High solids paint composition comprising hydroxy functional oligoesters and hydroxy functional copolymers

Claim 2

A high solids, thermosetting coating composition which, exclusive of pigments, solvents and other nonreactive components, consists essentially of: (A) A hydroxy functional component consisting of: (1) between about 1 and about 90 weight percent of one or more oligoesters (i) having a number average molecular weight (M n ) of between about 150 and about 3000, (ii) bearing at least 2 hydroxyl groups per molecule, and (iii) being formed by an esterification reaction between a carboxylic acid and an epoxide; and (2) between about 99 and about 10 weight percent of a hydroxy functional copolymer having a number average molecular weight (M n ) of between about 500 and 15,000, said hydroxy functional copolymer being formed from about 10 to about 50 weight percent of hydroxy functional monoethylenically unsaturated monomers selected from the group consisting of hydroxy bearing aliphatic alcohol esters of acrylic and methacrylic acids, and a remainder of other monoethylenically unsaturated monomers; and (B) A crosslinking agent capable of reacting with hydroxy functionality of said hydroxyl functional component.

Claim 3

A high solids, thermosetting coating composition in accordance with claim 1 wherein said oligoesters are selected from the group consisting of: (a) the esterification reaction product of a polycarboxylic acid and a monoepoxide; (b) the esterification reaction product of a polyepoxide and a monocarboxylic acid bearing no hydroxy functionality; (c) the esterification reaction product of a hydroxy functional carboxylic acid and a monoepoxide; (d) the esterification reaction product of a monocarboxylic acid and a hydroxy functional monoepoxide; and (e) mixtures of (a)-(d).

Claim 4

A high solids, thermosetting coating composition in accordance with claim 1 or 2 wherein said oligoester bears functionality other than hydroxy functionality, which functionality does not interfere with the crosslinking reaction between said hydroxy functionality and said crosslinking agent.

Claim 5

A high solids, thermosetting coating composition in accordance with claims 1 or 2 wherein said crosslinking agent is an amino crosslinking agent and is included in said coating composition in an amount equal to the total of (1) between about 40 and about 150 parts by weight per 100 parts by weight of said oligoesters and (2) between about 25 and about 67 parts by weight per 100 parts by weight of said hydroxy functional copolymer.

Claim 6

A thermosetting coating composition in accordance with claim 4 wherein said amino crosslinking agent is selected from the group consisting of condensation products of formaldehyde with melamine, substituted melamine, urea, benzoguanamine or substituted benzoguanamine.

Claim 7

A thermosetting coating composition in accordance with claim 5 wherein said amino crosslinking agent is monomeric.

Claim 8

A thermosetting coating composition in accordance with claim 5 wherein said amino crosslinking agent is an ether of a fully methylated melamine.

Claim 9

A high solids, thermosetting coating composition in accordance with claims 1 or 2 wherein said crosslinking agent is a polyisocyanate crosslinking agent having two or more reactive isocyanate groups per molecule and being included in said coating composition in an amount equal to between about 0.5 and about 1.6 reactive isocyanate groups per hydroxyl group present in said composition.

Claim 10

A high solids, thermosetting coating composition in accordance with claim 8 wherein said polyisocyanate crosslinking agent is included in said composition in an amount sufficient to provide between about 0.8 and about 1.3 reactive isocyanate groups per hydroxyl group in said composition.

Claim 11

A high solids, thermosetting coating composition in accordance with claim 8 wherein said polyisocyanate crosslinking agent is a diisocyanate.

Claim 12

A high solids, thermosetting coating composition in accordance with claim 8 wherein said polyisocyanate crosslinking agent has 3 or more reactive isocyanates per molecule.

Claim 13

A high solids, thermosetting coating composition in accordance with claim 11 wherein said polyisocyanate crosslinking agent is a trimerized product of an aliphatic diisocyanate.

Claim 14

A high solids, thermosetting coating composition in accordance with claim 11 wherein said polyisocyanate crosslinking agent is a trimerized reaction product of 1,6 hexamethylene diisocyanate.

Claim 15

A high solids, thermosetting coating composition in accordance with claim 11 wherein said polyisocyanate crosslinking agent is a polyisocyanate having a biuret structure.

Claim 16

A high solids, thermosetting coating composition in accordance with claim 1 wherein said hydroxy functional oligoester is an esterification reaction product of an aliphatic dicarboxylic acid containing 6 to 12 carbon atoms and an alkylene oxide.

