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US4654318A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for preparing catalyst component for polymerization of olefins

Assignee: Tonen General Sekiyu KK
•
Filing: 1985-02-26
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Granted: 1987-03-31
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Expires: 2005-02-26
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Abstract

Abstract A process for preparing a catalyst component for the polymerization of olefins which comprises the steps of contacting (a) a magnesium dialkoxide soluble in an inert solvent, (b) a silicon compound having the hydrogen-silicon bond, and (c) an electron donor compound with one another in the presence of an inert solvent, and contacting the resulting reaction product with (d) a titanium compound.

Inventors

  • 👤 Tadashi Yamamoto
  • 👤 Masafumi Imai
  • 👤 Hiroyuki Furuhashi
  • 👤 Hiroshi Ueno
  • 👤 Naomi Inaba

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 00:26
CPC Classifications
C; C08; C08F; C08F10/00

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 103 words
A catalyst component comprising: A titanium containing catalyst component obtained by contacting (i) Component A, a magnesium dialkoxide soluble in inert solvents represented by the formula Mg(OR)(OR 1 ) wherein R and R 1 are the same or different branched alkyls or alkyl substituted cycloalkyls, each R and R 1 having 7 or more carbon atoms, (ii) Component B, a silicon compound having a hydrogen-silicon bond (iii) Component C, an electron donor compound, and (iiii) a titanium compound with the proviso that Component A, B and C are contacted with one another in an inert solvent prior to contact with the titanium compound.
Claim 2
Dependent Claim 103 words
A catalyst component comprising: A titanium containing catalyst component obtained by contacting (i) Component A, a magnesium dialkoxide soluble in inert solvents represented by the formula Mg(OR)(OR 1 ) wherein R and R 1 are the same or different branched alkyls or alkyl substituted cycloalkyls, each R and R 1 having 7 or more carbon atoms, (ii) Component B, a silicon compound having a hydrogen-silicon bond (iii) Component C, an electron donor compound, and (iiii) a titanium compound with the proviso that Component A, B and C are contacted with one another in an inert solvent prior to contact with the titanium compound.
Claim 3
Dependent Claim 17 words
The catalyst component of claim 1 wherein the silicon compound is selected from trichlorosilane, methyldichlorosilane and dimethylchlorosilane.
Claim 4
Dependent Claim 24 words
The catalyst component of claim 1 wherein the magnesium alkoxide is selected from magnesium di-2-ethylhexyloxide, magnesium di-1-methylhexyloxide, magnesium di-1-ethylpentyloxide, magnesium di-1-methylheptyloxide, and magnesium di-1-ethylhexyloxide.
Claim 5
Dependent Claim 30 words
The catalyst component of claim 1 wherein the electron donor compounds are selected from ethyl benzoate, diisobutylphthalate, benzoic acid anhydride, benzoyl chloride, diisobutylphthalate, phalic acid-di-chloride, phthalic acid anhydride and n-butylmaleate.
Claim 6
Dependent Claim 21 words
The catalyst component of claim 1 wherein Component A is magnesium di-2-ethylhexyloxide, component B is trichlorosilane and Component C is ethylbenzoate.
Claim 7
Dependent Claim 24 words
An olefin polymerization catalyst comprising the catalyst component of claim 1 and an organo metal compound of Groups I-III metals of the Periodic Table.
Claim 8
Dependent Claim 24 words
An olefin polymerization catalyst comprising the catalyst component of claim 2 and an organo metal compound of Groups I-III metals of the Periodic Table.
Claim 9
Dependent Claim 24 words
An olefin polymerization catalyst comprising the catalyst component of claim 3 and an organo metal compound of Groups I-III metals of the Periodic Table.
Claim 10
Dependent Claim 24 words
An olefin polymerization catalyst comprising the catalyst component of claim 4 and an organo metal compound of Groups I-III metals of the Periodic Table.
Claim 11
Dependent Claim 24 words
An olefin polymerization catalyst comprising the catalyst compound of claim 5 and an organo metal compound of Groups I-III metals of the Periodic Table.
Claim 12
Dependent Claim 12 words
The olefin polymerization catalyst of claim 6 wherein the cocatalyst is triethylaluminum.
Claim 13
Dependent Claim 20 words
The olefin polymerization catalyst of claim 6 which is further combined with an electron donor compound and/or an organosilicon compound.
Claim 14
Dependent Claim 18 words
The olefin polymerization catalyst of claim 12 wherein the electron donor is selected from ethyl benzoate and ethyl-p-anisate.
Claim 15
Dependent Claim 19 words
The olefin polymerization catalyst of claim 12 wherein the electron donor compound is a sterically hindered electron donor compound.
Claim 16
Dependent Claim 14 words
The olefin polymerization catalyst of claim 14 wherein the electron donor compound is 2,2,6,6-tetramethylpiperidine.
Claim 17
Dependent Claim 14 words
The olefin polymerization catalyst of claim 12 wherein the organo silicon compound is phenyltriethoxysilane.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-03-30 1990-09-29 1991-03-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-03-30 1994-09-29 1995-03-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-03-30 1998-09-29 1999-03-31 $7700.00 Window Closed / Lapsed

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