Recovery of sulfur from a solid sulfur-containing solution of solubilized iron chelate of nitrilotriacetic acid

Claim 2

A process for recovering sulfur from a solid sulfur-containing solution of solubilized iron chelate of nitrilotriacetic acid comprising (a) introducing said solid sulfur-containing solution into an at least substantially oxygen-free zone containing an upper phase comprising a substantially sulfur-free solution of solubilized iron chelates of nitrilotriacetic acid, and a lower phase comprising molten sulfur, the temperature of the zone being maintained at a temperature sufficient to melt the sulfur added, and allowing the solid sulfur added to melt and become part of the lower phase; and (b) recovering molten sulfur from the lower phase.

Claim 3

The process of claim 1 wherein the solid sulfur-containing solution contains from 2 to 30 percent by weight of sulfur, based on the weight of the solution and the sulfur.

Claim 4

A process for recovering sulfur from a solid sulfur-containing solution of a solubilized iron chelate of nitrilotriacetic acid comprising (a) heating the sulfur-containing solution, in an at least substantially oxygen-free environment, to a temperature sufficient to melt the sulfur, and producing a solution of said solubilized iron chelate of nitrilotriacetic acid containing molten sulfur; (b) separating molten sulfur-containing solution from step (a) in a separation zone maintained at a temperature at or above the melting point of sulfur and having an at least substantially oxygen-free environment into an upper phase containing substantially sulfur-free solution of solubilized iron chelates of nitrilotriacetic acid and a lower phase admixture comprising molten sulfur; and (c) recovering molten sulfur from the separation zone.

Claim 5

A process for recovering sulfur from a solid sulfur-containing solution of a solubilized iron chelate of nitrilotriacetic acid comprising (a) heating the sulfur-containing solution, in an at least substantially oxygen-free environment, to a temperature sufficient to melt the sulfur, and producing a solution of said solubilized iron chelate of nitrilotriacetic acid containing molten sulfur; (b) separating molten sulfur-containing solution from step (a) in a separation zone maintained at a temperature at or above the melting point of sulfur and having an at least substantially oxygen-free environment into an upper phase containing substantially sulfur-free solution of solubilized iron chelates of nitrilotriacetic acid and a lower phase admixture comprising molten sulfur; and (c) recovering molten sulfur from the separation zone.

Claim 6

A process for recovering sulfur from a solid sulfur-containing solution of a solubilized iron chelate of nitrilotriacetic acid comprising (a) heating the sulfur-containing solution, in an at least substantially oxygen-free environment, to a temperature sufficient to melt the sulfur, and producing a solution of said solubilized iron chelate of nitrilotriacetic acid containing molten sulfur; (b) separating molten sulfur-containing solution from step (a) in a separation zone maintained at a temperature at or above the melting point of sulfur and having an at least substantially oxygen-free environment into an upper phase containing substantially sulfur-free solution of solubilized iron chelates of nitrilotriacetic acid and a lower phase comprising molten sulfur; and (c) filtering sulfur from step (b) to produce substantially pure molten sulfur.

Claim 7

A process for recovering sulfur from a solid sulfur-containing solution of a solubilized iron chelate of nitrilotriacetic acid comprising (a) heating the sulfur-containing solution, in an at least substantially oxygen-free environment, to a temperature sufficient to melt the sulfur, and producing a solution of said solubilized iron chelate of nitrilotriacetic acid containing molten sulfur; (b) separating molten sulfur-containing solution from step (a) in a separation zone maintained at a temperature at or above the melting point of sulfur and having an at least substantially oxygen-free environment into an upper phase containing substantially sulfur-free solution of solubilized iron chelates of nitrilotriacetic acid and a lower phase comprising molten sulfur; and (c) filtering sulfur from step (b) to produce substantially pure molten sulfur.

