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Non-rigid vinyl chloride polymer resin composition

Assignee: Mitsubishi Chemical Corp
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Filing: 1985-11-06
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Granted: 1987-05-05
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Expires: 2005-11-06
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Abstract

Abstract Disclosed is a non-rigid vinyl chloride polymer composition comprising 100 weight parts of a vinyl chloride polymer resin, 5-50 weight parts of a graft copolymer modifier and 10-300 weight parts of a plasticizer. The graft copolymer modifier is obtained by graft-polymerizing 25-150 weight parts of an alkyl ester of methacrylic acid having 1 to 4 carbon atoms in the alkyl group or a monomer mixture composed of at least more than 50% by weight of said alkyl ester of methacrylic acid onto 100 weight parts of an acrylic elastomer having a swelling degree of 5 to 25 so that the grafting ratio is not larger than 50%. The acrylic elastomer is obtained by polymerizing a mixture comprising an alkyl ester of acrylic acid having 2 to 10 carbon atoms in the alkyl group or a monomer mixture composed of at least 50% by weight of said alkyl ester of acrylic acid, and a polyfunctional crosslinking agent. The non-rigid vinyl chloride polymer composition has excellent weatherability and impact resistance, and exhibits a good molding processability.

Inventors

  • 👤 Kazuo Kishida
  • 👤 Kazuo Ueda
  • 👤 Kiyokazu Kitai
  • 👤 Tsuruyoshi Matsumoto

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 16:53
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/0008; C08K5/0016; C08L; C08L27/00; C08L27/02; C08L27/04; C08L27/06; C08L51/00; C08L51/003

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 173 words
A non-rigid vinyl chloride polymer resin composition comprising: (i) 100 parts by weight of a vinyl chloride polymer resin comprising at least 70% by weight of units derived from vinyl chloride, (ii) 5 to 50 parts by weight of a graft copolymer obtained by graft-polymerizing 25 to 150 parts by weight of an alkyl ester of methacrylic acid having 1 to 4 carbon atoms in the alkyl group or a monomer mixture composed of at least 50% by weight of said alkyl ester of methacrylic acid onto 100 parts by weight of an acrylic elastomer having a degree of swelling of 5 to 25 so that the grafting ratio is not larger than 50%, which elastomer is obtained by polymerizing a mixture comprising an alkyl ester of acrylic acid having 2 to 10 carbon atoms in the alkyl group or a monomer mixture composed of at least 50% by weight of said alkyl ester of acrylic acid, and a polyfunctional crosslinking agent, and (iii) 10 to 300 parts by weight of a plasticizer.
Claim 2
Dependent Claim 173 words
A non-rigid vinyl chloride polymer resin composition comprising: (i) 100 parts by weight of a vinyl chloride polymer resin comprising at least 70% by weight of units derived from vinyl chloride, (ii) 5 to 50 parts by weight of a graft copolymer obtained by graft-polymerizing 25 to 150 parts by weight of an alkyl ester of methacrylic acid having 1 to 4 carbon atoms in the alkyl group or a monomer mixture composed of at least 50% by weight of said alkyl ester of methacrylic acid onto 100 parts by weight of an acrylic elastomer having a degree of swelling of 5 to 25 so that the grafting ratio is not larger than 50%, which elastomer is obtained by polymerizing a mixture comprising an alkyl ester of acrylic acid having 2 to 10 carbon atoms in the alkyl group or a monomer mixture composed of at least 50% by weight of said alkyl ester of acrylic acid, and a polyfunctional crosslinking agent, and (iii) 10 to 300 parts by weight of a plasticizer.
Claim 3
Dependent Claim 36 words
A non-rigid vinyl chloride polymer resin composition according to claim 1, wherein the alkyl ester of acrylic acid is at least one monomer selected from the group consisting of n-butyl acrylate, n-octyl acrylate and 2-ethylhexyl acrylate.
Claim 4
Dependent Claim 21 words
A non-rigid vinyl chloride polymer resin composition according to claim 1, wherein the alkyl ester of acrylic acid is n-butyl acrylate.
Claim 5
Dependent Claim 36 words
A non-rigid vinyl chloride polymer resin composition according to claim 1, wherein the polyfunctional crosslinking agent is at least one compound selected from the group consisting of divinylbenzene, 1,3-butylene glycol dimethacrylate, dicyclopentenyl acrylate and dicyclopentenyl methacrylate.
Claim 6
Dependent Claim 19 words
A non-rigid vinyl chloride polymer resin composition according to claim 1, wherein the polyfunctional crosslinking agent is dicyclopentenyl acrylate.
Claim 7
Dependent Claim 19 words
A non-rigid vinyl chloride polymer resin composition according to claim 1, wherein the polyfunctional crosslinking agent is dicyclopentenyl methacrylate.
Claim 8
Dependent Claim 21 words
A non-rigid vinyl chloride polymer resin composition according to claim 1, wherein the alkyl ester of methacrylic acid is methyl methacrylate.

References Cited (Backward Citations)

US4220734A Cited
US4014842A Cited
US3994991A Cited
US4229549A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-05-04 1990-11-03 1991-05-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-05-04 1994-11-03 1995-05-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-05-04 1998-11-03 1999-05-05 $7700.00 Window Closed / Lapsed

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