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US4654138A Expired / Lapsed US ⏱️ 0.0 years remaining

Catalytic process for modifying organic compounds

Assignee: Mobil Oil AS
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Filing: 1984-08-21
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Granted: 1987-03-31
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Expires: 2004-08-21
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Abstract

Abstract The crystalline silicophosphoaluminate designated MCM-10 catalyzes various processes for modifying organic compounds, particularly the cracking of hydrocarbons and the conversion of alcohols and ethers to olefins.

Inventors

  • 👤 Eric G. Derouane
  • 👤 Ernest W. Valyocsik
  • 👤 Roland von Ballmoos

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 04:19
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/82; B01J20/00; B01J20/02; B01J20/10; B01J20/16; B01J20/18; B01J29/84; B01J29/85; B01J39/00; B01J39/08; B01J39/12; C; C01; C01B; C01B33/00; C01B33/20; C01B33/26; C01B33/28; C01B37/00; C01B37/06; C01B37/08; B01J2229/00; B01J2229/10; B01J2229/26; B01J2229/30; B01J2229/42

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 186 words
A process for cracking hydrocarbons, said process comprising contacting said hydrocarbons with a catalyst under hydrocarbon cracking conditions at a temperature of from about 300° C. to about 700° C., a pressure of from about 0.1 atmosphere to about 30 atmospheres and a weight hourly space velocity of from 0.1 hr. -1 to about 20 hr. -1 , said catalyst comprising a synthetic crystalline material comprising silicon, phosphorus and aluminum which, as synthesized, exhibits a characteristic X-ray diffraction pattern as shown in Table 1-A of the specification, and which in the anhydrous crystalline form has the formula: (AlO.sub.2).sub.1-y.sup.- :(PO.sub.2).sub.1-x.sup.+ :(SiO.sub.2).sub.x+y wherein x and y are numbers of from greater than -1 to less than+1 which satisfy the relationships: (1) if x is 0, then y is not 0, (2) if y is 0, then x is not 0, (3) if the atomic ratio of Al/P is greater than 1, then (x+y) is greater than 0.001 and y+0.6x is less than 0.4, and (4) if the atomic ratio of Al/P is less than 1, then (x+y) is greater than 0.001 and X+0.5 y is less than 0.5.
Claim 2
Dependent Claim 186 words
A process for cracking hydrocarbons, said process comprising contacting said hydrocarbons with a catalyst under hydrocarbon cracking conditions at a temperature of from about 300° C. to about 700° C., a pressure of from about 0.1 atmosphere to about 30 atmospheres and a weight hourly space velocity of from 0.1 hr. -1 to about 20 hr. -1 , said catalyst comprising a synthetic crystalline material comprising silicon, phosphorus and aluminum which, as synthesized, exhibits a characteristic X-ray diffraction pattern as shown in Table 1-A of the specification, and which in the anhydrous crystalline form has the formula: (AlO.sub.2).sub.1-y.sup.- :(PO.sub.2).sub.1-x.sup.+ :(SiO.sub.2).sub.x+y wherein x and y are numbers of from greater than -1 to less than+1 which satisfy the relationships: (1) if x is 0, then y is not 0, (2) if y is 0, then x is not 0, (3) if the atomic ratio of Al/P is greater than 1, then (x+y) is greater than 0.001 and y+0.6x is less than 0.4, and (4) if the atomic ratio of Al/P is less than 1, then (x+y) is greater than 0.001 and X+0.5 y is less than 0.5.
Claim 3
Dependent Claim 179 words
A process for converting alcohols or ethers to olefins by contacting said alcohols or ethers at a temperature of from about 275° C. to about 600° C., a pressure of from about 0.5 atmosphere to about 50 atmospheres, and a liquid hourly space velocity of from about 0.5 to about 100, with a synthetic crystalline material comprising silicon, phosphorus and aluminum which, as synthesized, exhibits a characteristic X-ray diffraction pattern as shown in Table 1-A of the specification, and which in the anhydrous crystalline form has the formula: (AlO.sub.2).sub.1-y.sup.- :(PO.sub.2).sub.1-x.sup.+ :(SiO.sub.2).sub.x+y wherein x and y are numbers of from greater than -1 to less than +1 which satisfy the relationships: (1) if x is 0, then y is not 0, (2) if y is 0, then x is not 0, (3) if the atomic ratio of Al/P is greater than 1, then (x+y) is greater than 0.001 and y+0.6 x is less than 0.4, and (4) if the atomic ratio of Al/P is less than 1, then (x+y) is greater than 0.001 and X+0.5 y is less than 0.5.
Claim 4
Dependent Claim 179 words
A process for converting alcohols or ethers to olefins by contacting said alcohols or ethers at a temperature of from about 275° C. to about 600° C., a pressure of from about 0.5 atmosphere to about 50 atmospheres, and a liquid hourly space velocity of from about 0.5 to about 100, with a synthetic crystalline material comprising silicon, phosphorus and aluminum which, as synthesized, exhibits a characteristic X-ray diffraction pattern as shown in Table 1-A of the specification, and which in the anhydrous crystalline form has the formula: (AlO.sub.2).sub.1-y.sup.- :(PO.sub.2).sub.1-x.sup.+ :(SiO.sub.2).sub.x+y wherein x and y are numbers of from greater than -1 to less than +1 which satisfy the relationships: (1) if x is 0, then y is not 0, (2) if y is 0, then x is not 0, (3) if the atomic ratio of Al/P is greater than 1, then (x+y) is greater than 0.001 and y+0.6 x is less than 0.4, and (4) if the atomic ratio of Al/P is less than 1, then (x+y) is greater than 0.001 and X+0.5 y is less than 0.5.

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Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-03-30 1990-09-29 1991-03-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-03-30 1994-09-29 1995-03-31 $3760.00 Window Closed / Lapsed
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