Claim 8

A process for the removal of H 2 S from a sour gaseous stream employing an aqueous reactant solution containing solubilized degradable iron chelates comprising (a) contacting the sour gaseous stream with aqueous reactant solution in a contacting zone at a temperature below the melting point of sulfur, the reactant solution containing solubilized ferric chelate of nitrilotriacetic acid, under conditions to convert H 2 S, producing a gaseous stream having reduced H 2 S content, and aqueous admixture containing solid sulfur and an increased concentration of solubilized ferrous chelate of nitrilotriacetic acid, and ratio of the solubilized ferric chelate of nitrilotriacetic acid to ferrous chelate in said reactant solution being from 0.2 to 6; (b) removing aqueous admixture from the contacting zone and separating a minor portion of said admixture having an increased solid sulfur concentration, and introducing admixture having an increased sulfur concentration into an at least substantially oxygen-free zone containing an upper phase comprising a substantially sulfur-free solution of solubilized iron chelates of nitrilotriacetic acid, and a lower phase comprising molten sulfur, the temperature of the zone being maintained at a temperature sufficient to melt the sulfur added, and allowing the solid sulfur added to melt and become part of the lower phase; (c) recovering molten sulfur from the lower phase; (d) regenerating the major portion of said admixture by contacting admixture to be regenerated with oxygen in a regeneration zone under conditions to convert solubilized ferrous chelate of nitrilotriacetic acid in the admixture to the solubilized ferric chelate of nitrilotriacetic acid, and producing regenerated aqueous reactant solution having a ratio of solubilized ferric chelate of nitrilotriacetic acid to solubilized ferrous chelate of nitrilotriacetic acid of from 0.5 to 6; and (e) passing regenerated aqueous reactant solution from step (d) to the contacting zone for use as aqueous reactant solution therein.

Claim 9

A process for the removal of H 2 S from a sour gaseous stream employing an aqueous reactant solution containing solubilized degradable iron chelates comprising (a) contacting the sour gaseous stream with aqueous reactant solution in a contacting zone at a temperature below the melting point of sulfur, the reactant solution containing solubilized ferric chelate of nitrilotriacetic acid, under conditions to convert H 2 S, producing a gaseous stream having reduced H 2 S content, and aqueous admixture containing solid sulfur and an increased concentration of solubilized ferrous chelate of nitrilotriacetic acid, and ratio of the solubilized ferric chelate of nitrilotriacetic acid to ferrous chelate in said reactant solution being from 0.2 to 6; (b) removing aqueous admixture from the contacting zone and separating a minor portion of said admixture having an increased solid sulfur concentration, and introducing admixture having an increased sulfur concentration into an at least substantially oxygen-free zone containing an upper phase comprising a substantially sulfur-free solution of solubilized iron chelates of nitrilotriacetic acid, and a lower phase comprising molten sulfur, the temperature of the zone being maintained at a temperature sufficient to melt the sulfur added, and allowing the solid sulfur added to melt and become part of the lower phase; (c) recovering molten sulfur from the lower phase; (d) regenerating the major portion of said admixture by contacting admixture to be regenerated with oxygen in a regeneration zone under conditions to convert solubilized ferrous chelate of nitrilotriacetic acid in the admixture to the solubilized ferric chelate of nitrilotriacetic acid, and producing regenerated aqueous reactant solution having a ratio of solubilized ferric chelate of nitrilotriacetic acid to solubilized ferrous chelate of nitrilotriacetic acid of from 0.5 to 6; and (e) passing regenerated aqueous reactant solution from step (d) to the contacting zone for use as aqueous reactant solution therein.

Claim 10

A process for the removal of the H 2 S from a sour gaseous stream employing an aqueous reactant solution containing solubilized degradable iron chelates comprising (a) contacting the sour gaseous stream with aqueous reactant solution in a contacting zone at a temperature below the melting point of sulfur, the reactant solution containing solubilized ferric chelate of nitrilotriacetic acid, and solubilized ferrous chelate of nitrilotriacetic acid, under conditions to convert H 2 S, producing a gaseous stream having a reduced H 2 S content, and aqueous admixture containing solid sulfur and an increased concentration of solubilized ferrous chelate of nitrilotriacetic acid, the ratio of the solubilized ferric chelate of nitrilotriacetic acid to solubilized ferrous chelate of nitrilotriacetic acid in said reactant solution being from 0.2 to 6; (b) removing aqueous admixture from the contacting zone and regenerating admixture by contacting admixture to be regenerated with oxygen in a regeneration zone under conditions to convert solubilized ferrous chelate of nitrilotriacetic acid in the admixture to the solubilized ferric chelate of nitrilotriacetic acid, and producing regenerated reactant solution containing solid sulfur having a ratio of solubilized ferric chelate of nitrilotriacetic acid to solubilized ferrous chelate of nitrilotriacetic acid of from 0.5 to 6; (c) separating a minor portion of said regenerated reactant mixture having an increased solid sulfur concentration, and introducing admixture having an increased solid sulfur concentration into an at least substantially oxygen-free zone containing an upper phase comprising a substantially sulfur-free solution of solubilized iron chelates of nitrilotriacetic acid, and a lower phase comprising molten sulfur, the temperature of the zone being maintained at a temperature sufficient to melt the sulfur added, and allowing the solid sulfur added to melt and become part of the lower phase; (d) recovering molten sulfur from the lower phase; and (e) passing regenerated aqueous reactant solution from step (c) to the contacting zone for use as aqueous reactant solution therein.

