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US4666870A Expired / Lapsed US ⏱️ 0.0 years remaining

Fluoride glasses

Assignee: LE VERRE FLUORE SA ZONE I DU CHAMP MARTIN VERN-SUR-SEICHE
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Filing: 1986-07-08
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Granted: 1987-05-19
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Expires: 2006-07-08
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Abstract

Abstract The invention relates to a beryllium free fluoride glass composition used to prepare fluoride glass and the fluoride glass prepared by the composition. The fluoride composition contains only fluoride compounds and does not contain any oxygen atoms.

Inventors

  • 👤 Marcel J. Poulain
  • 👤 Michel A. Poulain
  • 👤 Gwenael A. Maze

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 21:19
CPC Classifications
C; C03; C03C; C03C3/00; C03C3/32; C03C3/325

Claims Analysis

Total Claims: 46
Claim 1
Independent Claim 41 words
A fluoride glass composition for preparing fluoride glass consisting of: 10-60% LiF 10-20% NaF 0-50% UF 4 , 0-25% ThF 4 , 0-25% BaF, 0-40% ScF 3 , 0-8% YF 3 ; and wherein all the above percentages are mole percent.
Claim 2
Dependent Claim 41 words
A fluoride glass composition for preparing fluoride glass consisting of: 10-60% LiF 10-20% NaF 0-50% UF 4 , 0-25% ThF 4 , 0-25% BaF, 0-40% ScF 3 , 0-8% YF 3 ; and wherein all the above percentages are mole percent.
Claim 3
Dependent Claim 15 words
The composition of claim 1 consisting of: 60% LiF, 10% NaF, 30% UF 4 .
Claim 4
Dependent Claim 15 words
The composition of claim 1 consisting of: 60% LiF, 15% NaF, 25% ThF 4 .
Claim 5
Dependent Claim 14 words
The composition of claim 1 consisting: 30% LiF, 20% NaF, 50% UF 4 .
Claim 6
Dependent Claim 23 words
The composition of claim 1 consisting of: 10% LiF, 17% NaF, 25% BaF 2 , 40% ScF 3 , 8% YF 3 .
Claim 7
Dependent Claim 41 words
A fluoride glass composition for preparing fluoride glass consisting of: 30-50% UF 4 , 0-30% AlF 3 , 0-20% LaF 3 , 0-20% YF 3 , 0-30% ThF 4 , 0-25% NaF and wherein all the above percentages are mole percent.
Claim 8
Dependent Claim 41 words
A fluoride glass composition for preparing fluoride glass consisting of: 30-50% UF 4 , 0-30% AlF 3 , 0-20% LaF 3 , 0-20% YF 3 , 0-30% ThF 4 , 0-25% NaF and wherein all the above percentages are mole percent.
Claim 9
Dependent Claim 19 words
The composition of claim 6 consisting of: 50% UF 4 , 30% AlF 3 , 20% LaF 3 .
Claim 10
Dependent Claim 23 words
The composition of claim 6 consisting of: 30% UF 4 , 20% AlF 3 , 20% YF 3 , 30% ThF 4 .
Claim 11
Dependent Claim 19 words
The composition of claim 6 consisting of: 50% UF 4 , 20% AlF 3 , 30% YF 3 .
Claim 12
Dependent Claim 17 words
The composition of claim 6 consisting of: 50% UF 4 , 25% AlF 3 , 25% NaF.
Claim 13
Dependent Claim 67 words
A fluoride glass composition for preparing fluoride glass consisting of: 20-30% YF 3 , 25-30% AlF 3 , 20-24% BaF 2 , 0-13% MgF 2 , 0-2% CaF 2 , 0-2% KF, 0-2% CeF 3 , 0-25% NaF, 0-30% YbF 3 , 0-20% CeF 4 , 0-20% PbF 4 , 0-20% NbF 4 , 0-20% ThF 4 ; and wherein all the above percentages are mole percent.