Claim 17

A high solids, thermosetting coating composition in accordance with claim 1 wherein said hydroxy functional oligoester is an esterification reaction product of an alkylene oxide and a polycarboxylic acid.

Claim 18

A high solids, thermosetting coating composition in accordance with claim 1 wherein said hydroxy functional oligoester is an esterification reaction product of one or more aliphatic monocarboxylic acids containing between about 1 and about 22 carbon atoms and a diepoxide.

Claim 19

A high solids, thermosetting coating composition in accordance with claim 1 wherein said hydroxy functional oligoester is an esterification reaction product of a hydroxy functional aliphatic monocarboxylic acid having between about 2 and 22 carbon atoms and a polyepoxide.

Claim 20

A high solids, thermosetting coating composition in accordance with claim 1 wherein said hydroxy functional oligoester is an esterification reaction product of an aliphatic carboxylic acid containing between 2 and 22 carbon atoms and an alkylene oxide.

Claim 21

A high solids, thermosetting coating composition in accordance with claims 1 or 2 wherein said hydroxy functional copolymer has a number average molecular weight (M n ) of between about 1500 and about 5000 and is prepared from between about 25 and 40 weight percent of hydroxy functional monoethylenically unsaturated monomers selected from the group consisting of hydroxy bearing aliphatic alcohol esters of acrylic and methacrylic acid, and a remainder of other monoethylenically unsaturated monomers.

Claim 22

A high solids, thermosetting coating composition in accordance with claim 20 wherein said remainder of other monoethylenically unsaturated monomers are monomers bearing alpha-beta olefinic unsaturation.

Claim 23

A high solids, thermosetting coating composition in accordance with claim 21 wherein said other monoethylenically unsaturated monomers are selected from the group consisting of acrylates, methacrylates, monovinyl hydrocarbons having between 8 and 12 carbon atoms, other modifying vinyl monomers and mixtures thereof.

Claim 24

A high solids, thermosetting coating composition in accordance with claim 20 wherein said other monoethylenically unsaturated monomers consist essentially of esters of C 1 -C 8 monoalcohols and acrylic or methacrylic acids.

Claim 25

A high solids, thermosetting coating composition in accordance with claim 1 wherein said hydroxy functional component consists of: (1) between about 5 and about 30 weight percent of hydroxyl bearing oligoester having a number average molecular weight (M n ) of between about 150 and about 3000 and being selected from the group consisting of: (a) the esterification reaction product of a di- or polycarboxylic acid and a monoepoxide; (b) the esterification reaction product of a polyepoxide with a monocarboxylic acid; (c) the esterification reaction product of a hydroxy functional carboxylic acid with a mono- or polyepoxide; (d) the esterification reaction product of a monocarboxylic acid and a hydroxy functional mono- or diepoxide; and (e) a mixture of the esterification reaction products of (a)-(d); and (2) between about 95 and about 70 weight percent of a hydroxy functional copolymer having a number average molecular weight (M n ) of between about 500 and 15,000 said hydroxy functional copolymer being formed from about 10 to about 50 weight percent of hydroxy functional monoethylenically unsaturated monomers selected from the group consisting of hydroxy bearing aliphatic alcohol esters of acrylic and methacrylic acid, and a remainder of other monoethylenically unsaturated monomers.

Claim 26

A high solids, thermosetting coating composition in accordance with claim 24 wherein said crosslinking agent is an amino crosslinking agent and is included in said coating composition in an amount equal to the total of (1) between about 40 and about 150 parts by weight per 100 parts by weight of said oligoesters and (2) between about 25 and about 67 parts by weight per 100 parts by weight of said hydroxy functional copolymer.

Claim 27

A high solids, thermosetting coating composition in accordance with claim 24 wherein said crosslinking agent is a polyisocyanate crosslinking agent having two or more reactive isocyanate groups per molecule and being included in said coating composition in an amount sufficient to provide between about 0.5 and about 1.6 reactive isocyanate groups per hydroxyl group present in said composition.

Claim 28

A high solids, thermosetting coating composition in accordance with claim 26 wherein (A) said hydroxy functional component consists of: (1) between about 10 and about 50 weight percent of said hydroxy functional oligoester; and (2) between about 90 and about 50 weight percent of said hydroxy functional copolymer; and (B) said crosslinking agent (1) has 3 or more reactive isocyanate groups per molecule; (2) has a biuret structure; and (3) is included in said composition in an amount sufficient to provide between about 0.8 and about 1.3 reactive isocyanate groups per hydroxyl group in said hydroxy functional component.

