Patent US4671894A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4671894A Expired / Lapsed US ⏱️ 0.0 years remaining

Liquid detergent compositions

Assignee: Procter and Gamble Co
•
Filing: 1985-11-04
•
Granted: 1987-06-09
•
Expires: 2005-11-04
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Stable liquid dishwashing detergent compositions are provided incorporating an alkyl benzene sulfonate and/or alkyl sulfate, an alkyl ethoxy sulfate, an ethoxylated C6-C13 alcohol containing an average of from 3 to 12 moles of ethylene oxide and wherein the ethoxylated alcohol contains no more than 1% by weight of unethoxylated alcohol and a zwitterionic surfactant containing a C10-C16 alkyl group.

Inventors

  • 👤 Christopher Lamb
  • 👤 John R. Lawson
  • 👤 Carol Pearson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 10:54
CPC Classifications
C; C11; C11D; C11D1/00; C11D1/88; C11D1/94; C11D1/02; C11D1/12; C11D1/14; C11D1/146; C11D1/22; C11D1/29; C11D1/66; C11D1/72

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 408 words
A physically stable enzyme-free liquid detergent composition consisting essentially of from about 22% to about 65% by weight of a surfactant system composed of a mixture of anionic, nonionic and zwitterionic surfactants in an organic solubiliser/hydrotrope-water medium wherein (i) the anionic surfactant comprises in combination (a) from about 4% to about 20% by weight of the composition of a primary C 10 -C 16 alkyl sulfate; (b) from about 5% to about 20% by weight of the composition of a C 10 -C 16 linear alkyl benzene sulfonate; (c) from about 5% to about 24% by weight of the composition of a C 10 -C 16 alkyl ethoxysulfate containing an average of up to about 6 moles of ethylene oxide per mole of ethoxysulfate; wherein, in said anionic surfactant combination, the cations include magnesium ion in a molar amount corresponding to from about 35% to about 65% of the molar amount of alkyl sulfate present in the combination; (ii) the nonionic surfactant comprises from about 1% to about 10% by weight of the composition of an ethoxylated C 6 -C 13 aliphatic alcohol containing an average of from about 1.5 to about 25 moles of ethylene oxide per mole of alcohol, said ethoxylated alcohol containing not more than about 1% by weight of unethoxylated alcohol where the alcohol contains an average of less than about 9 moles of ethylene oxide and not more than about 2% by weight of unethoxylated alcohol where the ethoxylated alcohol containing an average of from about 9 to about 25 moles of ethylene oxide per mole of alcohol; (iii) the zwitterionic surfactant comprises from about 0.25% to about 10% by weight of the composition of a compound of the general formula ##STR7## wherein R 1 is C 10 -C 16 alkyl R 2 is C 1 -C 3 alkyl R 3 is a `(CH 2 ) 3 group or a ##STR8## Y is ##STR9## n and m are O or 1 X - is CH 2 COO - or SO 3 - ; provided that where X - is CH 2 COO - , m is O and where X - is SO 3 - , m is 1, and wherein said organic solubilizer/hydrotrope-water medium is the balance of the formula and said organic solubilizer/hydrotrope is selected from the group consisting of urea, a C 1 -C 3 aliphatic alcohol, a lower alkyl or dialkyl benzene sulfonate salt, and mixtures of the above.
Claim 2
Dependent Claim 408 words
A physically stable enzyme-free liquid detergent composition consisting essentially of from about 22% to about 65% by weight of a surfactant system composed of a mixture of anionic, nonionic and zwitterionic surfactants in an organic solubiliser/hydrotrope-water medium wherein (i) the anionic surfactant comprises in combination (a) from about 4% to about 20% by weight of the composition of a primary C 10 -C 16 alkyl sulfate; (b) from about 5% to about 20% by weight of the composition of a C 10 -C 16 linear alkyl benzene sulfonate; (c) from about 5% to about 24% by weight of the composition of a C 10 -C 16 alkyl ethoxysulfate containing an average of up to about 6 moles of ethylene oxide per mole of ethoxysulfate; wherein, in said