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US4656729A
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Dual electron injection structure and process with self-limiting oxidation barrier
Assignee: International Business Machines Corp
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Filing: 1985-03-25
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Granted: 1987-04-14
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Expires: 2005-03-25
Abstract
Abstract A dual electron injection structure (DEIS) and process for incorporating it into a semi-conductor structure, such as an E2PROM and/or NVRAM, is disclosed. The DEIS includes a composite structure formed from a layer of silicon rich nitride, a layer of silicon dioxide (SiO 2 ) and a layer of silicon rich oxide. Preferably, a Plasma Enhanced Chemical Vapor Deposit (PECVD) method or a low pressure chemical vapor deposit (LPCVD) method is used to place the DEIS between the Poly 1 and Poly 2 devices of the semi-conductor structure.
Inventors
- 👤 Charles T. Kroll, Jr.
- 👤 Geoffrey B. Stephens
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 21:30
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/60; H10P14/63; H10P14/6326; H10P14/6328; H10P14/6334; H10P14/6336; H10B; H10B69/00; H10P14/66; H10P14/668; H10P14/6681; H10P14/6682; H10P14/69; H10P14/692; H10P14/6921; H10P14/69215; H10P14/694; H10P14/6943; H10P14/69433
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
228 words
A method for incorporating a non-continuous DEIS structure between multiple layers of polysilicon in an array of devices on an integrated circuit substrate comprising the following steps: (a) fabricating at least one thin oxide region surrounded by thick oxide regions on a silicon substrate; (b) depositing a first polysilicon gate interconnect layer on the substrate; (c) depositing a layer of silicon rich nitride on said polysilicon gate interconnect layer; (d) patterning a first photoresist mask on the silicon rich nitride layer with said photoresist mask defining a profile for the silicon rich nitride; (e) etching the uncovered areas of the silicon rich nitride; (f) patterning a second mask on the first polysilicon gate interconnect layer with said second mask defining a profile for the first polysilicon gate interconnect layer; (g) etching the uncovered areas of the first polysilicon gate interconnect layer; (h) etching back the thin oxide region in step (a) to the silicon substrate; (i) growing an oxide layer of sufficient thickness on the silicon rich nitride, the first polysilicon gate interconnect layer and oxidizing the silicon substrate of step (h); (j) depositing a layer of silicon rich oxide on the oxide layer of step (i); (k) depositing a second polysilicon layer on the silicon rich oxide of step (j); and (l) patterning the second polysilicon layer of step (k) to form at least one gate electrode.
Claim 2
Independent Claim
228 words
A method for incorporating a non-continuous DEIS structure between multiple layers of polysilicon in an array of devices on an integrated circuit substrate comprising the following steps: (a) fabricating at least one thin oxide region surrounded by thick oxide regions on a silicon substrate; (b) depositing a first polysilicon gate interconnect layer on the substrate; (c) depositing a layer of silicon rich nitride on said polysilicon gate interconnect layer; (d) patterning a first photoresist mask on the silicon rich nitride layer with said photoresist mask defining a profile for the silicon rich nitride; (e) etching the uncovered areas of the silicon rich nitride; (f) patterning a second mask on the first polysilicon gate interconnect layer with said second mask defining a profile for the first polysilicon gate interconnect layer; (g) etching the uncovered areas of the first polysilicon gate interconnect layer; (h) etching back the thin oxide region in step (a) to the silicon substrate; (i) growing an oxide layer of sufficient thickness on the silicon rich nitride, the first polysilicon gate interconnect layer and oxidizing the silicon substrate of step (h); (j) depositing a layer of silicon rich oxide on the oxide layer of step (i); (k) depositing a second polysilicon layer on the silicon rich oxide of step (j); and (l) patterning the second polysilicon layer of step (k) to form at least one gate electrode.
Claim 3
Dependent Claim
26 words
The method of claim 1 wherein the silicon rich nitride layer of step (c) is being deposited in a plasma enhanced chemical vapor deposition (PECVD) system.