Claim 11

A process for the removal of the H 2 S from a sour gaseous stream employing an aqueous reactant solution containing solubilized degradable iron chelates comprising (a) contacting the sour gaseous stream with aqueous reactant solution in a contacting zone at a temperature below the melting point of sulfur, the reactant solution containing solubilized ferric chelate of nitrilotriacetic acid, and solubilized ferrous chelate of nitrilotriacetic acid, under conditions to convert H 2 S, producing a gaseous stream having a reduced H 2 S content, and aqueous admixture containing solid sulfur and an increased concentration of solubilized ferrous chelate of nitrilotriacetic acid, the ratio of the solubilized ferric chelate of nitrilotriacetic acid to solubilized ferrous chelate of nitrilotriacetic acid in said reactant solution being from 0.2 to 6; (b) removing aqueous admixture from the contacting zone and regenerating admixture by contacting admixture to be regenerated with oxygen in a regeneration zone under conditions to convert solubilized ferrous chelate of nitrilotriacetic acid in the admixture to the solubilized ferric chelate of nitrilotriacetic acid, and producing regenerated reactant solution containing solid sulfur having a ratio of solubilized ferric chelate of nitrilotriacetic acid to solubilized ferrous chelate of nitrilotriacetic acid of from 0.5 to 6; (c) separating a minor portion of said regenerated reactant mixture having an increased solid sulfur concentration, and introducing admixture having an increased solid sulfur concentration into an at least substantially oxygen-free zone containing an upper phase comprising a substantially sulfur-free solution of solubilized iron chelates of nitrilotriacetic acid, and a lower phase comprising molten sulfur, the temperature of the zone being maintained at a temperature sufficient to melt the sulfur added, and allowing the solid sulfur added to melt and become part of the lower phase; (d) recovering molten sulfur from the lower phase; and (e) passing regenerated aqueous reactant solution from step (c) to the contacting zone for use as aqueous reactant solution therein.

Claim 12

A process for the removal of H 2 S from a sour gaseous stream employing an aqueous reactant solution containing solubilized degradable iron chelates comprising (a) contacing the sour gaseous stream with aqueous reactant solution in a contacting zone at a temperature below the melting point of sulfur, the reactant solution containing solubilized ferric chelate of nitrilotriacetic acid, under conditions to convert H 2 S, producing a gaseous stream having reduced H 2 S content, and aqueous admixture containing solid sulfur and an increased concentration of solubilized ferrous chelate of nitrilotriacetic acid, the ratio of the solubilized ferric chelate of nitrilotriacetic acid to ferrous chelate of nitrilotriacetic acid in said reactant solution being from 0.2 to 6; (b) removing aqueous admixture from the contacting zone and separating a minor portion of said admixture having an increased sulfur concentration, and heating admixture having an increased sulfur concentration in an at least substantially oxygen free environment to a temperature sufficient to melt the sulfur, and producing a solution of solubilized iron chelates of nitrilotriacetic acid containing molten sulfur; (c) separating molten-sulfur containing solution from step (b) in a separation zone in an at least substantially-oxygen free environment into an upper phase comprising substantially-sulfur free solution of solubilized iron chelates of nitrilotriacetic acid and a lower phase comprising molten sulfur; (d) recovering molten sulfur from said separation zone; (e) regenerating the major portion of said admixture by contacting admixture to be regenerated with oxygen in a regeneration zone under conditions to convert solubilized ferrous chelate of nitrilotriacetic acid in the admixture to the solubilized ferric chelate of nitrilotriacetic acid and producing regenerated aqueous reactant solution having a ratio of solubilized ferric chelate of nitrilotriacetic acid to solubilized ferrous chelate of nitrilotriacetic acid of from 0.5 to 6; and (f) passing regenerated aqueous reactant solution from step e) to the contacting zone for use as aqueous reactant solution therein.