Claim 29

A thermosetting coating composition in accordance with claim 24 wherein said hydroxy functional copolymer has a number average molecular weight (M n ) of between about 1500 and about 5000 and is prepared from between about 25 and about 40 weight percent of an hydroxy functional monoethylenically unsaturated monomer selected from the group consisting of hydroxy bearing aliphatic alcohol esters of acrylic and methacrylic acid, and a remainder of other monoethylenically unsaturated monomers.

Claim 30

A thermosetting coating composition in accordance with claim 28 wherein said remainder of other monoethylenically unsaturated monomers are monomers bearing alpha-beta olefinic unsaturation.

Claim 31

A thermosetting coating composition in accordance with claim 28 wherein said other monoethylenically unsaturated monomers are selected from the group consisting of acrylates, methacrylates, monovinyl hydrocarbons having between 8 and 12 carbon atoms, other modifying vinyl monomers and mixtures thereof.

Claim 32

A high solids, thermosetting coating composition which, exclusive of pigments, solvents and other nonreactive components, consist essentially of: (A) a hydroxy functional component consisting of: (1) between about 10 and about 90 weight percent of hydroxyl bearing oligoester having a number average molecular weight (M n ) of between about 150 and about 3000 and being selected from the group consisting of: (a) the esterification reaction product of a di- or polycarboxylic acid and a monoepoxide; (b) the esterification reaction product of a polyepoxide with a monocarboxylic acid; (c) the esterification reaction product of a hydroxy functional carboxylic acid with a mono- or polyepoxide; and (d) the esterification reaction product of a monocarboxylic acid and a hydroxy functional mono- or polyepoxide and (e) a mixture of the esterification reaction product of (a)-(d); and (2) between about 90 and about 10 weight percent of a hydroxy functional copolymer having a number average molecular weight (M n ) of between about 500 and about 15,000, said hydroxy functional monoethylenically unsaturated monomers selected from the group consisting of hydroxy bearing aliphatic alcohol esters of acrylic and methacrylic acid, and a remainder of other monoethylenically unsaturated monomers; and (B) a polyisocyanate crosslinking agent having 2 or more reactive isocyanate groups per molecule, said polyisocyanate crosslinking agent being included in said coating composition in an amount sufficient to provide between about 0.5 and about 1.6 reactive isocyanate groups per hydroxy functional group in said composition.

Claim 33

A high solids, thermosetting coating composition which, exclusive of pigments, solvents and other nonreactive components, consist essentially of: (A) a hydroxy functional component consisting of: (1) between about 10 and about 90 weight percent of hydroxyl bearing oligoester having a number average molecular weight (M n ) of between about 150 and about 3000 and being selected from the group consisting of: (a) the esterification reaction product of a di- or polycarboxylic acid and a monoepoxide; (b) the esterification reaction product of a polyepoxide with a monocarboxylic acid; (c) the esterification reaction product of a hydroxy functional carboxylic acid with a mono- or polyepoxide; and (d) the esterification reaction product of a monocarboxylic acid and a hydroxy functional mono- or polyepoxide and (e) a mixture of the esterification reaction product of (a)-(d); and (2) between about 90 and about 10 weight percent of a hydroxy functional copolymer having a number average molecular weight (M n ) of between about 500 and about 15,000, said hydroxy functional monoethylenically unsaturated monomers selected from the group consisting of hydroxy bearing aliphatic alcohol esters of acrylic and methacrylic acid, and a remainder of other monoethylenically unsaturated monomers; and (B) a polyisocyanate crosslinking agent having 2 or more reactive isocyanate groups per molecule, said polyisocyanate crosslinking agent being included in said coating composition in an amount sufficient to provide between about 0.5 and about 1.6 reactive isocyanate groups per hydroxy functional group in said composition.

Claim 34

A thermosetting coating composition in accordance with claim 30 wherein said polyisocyanate crosslinking agent is included in said composition in an amount sufficient to provide between about 0.8 and about 1.3 reactive isocyanate groups per hydroxy group in said composition.

Claim 35

A thermosetting coating composition in accordance with claim 30 wherein said polyisocyanate crosslinking agent is a diisocyanate.

Claim 36

A thermosetting coating composition in accordance with claim 30 wherein said polyisocyanate crosslinking agent has 3 or more reactive isocyanates per molecule.