Claim 4
Dependent Claim
71 words
The method of claim 2 wherein the PECVD system includes the conditions of: (a) a pressure of 375 microns of mercury, said pressure being attained with a mixture of 1.5% SiH 4 in argon and 0.4 cc/min. of O 2 ; (b) backfilling the chamber to 1800 microns with N 2 ; and (c) resistively heating the substrate to 350° C. and the rf energy is being maintained at 125 watts.
Claim 5
Dependent Claim
30 words
The method of claim 2 further including a deposition time in the order of 60 seconds to give a deposit thickness of approximately 450° A and refractive index of 1.85.
Claim 6
Dependent Claim
83 words
The method of claim 1 wherein the silicon rich oxide layer of step (j) is being deposited by e PECVD system having the conditions of: (a) a pressure of 375 microns of mercury, said pressure being attained with a mixture of 1.5% SiH 4 in argon and 0.7 cc/min. of O 2 ; (b) backfilling the chamber to 1800 microns with N 2 ; and (c) resistively heating the substrate to 350° C. and the rf energy is being maintained at 125 watts.
Claim 7
Independent Claim
167 words
A method for fabricating an improved semi-conductor module comprising the steps of: (a) providing a silicon substrate having at least one thin oxide region thereon; (b) depositing a first polysilicon gate interconnecting layer on the substrate; (c) depositing a silicon rich nitride (SRN) layer on the first polysilicon gate interconnecting layer; (d) depositing a silicon dioxide (SiO 2 ) layer on the SRN layer; (e) masking the SiO 2 layer; (f) etching the unmasked section of the SRN layer, the SiO 2 layer and the unmasked section of first polysilicon gate layer; (g) etching back the thin oxide region of step (a) to the silicon substrate; (h) stripping the mask in step (e); (i) thermally oxidizing the module; (j) depositing a layer of silicon rich oxide on the SiO 2 layer of step (d); (k) depositing a second polysilicon gate interconnecting layer on the silicon rich oxide layer in step (j); and (l) generating gate electrode and poly 2 devices in said interconnecting layer of step (k).
Claim 8
Independent Claim
167 words
A method for fabricating an improved semi-conductor module comprising the steps of: (a) providing a silicon substrate having at least one thin oxide region thereon; (b) depositing a first polysilicon gate interconnecting layer on the substrate; (c) depositing a silicon rich nitride (SRN) layer on the first polysilicon gate interconnecting layer; (d) depositing a silicon dioxide (SiO 2 ) layer on the SRN layer; (e) masking the SiO 2 layer; (f) etching the unmasked section of the SRN layer, the SiO 2 layer and the unmasked section of first polysilicon gate layer; (g) etching back the thin oxide region of step (a) to the silicon substrate; (h) stripping the mask in step (e); (i) thermally oxidizing the module; (j) depositing a layer of silicon rich oxide on the SiO 2 layer of step (d); (k) depositing a second polysilicon gate interconnecting layer on the silicon rich oxide layer in step (j); and (l) generating gate electrode and poly 2 devices in said interconnecting layer of step (k).
Claim 9
Dependent Claim
15 words
The method of claim 6 wherein the silicon rich nitride layer is approximately 15 nm.
Claim 10
Dependent Claim
14 words
The method of claim 7 wherein the SiO 2 layer is approximately 10 nm.
Claim 11
Dependent Claim
17 words
The method of claim 8 wherein the SiO 2 layer is being formed by a PECVD system.
Claim 12
Dependent Claim
68 words
The method of claim 9 wherein the PECVD system includes the condition of: (a) a pressure of 100 microns of mercury being attained with a mixture of 1.5% SiH 4 in argon and 3.0 cc/min. of O 2 ; (b) back filling the chamber with N2 to 1600 microns; and (c) resistively heating the substrate to 350° C. with an rf energy being maintained at approximately 125 watts.
Claim 13
Dependent Claim
31 words
The method of claim 9 further including the conditions of utilizing a deposition time of approximately 80 seconds thereby giving a deposited thickness of 100° A and refractive index of 1.47.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-04-13 | 1990-10-13 | 1991-04-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-04-13 | 1994-10-13 | 1995-04-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-04-13 | 1998-10-13 | 1999-04-14 | $7700.00 | Window Closed / Lapsed |