Claim 13

A process for the removal of H 2 S from a sour gaseous stream employing an aqueous reactant solution containing solubilized degradable iron chelates comprising (a) contacing the sour gaseous stream with aqueous reactant solution in a contacting zone at a temperature below the melting point of sulfur, the reactant solution containing solubilized ferric chelate of nitrilotriacetic acid, under conditions to convert H 2 S, producing a gaseous stream having reduced H 2 S content, and aqueous admixture containing solid sulfur and an increased concentration of solubilized ferrous chelate of nitrilotriacetic acid, the ratio of the solubilized ferric chelate of nitrilotriacetic acid to ferrous chelate of nitrilotriacetic acid in said reactant solution being from 0.2 to 6; (b) removing aqueous admixture from the contacting zone and separating a minor portion of said admixture having an increased sulfur concentration, and heating admixture having an increased sulfur concentration in an at least substantially oxygen free environment to a temperature sufficient to melt the sulfur, and producing a solution of solubilized iron chelates of nitrilotriacetic acid containing molten sulfur; (c) separating molten-sulfur containing solution from step (b) in a separation zone in an at least substantially-oxygen free environment into an upper phase comprising substantially-sulfur free solution of solubilized iron chelates of nitrilotriacetic acid and a lower phase comprising molten sulfur; (d) recovering molten sulfur from said separation zone; (e) regenerating the major portion of said admixture by contacting admixture to be regenerated with oxygen in a regeneration zone under conditions to convert solubilized ferrous chelate of nitrilotriacetic acid in the admixture to the solubilized ferric chelate of nitrilotriacetic acid and producing regenerated aqueous reactant solution having a ratio of solubilized ferric chelate of nitrilotriacetic acid to solubilized ferrous chelate of nitrilotriacetic acid of from 0.5 to 6; and (f) passing regenerated aqueous reactant solution from step e) to the contacting zone for use as aqueous reactant solution therein.

Claim 14

A process for the removal of H 2 S from a sour gaseous stream employing an aqueous reactant solution containing solubilized degradable iron chelates comprising (a) contacting the sour gaseous stream with aqueous reactant solution in a contacting zone at a temperature below the melting point of sulfur, the reactant solution containing solubilized ferric chelate of nitrilotriacetic acid, under conditions to convert H 2 S, producing a gaseous stream having reduced H 2 S content, and aqueous admixture containing solid sulfur and an increased concentration of solubilized ferrous chelate of nitrilotriacetic acid, the ratio of solubilized ferric chelate of nitrilotriacetic acid to solubilized ferrous chelate of nitrilotriacetic acid in said reactant solution being from 0.2 to 6; (b) removing aqueous admixture from the contacting zone and separating a minor portion of said admixture having an increased solid sulfur concentration, and heating admixture having an increased solid sulfur concentration in an at least substantially oxygen-free environment to a temperature sufficient to melt the sulfur, and producing a solution of solubilized iron chelates of nitrilotriacetic acid containing molten sulfur; (c) separating molten sulfur-containing solution from step (b) in a separation zone in an at least substantially oxygen-free environment into an upper phase comprising substantially sulfur-free solution of solubilized iron chelates of nitrilotriacetic acid and a lower phase comprising molten sulfur; (d) filtering sulfur from step (c) to produce substantially pure molten sulfur; (e) regenerating the major portion of said admixture by contacting admixture to be regenerated with oxygen in a regeneration zone under conditions to convert solubilized ferrous chelate of nitrilotriacetic acid; in the admixture to the solubilized ferric chelate of nitrilotriacetic acid; and producing regenerated aqueous reactant solution having a ratio of solubilized ferric chelate of nitrilotriacetic acid to solubilized ferrous chelate of nitrolotriacetic acid of from 0.5 to 6; and (f) passing regenerated aqueous reactant solution from step e) to the contacting zone for use as aqueous reactant solution therein.