Claim 37

A thermosetting coating composition in accordance with claim 34 wherein said polyisocyanate crosslinking agent is a trimerized product of an aliphatic diisocyanate.

Claim 38

A thermosetting coating composition in accordance with claim 35 wherein said polyisocyanate crosslinking agent is a trimerized reaction product of 1,6 hexamethylene diisocyanate.

Claim 39

A thermosetting coating composition in accordance with claim 34 wherein said polyisocyanate crosslinking agent is a polyisocyanate having a biuret structure.

Claim 40

A thermosetting coating composition in accordance with claim 30 wherein said hydroxy functional oligoester is an esterification reaction product of an alkylene oxide and an aliphatic dicarboxylic acid containing 6 to 12 carbon atoms.

Claim 41

A thermosetting coating composition in accordance with claim 30 wherein said hydroxy functional oligoester is an esterification reaction product of an alkylene oxide and a polycarboxylic acid.

Claim 42

A thermosetting coating composition in accordance with claim 30 wherein said hydroxy functional oligoester is an esterification reaction product of a diepoxide and one or more aliphatic monocarboxylic acids containing between about 1 and about 22 carbon atoms.

Claim 43

A thermosetting coating composition in accordance with claim 30 wherein said hydroxy functional oligoester is an esterification reaction product of a hydroxy functional aliphatic monocarboxylic acid having between about 2 and 22 carbon atoms and a polyepoxide.

Claim 44

A thermosetting coating composition in accordance with claim 30 wherein said hydroxy functional oligoester is an esterification reaction product of a hydroxy functional aliphatic carboxylic acid containing between about 2 and 22 carbon atoms and an alkylene oxide.

Claim 45

A thermosetting coating composition which, exclusive of pigments, solvents and other nonreactive components consists essentially of: (A) A hydroxy functional component consisting of: (1) between about 10 and about 50 weight percent of a hydroxy bearing oligoester having a number average molecular weight (M n ) of between about 150 and about 3000, said hydroxy bearing oligoester being the esterification reaction product of a aliphatic dicarboxylic acid having between about 6 and 12 carbon atoms and an alkylene oxide; and (2) between about 90 and about 50 weight percent of a hydroxy functional copolymer formed from between about 25 and about 40 weight percent of a hydroxy functional monoethylenically unsaturated monomer selected from the group consisting of hydroxy bearing aliphatic alcohol esters of acrylic and methacrylic acid, and a remainder of other monoethylenically unsaturated monomers bearing alpha-beta olefinic unsaturation, said other monoethylenically unsatured monomers being selected from the group consisting of acrylates, methacrylates, monovinyl hydrocarbons having 8-12 carbons, other modifying monomers and mixtures thereof; and (B) a polyisocyanate crosslinking agent having 3 or more reactive isocyanate groups per molecule, said isocyanate crosslinking agent having a biuret structure and being included in said composition in an amount sufficient to provide between about 0.8 and about 1.3 reactive isocyanate groups per hydroxy group of said hydroxy functional component.

Claim 46

A thermosetting coating composition which, exclusive of pigments, solvents and other nonreactive components consists essentially of: (A) A hydroxy functional component consisting of: (1) between about 10 and about 50 weight percent of a hydroxy bearing oligoester having a number average molecular weight (M n ) of between about 150 and about 3000, said hydroxy bearing oligoester being the esterification reaction product of a aliphatic dicarboxylic acid having between about 6 and 12 carbon atoms and an alkylene oxide; and (2) between about 90 and about 50 weight percent of a hydroxy functional copolymer formed from between about 25 and about 40 weight percent of a hydroxy functional monoethylenically unsaturated monomer selected from the group consisting of hydroxy bearing aliphatic alcohol esters of acrylic and methacrylic acid, and a remainder of other monoethylenically unsaturated monomers bearing alpha-beta olefinic unsaturation, said other monoethylenically unsatured monomers being selected from the group consisting of acrylates, methacrylates, monovinyl hydrocarbons having 8-12 carbons, other modifying monomers and mixtures thereof; and (B) a polyisocyanate crosslinking agent having 3 or more reactive isocyanate groups per molecule, said isocyanate crosslinking agent having a biuret structure and being included in said composition in an amount sufficient to provide between about 0.8 and about 1.3 reactive isocyanate groups per hydroxy group of said hydroxy functional component.