US4659780A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Acrylourethane reaction product
Assignee: EIDP Inc
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Filing: 1985-03-18
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Granted: 1987-04-21
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Expires: 2005-03-18
Abstract
Abstract The ungelled reaction product of an acrylic prepolymer, a diol and a diisocyanate, reacted in the presence of a small amount of a monoalcohol to prevent gelling, is an acrylourethane polymer which may be acid modified and is useful in high solids coating compositions.
Inventors
- 👤 Andrew P. Stamegna
- 👤 Clifford H. Strolle
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 04:12
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/83; C08G18/831; C08G18/08; C08G18/0804; C08G18/0819; C08G18/0823; C08G18/28; C08G18/2805; C08G18/2815; C08G18/282; C08G18/40; C08G18/4009; C08G18/4063; C08G18/62; C08G18/6216; C08G18/622; C08G18/6225; C08G18/6229; C08G18/65; C08G18/6505; C08G18/6511; C09; C09D; C09D175/00; C09D175/04
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
79 words
The ungelled reaction product, by weight based on total polymer solids, of (a) 50-70% of an acrylic prepolymer having a number average molecular weight of 2,000-10,000 and an average of 5-15, hydroxyl groups per chain said prepolymer comprising the following monomers in percent by weight based on the prepolymer: 40-60% of one or more of butyl methacrylate or butyl acrylate 10-30% lauryl methacrylate 20-40% of one or more of hydroxyethyl acrylate, hydroxyethyl methacrylate, hydroxypropyl acrylate or hydroxypropyl methacrylate, and
Claim 2
Dependent Claim
79 words
The ungelled reaction product, by weight based on total polymer solids, of (a) 50-70% of an acrylic prepolymer having a number average molecular weight of 2,000-10,000 and an average of 5-15, hydroxyl groups per chain said prepolymer comprising the following monomers in percent by weight based on the prepolymer: 40-60% of one or more of butyl methacrylate or butyl acrylate 10-30% lauryl methacrylate 20-40% of one or more of hydroxyethyl acrylate, hydroxyethyl methacrylate, hydroxypropyl acrylate or hydroxypropyl methacrylate, and
Claim 3
Dependent Claim
80 words
0-30% of one or more of styrene, methyl methacrylate and ethylmethacrylate, (b) 20-35% of at least one of a monomeric diol and an oligomeric diol having a number average molecular weight of 200-2,000, (c) 5-15% of an aliphatic or aromatic diisocyanate, and (d) 1.0-4.0% of a monofunctional alcohol, said reaction being performed by first forming the acrylic prepolymer of (a) then mixing with (a) the diol of (b) and the alcohol of (d), then mixing therewith the diisocyanate of (c).
Claim 4
Dependent Claim
80 words
0-30% of one or more of styrene, methyl methacrylate and ethylmethacrylate, (b) 20-35% of at least one of a monomeric diol and an oligomeric diol having a number average molecular weight of 200-2,000, (c) 5-15% of an aliphatic or aromatic diisocyanate, and (d) 1.0-4.0% of a monofunctional alcohol, said reaction being performed by first forming the acrylic prepolymer of (a) then mixing with (a) the diol of (b) and the alcohol of (d), then mixing therewith the diisocyanate of (c).
Claim 5
Dependent Claim
23 words
The reaction product of claim 1 in which 5-50% of the hydroxyl groups on the acrylic prepolymer have reacted with diol or diisocyanate.
Claim 6
Dependent Claim
16 words
The reaction product of claim 2 in which 10-30% of the hydroxyl groups have so reacted.
Claim 7
Dependent Claim
25 words
The reaction product of claim 2 in which the diol is dimethylolpropionic acid and the acid number of the reaction product is at least 10.
Claim 8
Dependent Claim
13 words
The reaction product of claim 4 in which the acid number is 15-25.
Claim 9
Dependent Claim
58 words
The reaction product of claim 3 in which (a) the acrylic prepolymer has a number average molecular weight of 3,000-5,000 and an average of 6-12 hydroxyl groups per chain, (b) the diol is either monomeric or an oligomer having a number average molecular weight of 500-1,500, (d) the monofunctional alcohol is present in the range of about 2.0-3.0%.
Claim 10
Dependent Claim
61 words
The reaction product of claim 6 in which (b) the diol is one or more of neopentyl glycol, ethylene glycol, cyclohexanedimethanol, 1,6-hexane diol, 1,4-butane diol, dimethylol propionic acid, or other diol having 2-10 carbon atoms, or a polyester diol oligomer including polycaprolactone diol, (c) the diisocyanate is one or more of 4,4'-methylene bis(cyclohexyl isocyanate), hexamethylene diisocyanate, trimethylhexamethylene diisocyanate, and toluene diisocyanate.
Claim 11
Dependent Claim
37 words
The reaction product of claim 6 in which (b) the diol is polycaprolactone diol having a number average molecular weight of about 1,000 and (d) the monofunctional is n-butyl alcohol, present in an amount of about 2.5%.
Claim 12
Dependent Claim
19 words
A coating composition comprising the reaction product of claim 1 and a crosslinking resin in an organic solvent media.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-04-20 | 1990-10-20 | 1991-04-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-04-20 | 1994-10-20 | 1995-04-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-04-20 | 1998-10-20 | 1999-04-21 | $7700.00 | Window Closed / Lapsed |