Claim 15

A process for the removal of H 2 S from a sour gaseous stream employing an aqueous reactant solution containing solubilized degradable iron chelates comprising (a) contacting the sour gaseous stream with aqueous reactant solution in a contacting zone at a temperature below the melting point of sulfur, the reactant solution containing solubilized ferric chelate of nitrilotriacetic acid, under conditions to convert H 2 S, producing a gaseous stream having reduced H 2 S content, and aqueous admixture containing solid sulfur and an increased concentration of solubilized ferrous chelate of nitrilotriacetic acid, the ratio of solubilized ferric chelate of nitrilotriacetic acid to solubilized ferrous chelate of nitrilotriacetic acid in said reactant solution being from 0.2 to 6; (b) removing aqueous admixture from the contacting zone and separating a minor portion of said admixture having an increased solid sulfur concentration, and heating admixture having an increased solid sulfur concentration in an at least substantially oxygen-free environment to a temperature sufficient to melt the sulfur, and producing a solution of solubilized iron chelates of nitrilotriacetic acid containing molten sulfur; (c) separating molten sulfur-containing solution from step (b) in a separation zone in an at least substantially oxygen-free environment into an upper phase comprising substantially sulfur-free solution of solubilized iron chelates of nitrilotriacetic acid and a lower phase comprising molten sulfur; (d) filtering sulfur from step (c) to produce substantially pure molten sulfur; (e) regenerating the major portion of said admixture by contacting admixture to be regenerated with oxygen in a regeneration zone under conditions to convert solubilized ferrous chelate of nitrilotriacetic acid; in the admixture to the solubilized ferric chelate of nitrilotriacetic acid; and producing regenerated aqueous reactant solution having a ratio of solubilized ferric chelate of nitrilotriacetic acid to solubilized ferrous chelate of nitrolotriacetic acid of from 0.5 to 6; and (f) passing regenerated aqueous reactant solution from step e) to the contacting zone for use as aqueous reactant solution therein.

Claim 16

The process of claim 8 wherein the stream from which the H 2 S is removed is selected from naturally-occurring gases, synthesis gases, process gases, CO 2 -containing streams, and fuel gases.

Claim 17

The process of claim 9 wherein the sour gaseous stream is natural gas or a stream derived from the gasification of coal or a liquid hydrocarbon.

Claim 18

The process of claim 9 wherein the sour gaseous stream is natural gas.

Claim 19

The process for the removal of H 2 S from a sour gaseous stream employing an aqueous reactant solution containing solubilized degradable iron chelates comprising (a) contacting the sour gaseous stream with aqueous reactant solution in a contacting zone at a temperature below the melting point of sulfur, the reactant solution containing solubilized ferric chelate of nitrilotriacetic acid, and solubilized ferrous chelate of nitrilotriacetic acid, under conditions to convert H 2 S, producing a gaseous stream having a reduced H 2 S content, and aqueous admixture containing solid sulfur and an increased concentration of solubilized ferrous chelate of nitrilotriacetic acid, the ratio of the solubilized ferric chelate of nitrilotriacetic acid to solubilized ferrous chelate of nitrilotriacetic acid in said reactant solution being from 0.2 to 6; (b) removing aqueous admixture from the contacting zone and regenerating admixture by contacting admixture to be regenerated with oxygen in a regeneration zone under conditions to convert solubilized ferrous chelate of nitrilotriacetic acid in the admixture to the solubilized ferric chelate of nitrilotriacetic acid, and producing regenerated reactant solution containing solid sulfur having a ratio of solubilized ferric chelate of nitrilotriacetic acid to solubilized ferrous chelate of nitrilotriacetic acid of from 0.5 to 6; (c) separating a minor portion of said regenerated reactant mixture having an increased solid sulfur concentration, and heating regenerated reactant mixture having an increased solid sulfur concentration in an at least substantially oxygen-free environment to a temperature sufficient to melt the sulfur, and producing a solution of an iron chelate of nitrilotriacetic acid containing molten sulfur; (d) separating molten sulfur-containing solution from step (c) in a separation zone in an at least substantially oxygen-free environment into an upper phase comprising substantially sulfur-free regenerated solution of solubilized iron chelates of nitrilotriacetic acid and a lower phase comprising molten sulfur; (e) recovering molten sulfur from said separation zone; and (f) passing regenerated aqueous reactant solution from step (c) to the contacting zone for use as aqueous reactant solution therein.

