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US4158621A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for increasing gasoline yield and quality during catalytic cracking of high metals content charge stocks using an alumina-aluminum phosphate-silica-zeolite catalyst

Assignee: Gulf Research and Development Co
•
Filing: 1978-07-21
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Granted: 1979-06-19
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Expires: 1998-07-21
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Abstract

Abstract A process for cracking gasoline feedstock with greater selectivity of gasoline production and greater metals tolerance wherein, said gasoline feedstock is brought into contact with a catalyst comprising a zeolite dispersed in an alumina-aluminum phosphate-silica matrix, said matrix having outstanding thermal stability.

Inventors

  • 👤 Harold E. Swift
  • 👤 John J. Stanulonis
  • 👤 Elizabeth H. Reynolds

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 01:58
CPC Classifications
C; C10; C10G; C10G11/00; C10G11/02; C10G11/04; C10G11/05; B; B01; B01J; B01J27/00; B01J27/14; B01J27/16; B01J27/18; B01J29/00; B01J29/04; B01J29/06; B01J29/08; B01J29/084; B01J35/00; B01J35/60; B01J35/61; B01J35/615; B01J35/63; B01J35/635; B01J35/64; B01J35/647

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 149 words
A process for increasing the gasoline yield and quality in a petroleum cracking reaction by contacting a hydrocarbon feedstock under catalytic cracking conditions with a catalyst comprising an alumina-aluminum phosphate-silica matrix characterized after calcination at 500° C. for 16 hours as amorphous, and having an average pore radius of from about 10° A to about 200° A; a surface area ranging from about 50 m 2 /g to about 300 m 2 /g; a pore volume of from about 0.1 cc/g to about 1.2 cc/g; and wherein the alumina-aluminum phosphate-silica matrix has a mole percent ratio of from about 15:80:5 to about 60:10:30 and wherein said matrix retains at least 70% of its surface area when the matrix is additionally calcined at a temperature up to about 900° C. for about 16 hours; said matrix being composited with from about 5 to about 50 weight percent of a REY-zeolite.
Claim 2
Dependent Claim 149 words
A process for increasing the gasoline yield and quality in a petroleum cracking reaction by contacting a hydrocarbon feedstock under catalytic cracking conditions with a catalyst comprising an alumina-aluminum phosphate-silica matrix characterized after calcination at 500° C. for 16 hours as amorphous, and having an average pore radius of from about 10° A to about 200° A; a surface area ranging from about 50 m 2 /g to about 300 m 2 /g; a pore volume of from about 0.1 cc/g to about 1.2 cc/g; and wherein the alumina-aluminum phosphate-silica matrix has a mole percent ratio of from about 15:80:5 to about 60:10:30 and wherein said matrix retains at least 70% of its surface area when the matrix is additionally calcined at a temperature up to about 900° C. for about 16 hours; said matrix being composited with from about 5 to about 50 weight percent of a REY-zeolite.
Claim 3
Dependent Claim 25 words
The process according to claim 1 wherein the alumina-aluminum phosphate-silica matrix has an average pore radius of from about 75° A to about 150° A.
Claim 4
Dependent Claim 27 words
The process of claim 1 wherein the alumina-aluminum phosphate-silica matrix has a surface area of from about 125 m 2 /g to about 275 m 2 /g.
Claim 5
Dependent Claim 24 words
The process according to claim 1 wherein the alumina-aluminum phosphate-silica matrix has a pore volume of from about 0.6 cc/g to about 1.0 cc/g.
Claim 6
Dependent Claim 23 words
The process of claim 1 wherein the alumina-aluminum phosphate-silica matrix has a mole percent ratio range of from about 30:60:10 to about 50:30:20.
Claim 7
Dependent Claim 23 words
The process according to claim 1 wherein from about 5 to about 35 weight percent REY-zeolite is composited with the alumina-aluminum phosphate-silica matrix.
Claim 8
Dependent Claim 38 words
The process of claim 1 wherein the REY-zeolite contains a rare earth metal selected from the group consisting of cerium, lanthanum, praseodymium, neodymium, illinium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, scandium, yttrium, lutecium and mixtures thereof.
Claim 9
Dependent Claim 29 words
The process according to claim 1 wherein the REY-zeolite contains a rare earth metal selected from the group consisting of cerium, lanthanum, praseodymium, neodymium, samarium, gadolinium, and mixtures thereof.
Claim 10
Dependent Claim 15 words
The process according to claim 1 wherein the REY-zeolite is a type Y synthetic faujasite.
Claim 11
Dependent Claim 14 words
The process according to claim 1 wherein the hydrocarbon feedstock is a gas oil.
Claim 12
Dependent Claim 24 words
The process of claim 1 wherein the hydrocarbon feedstock and catalyst are contacted at a molar ratio of from about 4:1 to about 12:1.
Claim 13
Dependent Claim 24 words
The process of claim 1 wherein the hydrocarbon feedstock and catalyst are contacted at a molar ratio of from about 6:1 to about 10:1.
Claim 14
Dependent Claim 26 words
The process according to claim 1 wherein the hydrocarbon feedstock and catalyst are contacted at a temperature of from about 400° C. to about 760° C.
Claim 15
Dependent Claim 26 words
The process according to claim 1 wherein the hydrocarbon feedstock and catalyst are contacted at a temperature of from about 475° C. to about 650° C.
Claim 16
Dependent Claim 16 words
The process of claim 1 wherein the hydrocarbon feedstock and catalyst are contacted at atmospheric pressure.
Claim 17
Dependent Claim 26 words
The process according to claim 1 wherein the hydrocarbon feedstock and catalyst are contacted at an hourly space velocity of from about 35 to about 500.
Claim 18
Dependent Claim 25 words
The process of claim 1 wherein the hydrocarbon feedstock and catalyst are contacted at an hourly space velocity of from about 50 to about 300.

References Cited (Backward Citations)

US3271299A Cited
US3342750A Cited
US3867279A Cited
US3944482A Cited
US3904550A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-06-18 1982-12-18 1983-06-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-06-18 1986-12-18 1987-06-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-06-18 1990-12-18 1991-06-19 $7700.00 Window Closed / Lapsed

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