Poly(ethynylphenyl)acetylene, its copolymer and composition thereof

Claim 2

A process for preparing a linear polymer having a recurring unit represented by the formula (I): ##STR157## wherein R 1 , R 2 , R 3 and R 4 each independently is a hydrogen atom, a C 1-10 alkyl group, a C 6-10 cycloalkyl group, an aryl group, or a halogen atom and the ethynyl group is in either meta position or para position to the main polymer chain; and a weight-average molecular weight of 1,000 to 1,000,000 which comprises polymerizing a monomer represented by the formula (III): ##STR158## wherein R 1 , R 2 , R 3 and R 4 each independently is a hydrogen atom, a C 1-10 alkyl group, a C 6-10 cycloalkyl group, an aryl group, or a halogen atom and the ethynyl group is in either meta position or para position to the other ethynyl group; in the presence of a catalyst.

Claim 3

The process according to claim 1, wherein the catalyst is a metal carbene compound and the metal is selected from the group consiting of molybdenum, tungsten, niobium and tantalum.

Claim 4

The process according to claim 2, wherein the carbene compound has the formula (V): ##STR159## wherein M is tungsten and molybdenum, R 5 is a C 1-10 alkoxy group or a C 6-10 aryl group, and R 6 is a C 1-10 alkyl group, a C 3-10 cycloalkyl group, a C 6-10 aryl group, or a hydrogen atom.

Claim 5

The process according to claim 2, wherein the carbene compound is a compound obtained by reacting tungsten hexachloride or molybdenum pentachloride with monosubstituted acetylene represented by the formula (VI): A.sub.1 --C.tbd.C--H (VI) wherein A 1 is a C 1-10 alkyl group, a C 6-14 aryl group, a C 3-10 is cycloalkyl group or a silyl group having a C 1-10 alkyl group, or a C 6-10 aryl group.

Claim 6

The process according to claim 2, wherein the carbene compound is a compound obtained by reacting niobium pentachloride or tantalum pentachloride with disubstituted acetylene represented by the formula (VII): A.sub.2 --C.tbd.C--A.sub.3 (VII) wherein A 2 and A 3 each independently is a chlorine atom, a C 1-10 alkyl group, a C 6-10 aryl group, a C 3-10 cycloalkyl group or a silyl group having a C 1-10 alkyl group, or a C 6-10 aryl group.

Claim 7

A process for preparing a linear copolymer having a weight-average molecular weight of 1,000 to 1,000,000 consisting of a recurring unit represented by the formula (I) and a recurring unit represented by the formula (II): ##STR160## wherein R 1 , R 2 , R 3 and R 4 each independently is a hydrogen atom, a C 1-10 alkyl group, a C 6-10 cycloalkyl group, a C 6-10 aryl group, or a halogen atom, X and Y each independently is a C 6-20 aryl group, a C 1-10 alkyl group, a C 6-10 cycloalkyl group, a silyl group having a C 1-10 alkyl group or a C 6-10 aryl group, a hydrogen atom or a halogen atom, and the ethynyl group of the unit (I) is in either meta position or para position to the main polymer chain; and the weight ratio of the unit (I) to the unit (II) ranges from 1/99 to 99.5/0.5 which comprises reacting a monomer represented by the formula (III): ##STR161## wherein R 1 , R 2 , R 3 and R 4 each independently is a hydrogen atom, a C 1-10 alkyl group, a C 6-10 cycloalkyl group, an aryl group, or a halogen atom and the ethynyl group is in either meta position or para position to the other ethynyl group; with a monomer represented by the formula (IV): X--C.tbd.C--Y (IV) wherein X and Y each independently is a C 6-20 aryl group, a C 1-10 alkyl group, a C 6-10 cycloalkyl group, a silyl group having a C 1-10 alkyl group, or a C 6-10 aryl group, a hydrogen atom or a halogen atom; in the presence of a catalyst.

Claim 8

A process for preparing a linear copolymer having a weight-average molecular weight of 1,000 to 1,000,000 consisting of a recurring unit represented by the formula (I) and a recurring unit represented by the formula (II): ##STR160## wherein R 1 , R 2 , R 3 and R 4 each independently is a hydrogen atom, a C 1-10 alkyl group, a C 6-10 cycloalkyl group, a C 6-10 aryl group, or a halogen atom, X and Y each independently is a C 6-20 aryl group, a C 1-10 alkyl group, a C 6-10 cycloalkyl group, a silyl group having a C 1-10 alkyl group or a C 6-10 aryl group, a hydrogen atom or a halogen atom, and the ethynyl group of the unit (I) is in either meta position or para position to the main polymer chain; and the weight ratio of the unit (I) to the unit (II) ranges from 1/99 to 99.5/0.5 which comprises reacting a monomer represented by the formula (III): ##STR161## wherein R 1 , R 2 , R 3 and R 4 each independently is a hydrogen atom, a C 1-10 alkyl group, a C 6-10 cycloalkyl group, an aryl group, or a halogen atom and the ethynyl group is in either meta position or para position to the other ethynyl group; with a monomer represented by the formula (IV): X--C.tbd.C--Y (IV) wherein X and Y each independently is a C 6-20 aryl group, a C 1-10 alkyl group, a C 6-10 cycloalkyl group, a silyl group having a C 1-10 alkyl group, or a C 6-10 aryl group, a hydrogen atom or a halogen atom; in the presence of a catalyst.

Claim 9

The process according to claim 6, wherein the catalyst is a metal carbene compound and the metal is selected from the group consisting of molybdenum, tungsten, niobium, and tantalum.

Claim 10

The process according to claim 7, wherein the carbene compound has the formula (V): ##STR162## wherein M is tungsten and molybdenum, R 5 is a C 1-10 alkoxy group or a C 6-10 aryl group, and R 6 is a C 1-10 alkyl group, a C 3-10 cycloalkyl group, a C 6-10 aryl group, or a hydrogen atom.

Claim 11

The process according to claim 7, wherein the carbene compound is a compound obtained by reacting tungsten hexachloride or molybdenum pentachloride with monosubstituted acetylene represented by the formula (VI): A.sub.1 --C.tbd.C--H (VI) wherein A 1 is a C 1-10 alkyl group, a C 6-14 aryl group, a C 3-10 cycloalkyl group, or a silyl group having a C 1-10 alkyl group or a C 6-10 aryl group.

Claim 12

The process according to claim 7, wherein the carbene compound is a compound obtained by reacting niobium pentachloride or tantalum pentachloride with disubstituted acetylene represented by the formula (VII): A.sub.2 --C.tbd.C--A.sub.3 (VII) wherein A 2 and A 3 each independently is a chlorine atom, a C 1-10 alkyl group, a C 6-10 aryl group, a C 3-10 cycloalkyl group, or a silyl group having a C 1-10 alkyl group or a C 6-10 aryl group.