anionic surfactant combination, the cations include magnesium ion in a molar amount corresponding to from about 35% to about 65% of the molar amount of alkyl sulfate present in the combination; (ii) the nonionic surfactant comprises from about 1% to about 10% by weight of the composition of an ethoxylated C 6 -C 13 aliphatic alcohol containing an average of from about 1.5 to about 25 moles of ethylene oxide per mole of alcohol, said ethoxylated alcohol containing not more than about 1% by weight of unethoxylated alcohol where the alcohol contains an average of less than about 9 moles of ethylene oxide and not more than about 2% by weight of unethoxylated alcohol where the ethoxylated alcohol containing an average of from about 9 to about 25 moles of ethylene oxide per mole of alcohol; (iii) the zwitterionic surfactant comprises from about 0.25% to about 10% by weight of the composition of a compound of the general formula ##STR7## wherein R 1 is C 10 -C 16 alkyl R 2 is C 1 -C 3 alkyl R 3 is a `(CH 2 ) 3 group or a ##STR8## Y is ##STR9## n and m are O or 1 X - is CH 2 COO - or SO 3 - ; provided that where X - is CH 2 COO - , m is O and where X - is SO 3 - , m is 1, and wherein said organic solubilizer/hydrotrope-water medium is the balance of the formula and said organic solubilizer/hydrotrope is selected from the group consisting of urea, a C 1 -C 3 aliphatic alcohol, a lower alkyl or dialkyl benzene sulfonate salt, and mixtures of the above.
Claim 3
Dependent Claim 100 words
A detergent composition according to claim 1 wherein the anionic surfactant combination comprises from about 6% to about 12% of a C 12 -C 14 alkyl sulfate, from about 5% to about 15% of a C 11 -C 13 alkyl benzene sulfonate and from about 6% to about 1% of a C 12 -C 14 alkyl ethoxysulfate containing an average of not more than about 2 ethoxy groups per mole of ethoxy sulfate, the cations in said combination including magnesium ion in a molar amount corresponding to approximately 50% of the molar amount of alkyl sulfate present in the combination.
Claim 4
Dependent Claim 61 words
A detergent composition according to claim 2 wherein the alkyl sulfate and alkyl ethoxysulfate components are provided by a single alkyl ethoxysulfate stock containing an average of from about 0.8 to about 2.0 ethoxy groups per mole of alkyl ethoxy sulfate, said single stock being present in an amount of from about 10% to about 25% by weight of the composition.
Claim 5
Dependent Claim 60 words
A detergent composition according to claim 3 wherein the anionic surfactant combination comprises from about 5% to about 10% by weight of a C 11 -C 13 linear alkyl benzene sulfonate and from about 15% to about 20% by weight of C 12 -C 14 linear alkyl ethoxy sulfate containing approximately 0.8 ethoxy groups per mole of alkyl ethoxy sulfate.
Claim 6
Dependent Claim 21 words
A detergent composition according to claim 1 wherein the nonionic surfactant has an HLB in the range from 8.0 to 17.0.
Claim 7
Dependent Claim 44 words
A detergent composition according to claim 5 wherein the nonionic surfactant comprises from about 2% to about 6% of a linear C 9 -C 11 alcohol containing an average of from about 6 to about 10 moles of ethylene oxide per mole of alcohol.
Claim 8
Dependent Claim 35 words
A detergent composition according to claim 6 wherein the zwitterionic surfactant is 1(N, N dimethyl N-C 12 -C 14 alkyl ammonio) methane-1-carboxy and comprises from about 1% to about 5% by weight of the composition.

References Cited (Backward Citations)

DE2361080A1 Cited
GB1524441A Cited
GB1551074A Cited
JPS5238508A Cited
GB2010893A Cited
EP0039110A1 Cited
US4435317A Cited
US4329334A Cited
US4544495A Cited
US4554098A Cited
US4595529A Cited
US4555360A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-06-08 1990-12-08 1991-06-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-06-08 1994-12-08 1995-06-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-06-08 1998-12-08 1999-06-09 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag