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Production of a lift-off mask and its application

Assignee: International Business Machines Corp
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Filing: 1986-03-17
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Granted: 1987-04-21
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Expires: 2006-03-17
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Abstract

Abstract A positive resist containing a weak base and polyvinyl phenol as a film forming component is deposited on a substrate, subsequently exposed imagewise, cured, blanket exposed and developed in a KOH solution at temperatures of less than 10° C. The resist pattern thus obtained is exposed to light having a wavelength ranging from 300 to 320 nm and finally heat-treated at temperatures ranging from 150° to 280° C. The finished lift-off mask is dimensionally stable at temperatures of ≦280° C. and does not emit liquid or volatile components when heated. During application of the lift-off mask, a material is blanket vapor deposited at a substrate temperature ranging from about 160° to 250° C. on the resist pattern having openings with overhanging walls. Subsequently, the resist pattern is dissolved in a sodium metasilicate solution, causing the material vapor deposited thereon to be lifted off, with the material deposited on the substrate directly remaining. The lift-off mask is particularly suitable for generating conductor patterns on semiconductor substrates if low and uniform contact resistances between the conductor and the semiconductor material and a high degree of pattern accuracy and packing density are required.

Inventors

  • 👤 Holger Moritz
  • 👤 Gerd Pfeiffer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 17:09
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/022; G03F7/023; G03F7/0233; G03F7/20; G03F7/2022

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 87 words
Method for producing a lift-off mask, wherein a positive resist containing a weak base is deposited on a substrate, exposed imagewise, cured, blanket exposed and developed, characterized in that a positive resist is used containing polyvinyl phenol as a film forming component, that development is effected in an alkaline solution at a temperature of <10° C., that after development, the resist pattern is exposed, using light having a wavelength ranging from 300 to 320 nm, and subsequently heat-treated at a temperature ranging from 150° to 280° C.
Claim 2
Dependent Claim 87 words
Method for producing a lift-off mask, wherein a positive resist containing a weak base is deposited on a substrate, exposed imagewise, cured, blanket exposed and developed, characterized in that a positive resist is used containing polyvinyl phenol as a film forming component, that development is effected in an alkaline solution at a temperature of <10° C., that after development, the resist pattern is exposed, using light having a wavelength ranging from 300 to 320 nm, and subsequently heat-treated at a temperature ranging from 150° to 280° C.
Claim 3
Dependent Claim 30 words
Method according to claim 1, characterized in that development is effected at temperatures ranging from 0° to 10° C., using a KOH solution whose normality ranges from 0.05 to 0.2.
Claim 4
Dependent Claim 20 words
Method according to claim 2, characterized in that development is effected in a KOH solution having a normality of 0.13.
Claim 5
Dependent Claim 21 words
Method according to claim 3, characterized in that the resist pattern is exposed to light having a wavelength of 308 nm.
Claim 6
Dependent Claim 22 words
Method according to claim 4, characterized in that the resist pattern is exposed at an energy density of ≧60 mJ/cm 2 .
Claim 7
Dependent Claim 15 words
Method according to claim 5, characterized in that 1-hydroxyethyl-2-alkylimidazoline is used as a weak base.
Claim 8
Dependent Claim 123 words
An improved method for producing a conductor pattern on a substrate comprising producing a lift-off mask by depositing on said substrate a positive resist, containing a weak base and polyvinyl phenol as a film forming component, exposing the resist imagewise, developing the exposed resist in an alkaline solution at a temperature of <10° C., exposing the developed resist to light of a wavelength of from 300 to 320 nm, heat treating the resist at a temperature in the range of 150° C. to 280° C. depositing a blanket layer of conductive material over said lift-off mask, dissolving the lift-off mask in an aqueous sodium metasilicate solution thereby dissolving the lift-off mask and causing the conductive material on the mask to be lifted off.
Claim 9
Dependent Claim 123 words
An improved method for producing a conductor pattern on a substrate comprising producing a lift-off mask by depositing on said substrate a positive resist, containing a weak base and polyvinyl phenol as a film forming component, exposing the resist imagewise, developing the exposed resist in an alkaline solution at a temperature of <10° C., exposing the developed resist to light of a wavelength of from 300 to 320 nm, heat treating the resist at a temperature in the range of 150° C. to 280° C. depositing a blanket layer of conductive material over said lift-off mask, dissolving the lift-off mask in an aqueous sodium metasilicate solution thereby dissolving the lift-off mask and causing the conductive material on the mask to be lifted off.
Claim 10
Dependent Claim 17 words
The method of claim 7 wherein said aqueous sodium metasilicate sodium has a concentration of ≦0.25 molar.
Claim 11
Dependent Claim 30 words
The method of claim 7 wherein said substrate is a semiconductor substrate provided with an insulating layer with contact holes, and said lift-off mask is deposited on said insulating layer.
Claim 12
Dependent Claim 32 words
The method of claim 7 wherein said layer of conductive material is a layer of metal that is vapor deposited at a substrate temperature in the range of 160° to 250° C.
Claim 13
Dependent Claim 11 words
The method of claim 7 wherein said weak base is 1-hydroxyethyl-2-alkylimidazaline.

References Cited (Backward Citations)

US4104070A Cited
US4378383A Cited
US4439516A Cited
US4443533A Cited
US4567132A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-04-20 1990-10-20 1991-04-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-04-20 1994-10-20 1995-04-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-04-20 1998-10-20 1999-04-21 $7700.00 Window Closed / Lapsed

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