Claim 14
Dependent Claim 67 words
A fluoride glass composition for preparing fluoride glass consisting of: 20-30% YF 3 , 25-30% AlF 3 , 20-24% BaF 2 , 0-13% MgF 2 , 0-2% CaF 2 , 0-2% KF, 0-2% CeF 3 , 0-25% NaF, 0-30% YbF 3 , 0-20% CeF 4 , 0-20% PbF 4 , 0-20% NbF 4 , 0-20% ThF 4 ; and wherein all the above percentages are mole percent.
Claim 15
Dependent Claim 23 words
The composition of claim 11 consisting of: 28% YF 3 , 28% AlF 3 , 24% BaF 2 , 20% ThF 4 .
Claim 16
Dependent Claim 21 words
The composition of claim 11 consisting of: 30% YF 3 , 30% AlF 3 , 20% BaF 2 , 20% NaF.
Claim 17
Dependent Claim 31 words
The composition of claim 11 consisting of: 26% YF 3 , 28% AlF 3 , 20% BaF 2 , 15% MgF 2 , 5% NaF, 2% CaF 2 , 2% KF.
Claim 18
Dependent Claim 29 words
The composition of claim 11 consisting of: 30% YF 3 , 30% AlF 3 , 20% BaF 2 , 2% CaF 2 , 5% NaF, 13% MgF 2 .
Claim 19
Dependent Claim 29 words
The composition of claim 11 consisting of: 20% BaF 2 , 20% YF 3 , 25% AlF 3 , 10% ThF 4 , 5% NaF, 20% CeF 4 .
Claim 20
Dependent Claim 29 words
The composition of claim 11 consisting of: 20% BaF 2 , 20% YF 3 , 25% AlF 3 , 10% ThF 4 , 5% NaF, 20% PbF 4 .
Claim 21
Dependent Claim 29 words
The composition of claim 11 consisting of: 20% BaF 2 , 20% YF 3 , 25% AlF 3 , 10% ThF 4 , 5% NaF, 20% NbF 4 .
Claim 22
Dependent Claim 61 words
A fluoride glass composition for preparing fluoride glass consisting of: 5-20% NaF, 5-15% MgF 2 , 20% BaF 2 , 0-50% UF 4 , 0-30% AlF 3 , 0-30% ErF 3 , 0-20% SnF 3 , 0-20% YF 3 , 0-20% TbF 3 , 0-10% GaF 3 , 0-30% InF 3 ; and wherein all the above percentages are mole percent.
Claim 23
Dependent Claim 61 words
A fluoride glass composition for preparing fluoride glass consisting of: 5-20% NaF, 5-15% MgF 2 , 20% BaF 2 , 0-50% UF 4 , 0-30% AlF 3 , 0-30% ErF 3 , 0-20% SnF 3 , 0-20% YF 3 , 0-20% TbF 3 , 0-10% GaF 3 , 0-30% InF 3 ; and wherein all the above percentages are mole percent.
Claim 24
Dependent Claim 21 words
The composition of claim 19 consisting of: 20% NaF, 10% MgF 2 , 20% BaF 2 , 50% UF 4 .
Claim 25
Dependent Claim 25 words
The composition of claim 19 consisting of: 5% NaF, 15% MgF 2 , 20% BaF 2 , 30% AlF 3 , 30% ErF 3 .
Claim 26
Dependent Claim 25 words
The composition of claim 19 consisting of: 5% NaF, 15% MgF 2 , 20% BaF 2 , 30% AlF 3 , 30% YbF 3 .
Claim 27
Dependent Claim 29 words
The composition of claim 19 consisting of: 25% NaF, 5% MgF 2 , 20% BaF 2 , 20% YF 3 , 20% TbF 3 , 10% GaF 3 .
Claim 28
Dependent Claim 25 words
The composition of claim 19 consisting of: 15% NaF, 15% MgF 2 , 20% BaF 2 , 30% AlF 3 , 20% SnF 3 .
Claim 29
Dependent Claim 29 words
The composition of claim 19 consisting of: 20% NaF, 10% MgF 2 , 20% BaF 2 , 10% CaF 2 , 20% YF 3 , 30% InF 3 .
Claim 30
Dependent Claim 27 words
A fluoride glass composition for preparing fluoride glass consisting of: 60% LiF, 35% KF, 5% ThF 4 ; and wherein all the above percentages are mole percent.
Claim 31
Dependent Claim 27 words
A fluoride glass composition for preparing fluoride glass consisting of: 60% LiF, 35% KF, 5% ThF 4 ; and wherein all the above percentages are mole percent.