Claim 20

The process for the removal of H 2 S from a sour gaseous stream employing an aqueous reactant solution containing solubilized degradable iron chelates comprising (a) contacting the sour gaseous stream with aqueous reactant solution in a contacting zone at a temperature below the melting point of sulfur, the reactant solution containing solubilized ferric chelate of nitrilotriacetic acid, and solubilized ferrous chelate of nitrilotriacetic acid, under conditions to convert H 2 S, producing a gaseous stream having a reduced H 2 S content, and aqueous admixture containing solid sulfur and an increased concentration of solubilized ferrous chelate of nitrilotriacetic acid, the ratio of the solubilized ferric chelate of nitrilotriacetic acid to solubilized ferrous chelate of nitrilotriacetic acid in said reactant solution being from 0.2 to 6; (b) removing aqueous admixture from the contacting zone and regenerating admixture by contacting admixture to be regenerated with oxygen in a regeneration zone under conditions to convert solubilized ferrous chelate of nitrilotriacetic acid in the admixture to the solubilized ferric chelate of nitrilotriacetic acid, and producing regenerated reactant solution containing solid sulfur having a ratio of solubilized ferric chelate of nitrilotriacetic acid to solubilized ferrous chelate of nitrilotriacetic acid of from 0.5 to 6; (c) separating a minor portion of said regenerated reactant mixture having an increased solid sulfur concentration, and heating regenerated reactant mixture having an increased solid sulfur concentration in an at least substantially oxygen-free environment to a temperature sufficient to melt the sulfur, and producing a solution of an iron chelate of nitrilotriacetic acid containing molten sulfur; (d) separating molten sulfur-containing solution from step (c) in a separation zone in an at least substantially oxygen-free environment into an upper phase comprising substantially sulfur-free regenerated solution of solubilized iron chelates of nitrilotriacetic acid and a lower phase comprising molten sulfur; (e) recovering molten sulfur from said separation zone; and (f) passing regenerated aqueous reactant solution from step (c) to the contacting zone for use as aqueous reactant solution therein.

Claim 21

A process for the removal of H 2 S from a sour gaseous stream employing an aqueous reactant solution containing solubilized degradable iron chelates comprising (a) contacting the sour gaseous stream with aqueous reactant solution in a contacting zone at a temperature below the melting point of sulfur, the reactant solution containing solubilized ferric chelate of nitrilotriacetic acid, and solubilized ferrous chelate of nitrilotriacetic acid, under conditions to convert H 2 S, producing a gaseous stream having reduced H 2 S content, and aqueous admixture containing solid sulfur and an increased concentration of solubilized ferrous chelate of nitrilotriacetic acid, the ratio of the solubilized ferrous chelate of nitrilotriacetic acid in said reactant solution being from 0.2 to 6; (b) removing aqueous admixture from the contacting zone and regenerating admixture by contacting admixture to be regenerated with oxygen in a regeneration zone under conditions to convert solubilized ferrous chelate of nitrilotriacetic acid in the admixture to the solubilized ferric chelate of nitrilotriacetic acid, and producing regenerated reactant solution containing solid sulfur having a ratio of solubilized ferric chelate of nitrilotriacetic acid to solubilized ferrous chelate of nitrilotriacetic acid of from 0.5 to 6; (c) separating a minor portion of said regenerated reactant mixture having an increased solid sulfur concentration, and heating regenerated reactant mixture having an increased solid sulfur concentration in an at least substantially oxygen-free environment to a temperature sufficient to melt the sulfur, and producing a solution of an iron chelate of nitrilotriacetic acid containing molten sulfur; (d) separating molten sulfur-containing solution from step (c) in a separation zone in an at least substantially oxygen-free environment into an upper phase comprising substantially sulfur-free regenerated solution of solubilized iron chelates of nitrilotriacetic acid and a lower phase comprising molten sulfur; (e) filtering sulfur from step (d) to produce substantially pure molten sulfur, and recovering the sulfur; and (f) passing regenerated aqueous reactant solution from step (c) to the contacting zone for use as aqueous reactant solution therein.

