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US4464478A Expired / Lapsed US ⏱️ 0.0 years remaining

Catalyst components and catalysts for polymerizing olefins

Assignee: Montedison SpA
•
Filing: 1982-09-30
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Granted: 1984-08-07
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Expires: 2002-09-30
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Abstract

Abstract Catalyst-forming components are prepared from (a) a halogenated Ti compound containing at least a Ti-halogen bond; (b) an electron-donor compound free of active hydrogen atoms; and (c) the solid product of the reaction between at least one electron-donor compound containing active hydrogen atoms and a Mg dihalide or a complex thereof with an electron-donor compound free of active hydrogen atoms, obtained by decomposing organic Mg compounds containing at least one Mg-R or Mg-OR group, in which R is an alkyl, aryl, cycloalkyl or alkenyl radical having 1 to 20 carbon atoms, by means of a halogenating agent different from (a). Catalysts for polymerizing olefins and prepared by mixing the aforesaid catalyst-forming components with an organometallic compound of Al are also disclosed.

Inventors

  • 👤 Umberto Scata
  • 👤 Enrico Albizzati
  • 👤 Enzo Giannetti

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 07:56
CPC Classifications
C; C08; C08F; C08F10/00; C08F4/00; C08F4/02; C08F4/022

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 250 words
Process for preparing components of catalysts for the polymerization of olefins which comprises mixing the solid product of the reaction of: (a) a halogenated Ti-compound containing at least a Ti-halogen bond, and (b) an electron-donor compound which does not contain active hydrogen atoms (ED) reacted as such or as a complex with product (c) prepared without cogrinding of the product (c) with compound (ED), and employed in such amount and under such conditions, that from 0.2 to 4 moles of compound (ED) per gram atom of Ti of compound (a) are present in the catalyst component; with (c) the solid product prepared without cogrinding, of the reaction between at least one electron-donor compound containing active hydrogen atoms (HED), selected from among the group consisting of aliphatic, cycloaliphatic and aromatic alcohols and thioalcohols having 1 to 20 C, phenols and thiophenols having 6 to 20 C and silanols having 1 to 20 C, and a Mg dihalide, or a complex of said Mg dihalide with a compound (ED), obtained by reaction of halogenating agents other than the Ti compounds of (a), with an organic Mg compound of formula: R.sub.m MgX.sub.n in which R is an alkyl, alkenyl, cycloalkyl or aryl radical containing 1 to 20 C, or a group OR, X is a halogen or a radical R, OR or COX' in which R has the meaning stated, X' is halogen, 0<m≦2, 0≦n<2, and n+m is 2, product (c) being reacted as such, without any intermediate pretreatment with an Al-alkyl compound.
Claim 2
Dependent Claim 250 words
Process for preparing components of catalysts for the polymerization of olefins which comprises mixing the solid product of the reaction of: (a) a halogenated Ti-compound containing at least a Ti-halogen bond, and (b) an electron-donor compound which does not contain active hydrogen atoms (ED) reacted as such or as a complex with product (c) prepared without cogrinding of the product (c) with compound (ED), and employed in such amount and under such conditions, that from 0.2 to 4 moles of compound (ED) per gram atom of Ti of compound (a) are present in the catalyst component; with (c) the solid product prepared without cogrinding, of the reaction between at least one electron-donor compound containing active hydrogen atoms (HED), selected from among the group consisting of aliphatic, cycloaliphatic and aromatic alcohols and thioalcohols having 1 to 20 C, phenols and thiophenols having 6 to 20 C and silanols having 1 to 20 C, and a Mg dihalide, or a complex of said Mg dihalide with a compound (ED), obtained by reaction of halogenating agents other than the Ti compounds of (a), with an organic Mg compound of formula: R.sub.m MgX.sub.n in which R is an alkyl, alkenyl, cycloalkyl or aryl radical containing 1 to 20 C, or a group OR, X is a halogen or a radical R, OR or COX' in which R has the meaning stated, X' is halogen, 0<m≦2, 0≦n<2, and n+m is 2, product (c) being reacted as such, without any intermediate pretreatment with an Al-alkyl compound.
Claim 3
Dependent Claim 111 words
The process of claim 1, in which compound (a) is a Ti tetrahalide, (b) compound (ED) is an alkyl, aryl or cycloalkyl ester of benzoic acid or of derivatives thereof, and (c) is the product of the reaction of 0.1 mole to 6 moles of an aliphatic alcohol or of a phenol with 1 mole of Mg dichloride or Mg dibromide, or a complex thereof with ethers, obtained through decomposition with halogenating agents selected from the group consisting of halogenated compounds of Si, SOCl 2 , an Al alkyl halide and SnCl 4 , of mono- and dialkyl Mg compounds, or complexes thereof with ethers, or of Mg mono- and dialcoholates.
Claim 4
Dependent Claim 20 words
Catalysts for polymerizing olefins, prepared by mixing catalyst components obtained by the process of claim 1, with organometallic aluminum compounds.
Claim 5
Dependent Claim 15 words
Catalysts according to claim 3, in which the organometallic Al compound is an Al trialkyl.
Claim 6
Dependent Claim 24 words
Catalysts according to claim 4, in which the aluminum trialkyl compound is complexed with from 0.1 mole to 1 mole of electron-donor compound (ED).

References Cited (Backward Citations)

US4076924A Cited
US4115319A Cited
US4143223A Cited
US4189553A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-08-07 1988-02-06 1988-08-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-08-07 1992-02-06 1992-08-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-08-07 1996-02-06 1996-08-07 $7700.00 Window Closed / Lapsed

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