reaction and simultaneous precipitation from the reaction medium comprising the steps of: a. in a high intensity mixing apparatus, forming a microdispersion of (1) an aqueous liquid solution of metal oxide and metal oxide ions and (2) at least a stoichiometric amount relative to the dissolved metal oxide and metal oxide ions of a fluid co-reactant which is soluble in the aqueous solvent for the metal oxides to effect liquid phase reactions between the dissolved metal oxide ions and the fluid co-reactant, the rates of which reactions are pH sensitive, and formation in the liquid phase of the metal oxides, the rate of forming the microdispersion being faster than the ionic reactions; b. simultaneously adjusting the pH of the microdispersion as necessary to maintain the reaction between the metal oxide ions and the coreactant at a rate faster than the rate of precipitation of metal oxides from the reaction medium; c. maintaining the microdispersion for a time sufficient to effect simultaneous precipitation of the formed metal oxides and formation of finely divided particles of a single solid solution of the metal oxides having the proportions of the initial metal oxide reactants and dispersion in the reaction medium of the finely divided solid solution particles; d. removing reaction medium containing the dispersed solid solution particles from the mixing apparatus; and e. separating the particles of solid solution of the metals or metal oxides from the removed reaction medium.

Claim 10

A process for forming a solid solution of two or more metal oxides by ionic reaction and simultaneous precipitation from the reaction medium comprising the steps of: a. in a high intensity mixing apparatus, forming a microdispersion of (1) an aqueous liquid solution of metal oxide and metal oxide ions and (2) at least a stoichiometric amount relative to the dissolved metal oxide and metal oxide ions of a fluid co-reactant which is soluble in the aqueous solvent for the metal oxides to effect liquid phase reactions between the dissolved metal oxide ions and the fluid co-reactant, the rates of which reactions are pH sensitive, and formation in the liquid phase of the metal oxides, the rate of forming the microdispersion being faster than the ionic reactions; b. simultaneously adjusting the pH of the microdispersion as necessary to maintain the reaction between the metal oxide ions and the coreactant at a rate faster than the rate of precipitation of metal oxides from the reaction medium; c. maintaining the microdispersion for a time sufficient to effect simultaneous precipitation of the formed metal oxides and formation of finely divided particles of a single solid solution of the metal oxides having the proportions of the initial metal oxide reactants and dispersion in the reaction medium of the finely divided solid solution particles; d. removing reaction medium containing the dispersed solid solution particles from the mixing apparatus; and e. separating the particles of solid solution of the metals or metal oxides from the removed reaction medium.

Claim 11

The process of claim 8 in which one component of the solid solution is RuO 2 and another component is selected from the group consisting of bismuth oxide, lead oxide and mixtures thereof, and the solid solution is a ruthenate of bismuth, lead or mixtures thereof having a pyrochlore-type structure.

Claim 12

The process of claim 8 in which one component of the solid solution is RuO 2 and another component is selected from the group consisting of copper oxide, bismuth oxide, gadolinium oxide, lead oxide and mixtures thereof, and the solid solution is a ruthenate of bismuth, lead or mixtures thereof having a pyrochlore-type structure.

Claim 13

A process for forming a solid solution of two or more metals or metal oxides by ionic reaction and simultaneous precipitation from the reaction medium comprising the steps of: a. in a high intensity mixing apparatus, forming a microdispersion of (1) an aqueous liquid solution of the metal ions and (2) at least a stoichiometric amount relative to the dissolved metal ions of a fluid co-reactant, which is soluble in the aqueous solvent for the metals, to effect liquid phase reactions between the dissolved metal ions and the fluid co-reactant, the rates of which reactions are pH sensitive, and formation in the liquid phase of the metals or metal oxides, the rate of forming the microdispersion being faster than the ionic reactions; b. simultaneously adjusting the pH of the microdispersion as necessary to maintain the reaction between the metal ions and the coreactant at a rate faster than the rate of precipitation of metals or metal oxides from the reaction medium; c. maintaining the microdispersion for a time sufficient to effect simultaneous precipitation of the formed metals or metal oxides and formation of finely divided particles of a single solid solution of the metals or metal oxides having the proportions of the initial metal or metal oxide reactants and dispersion in the reaction medium of the finely divided solid solution particles; d. removing reaction medium containing the dispersed solid solution particles from the mixing apparatus; and e. separating the particles of solid solution of the metals or metal oxides from the removed reaction medium.

Claim 14

A process for forming a solid solution of two or more metals or metal oxides by ionic reaction and simultaneous precipitation from the reaction medium comprising the steps of: a. in a high intensity mixing apparatus, forming a microdispersion of (1) an aqueous liquid solution of the metal ions and (2) at least a stoichiometric amount relative to the dissolved metal ions of a fluid co-reactant, which is soluble in the aqueous solvent for the metals, to effect liquid phase reactions between the dissolved metal ions and the fluid co-reactant, the rates of which reactions are pH sensitive, and formation in the liquid phase of the metals or metal oxides, the rate of forming the microdispersion being faster than the ionic reactions; b. simultaneously adjusting the pH of the microdispersion as necessary to maintain the reaction between the metal ions and the coreactant at a rate faster than the rate of precipitation of metals or metal oxides from the reaction medium; c. maintaining the microdispersion for a time sufficient to effect simultaneous precipitation of the formed metals or metal oxides and formation of finely divided particles of a single solid solution of the metals or metal oxides having the proportions of the initial metal or metal oxide reactants and dispersion in the reaction medium of the finely divided solid solution particles; d. removing reaction medium containing the dispersed solid solution particles from the mixing apparatus; and e. separating the particles of solid solution of the metals or metal oxides from the removed reaction medium.

Claim 15

The process of claim 11 in which the recovered particles from Step E are heated to at least 300° C. but below the melting point of the solid solution to effect reduction of the surface area of the particles.