Claim 32
Dependent Claim 29 words
A fluoride glass composition for preparing fluoride glass consisting of: 45% LiF, 20% BaF 2 , 35% ZrF 4 ; and wherein all the above percentages are mole percent.
Claim 33
Dependent Claim 29 words
A fluoride glass composition for preparing fluoride glass consisting of: 45% LiF, 20% BaF 2 , 35% ZrF 4 ; and wherein all the above percentages are mole percent.
Claim 34
Dependent Claim 33 words
A fluoride glass composition for preparing fluoride glass consisting of: 20% NaF, 10% MgF 2 , 20% YF 3 , 50% UF 4 ; and wherein all the above percentages are mole percent.
Claim 35
Dependent Claim 33 words
A fluoride glass composition for preparing fluoride glass consisting of: 20% NaF, 10% MgF 2 , 20% YF 3 , 50% UF 4 ; and wherein all the above percentages are mole percent.
Claim 36
Dependent Claim 37 words
A fluoride glass composition for preparing fluoride glass consisting of: 15% NaF, 20% BaF 2 , 30% ScF 3 , 20% YF 3 , 15% ThF 4 ; and wherein all the above percentages are mole percent.
Claim 37
Dependent Claim 37 words
A fluoride glass composition for preparing fluoride glass consisting of: 15% NaF, 20% BaF 2 , 30% ScF 3 , 20% YF 3 , 15% ThF 4 ; and wherein all the above percentages are mole percent.
Claim 38
Dependent Claim 47 words
A fluoride glass composition for preparing fluoride glass consisting of: 5% NaF, 2% KF, 15% MgF 2 , 2% CaF 2 , 20% BaF 2 , 28% AlF 3 , 2% CeF 3 , 26% YbF 3 ; and wherein all the above percentages are mole percent.
Claim 39
Dependent Claim 47 words
A fluoride glass composition for preparing fluoride glass consisting of: 5% NaF, 2% KF, 15% MgF 2 , 2% CaF 2 , 20% BaF 2 , 28% AlF 3 , 2% CeF 3 , 26% YbF 3 ; and wherein all the above percentages are mole percent.
Claim 40
Dependent Claim 29 words
A fluoride glass composition for preparing fluoride glass consisting of: 25% NaF, 25% BaF 2 , 50% TiF 4 ; and wherein all the above percentages are mole percent.
Claim 41
Dependent Claim 29 words
A fluoride glass composition for preparing fluoride glass consisting of: 25% NaF, 25% BaF 2 , 50% TiF 4 ; and wherein all the above percentages are mole percent.
Claim 42
Dependent Claim 10 words
A fluoride glass prepared from the composition of claim 1.
Claim 43
Dependent Claim 10 words
A fluoride glass prepared from the composition of claim 6.
Claim 44
Dependent Claim 10 words
A fluoride glass prepared from the composition of claim 11.
Claim 45
Dependent Claim 10 words
A fluoride glass prepared from the composition of claim 19.
Claim 46
Dependent Claim 10 words
A fluoride glass prepared from the composition of claim 26.

References Cited (Backward Citations)

US2511224A Cited
US2466509A Cited
US2819977A Cited
FR2077731A1 Cited
US4141741A Cited
FR2396981A1 Cited
US4244722A Cited
US4328318A Cited
US4308066A Cited
US4346176A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-05-18 1990-11-17 1991-05-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-05-18 1994-11-17 1995-05-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-05-18 1998-11-17 1999-05-19 $7700.00 Window Closed / Lapsed

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