Claim 22

A process for the removal of H 2 S from a sour gaseous stream employing an aqueous reactant solution containing solubilized degradable iron chelates comprising (a) contacting the sour gaseous stream with aqueous reactant solution in a contacting zone at a temperature below the melting point of sulfur, the reactant solution containing solubilized ferric chelate of nitrilotriacetic acid, and solubilized ferrous chelate of nitrilotriacetic acid, under conditions to convert H 2 S, producing a gaseous stream having reduced H 2 S content, and aqueous admixture containing solid sulfur and an increased concentration of solubilized ferrous chelate of nitrilotriacetic acid, the ratio of the solubilized ferrous chelate of nitrilotriacetic acid in said reactant solution being from 0.2 to 6; (b) removing aqueous admixture from the contacting zone and regenerating admixture by contacting admixture to be regenerated with oxygen in a regeneration zone under conditions to convert solubilized ferrous chelate of nitrilotriacetic acid in the admixture to the solubilized ferric chelate of nitrilotriacetic acid, and producing regenerated reactant solution containing solid sulfur having a ratio of solubilized ferric chelate of nitrilotriacetic acid to solubilized ferrous chelate of nitrilotriacetic acid of from 0.5 to 6; (c) separating a minor portion of said regenerated reactant mixture having an increased solid sulfur concentration, and heating regenerated reactant mixture having an increased solid sulfur concentration in an at least substantially oxygen-free environment to a temperature sufficient to melt the sulfur, and producing a solution of an iron chelate of nitrilotriacetic acid containing molten sulfur; (d) separating molten sulfur-containing solution from step (c) in a separation zone in an at least substantially oxygen-free environment into an upper phase comprising substantially sulfur-free regenerated solution of solubilized iron chelates of nitrilotriacetic acid and a lower phase comprising molten sulfur; (e) filtering sulfur from step (d) to produce substantially pure molten sulfur, and recovering the sulfur; and (f) passing regenerated aqueous reactant solution from step (c) to the contacting zone for use as aqueous reactant solution therein.

Claim 23

The process of claim 13 wherein the stream from which the H 2 S is removed is selected from naturally-occurring gases, synthesis gases, process gases, CO 2 -containing streams, and fuel gases.

Claim 24

The process of claim 14 wherein the sour gaseous stream is natural gas or a stream derived from the gasification of coal or a liquid hydrocarbon.

Claim 25

The process of claim 14 wherein the sour gaseous stream is natural gas.

Claim 26

The process of claim 5 wherein substantially sulfur-free solution is recovered and returned for use in the process.

Claim 27

The process of claim 6 wherein substantially sulfur-free solution is recovered and returned for use in the process.

Claim 28

The process of claim 7 wherein substantially sulfur-free solution is recovered and returned for use in the process.

Claim 29

The process of claim 8 wherein substantially sulfur-free solution is recovered and returned for use in the process.

Claim 30

The process of claim 12 wherein substantially sulfur-free solution is recovered and returned for use in the process.

Claim 31

The process of claim 13 wherein the substantially sulfur-free solution is recovered and returned for use in the process.

Claim 32

The process of claim 7 wherein the admixture having an increased solid sulfur concentration is contacted with a reducing gas.

Claim 33

The process of claim 23 wherein the reducing gas is an H 2 S-containing gas.

Claim 34

The process of claim 7 wherein the oxygen free environment is maintained by use of a reducing gas.

Claim 35

The process of claim 25 wherein the oxygen reducing gas is an H 2 S containing gas.

Claim 36

The process of claim 12 wherein the admixture having an increased solid sulfur concentration is contacted with a reducing gas.

Claim 37

The process of claim 27 wherein the reducing gas is an H 2 S-containing gas.

Claim 38

The process of claim 12 wherein the oxygen free environment is maintained by use of a reducing gas.

Claim 39

The process of claim 29 wherein the oxygen reducing gas is an H 2 S containing gas.