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US4158621A
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Process for increasing gasoline yield and quality during catalytic cracking of high metals content charge stocks using an alumina-aluminum phosphate-silica-zeolite catalyst
Assignee: Gulf Research and Development Co
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Filing: 1978-07-21
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Granted: 1979-06-19
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Expires: 1998-07-21
Abstract
Abstract A process for cracking gasoline feedstock with greater selectivity of gasoline production and greater metals tolerance wherein, said gasoline feedstock is brought into contact with a catalyst comprising a zeolite dispersed in an alumina-aluminum phosphate-silica matrix, said matrix having outstanding thermal stability.
Inventors
- 👤 Harold E. Swift
- 👤 John J. Stanulonis
- 👤 Elizabeth H. Reynolds
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 17:58
CPC Classifications
C; C10; C10G; C10G11/00; C10G11/02; C10G11/04; C10G11/05; B; B01; B01J; B01J27/00; B01J27/14; B01J27/16; B01J27/18; B01J29/00; B01J29/04; B01J29/06; B01J29/08; B01J29/084; B01J35/00; B01J35/60; B01J35/61; B01J35/615; B01J35/63; B01J35/635; B01J35/64; B01J35/647
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
149 words
A process for increasing the gasoline yield and quality in a petroleum cracking reaction by contacting a hydrocarbon feedstock under catalytic cracking conditions with a catalyst comprising an alumina-aluminum phosphate-silica matrix characterized after calcination at 500° C. for 16 hours as amorphous, and having an average pore radius of from about 10° A to about 200° A; a surface area ranging from about 50 m 2 /g to about 300 m 2 /g; a pore volume of from about 0.1 cc/g to about 1.2 cc/g; and wherein the alumina-aluminum phosphate-silica matrix has a mole percent ratio of from about 15:80:5 to about 60:10:30 and wherein said matrix retains at least 70% of its surface area when the matrix is additionally calcined at a temperature up to about 900° C. for about 16 hours; said matrix being composited with from about 5 to about 50 weight percent of a REY-zeolite.
Claim 2
Dependent Claim
149 words
A process for increasing the gasoline yield and quality in a petroleum cracking reaction by contacting a hydrocarbon feedstock under catalytic cracking conditions with a catalyst comprising an alumina-aluminum phosphate-silica matrix characterized after calcination at 500° C. for 16 hours as amorphous, and having an average pore radius of from about 10° A to about 200° A; a surface area ranging from about 50 m 2 /g to about 300 m 2 /g; a pore volume of from about 0.1 cc/g to about 1.2 cc/g; and wherein the alumina-aluminum phosphate-silica matrix has a mole percent ratio of from about 15:80:5 to about 60:10:30 and wherein said matrix retains at least 70% of its surface area when the matrix is additionally calcined at a temperature up to about 900° C. for about 16 hours; said matrix being composited with from about 5 to about 50 weight percent of a REY-zeolite.
Claim 3
Dependent Claim
25 words
The process according to claim 1 wherein the alumina-aluminum phosphate-silica matrix has an average pore radius of from about 75° A to about 150° A.
Claim 4
Dependent Claim
27 words
The process of claim 1 wherein the alumina-aluminum phosphate-silica matrix has a surface area of from about 125 m 2 /g to about 275 m 2 /g.
Claim 5
Dependent Claim
24 words
The process according to claim 1 wherein the alumina-aluminum phosphate-silica matrix has a pore volume of from about 0.6 cc/g to about 1.0 cc/g.
Claim 6
Dependent Claim
23 words
The process of claim 1 wherein the alumina-aluminum phosphate-silica matrix has a mole percent ratio range of from about 30:60:10 to about 50:30:20.
Claim 7
Dependent Claim
23 words
The process according to claim 1 wherein from about 5 to about 35 weight percent REY-zeolite is composited with the alumina-aluminum phosphate-silica matrix.
Claim 8
Dependent Claim
38 words
The process of claim 1 wherein the REY-zeolite contains a rare earth metal selected from the group consisting of cerium, lanthanum, praseodymium, neodymium, illinium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, scandium, yttrium, lutecium and mixtures thereof.
Claim 9
Dependent Claim
29 words
The process according to claim 1 wherein the REY-zeolite contains a rare earth metal selected from the group consisting of cerium, lanthanum, praseodymium, neodymium, samarium, gadolinium, and mixtures thereof.
Claim 10
Dependent Claim
15 words
The process according to claim 1 wherein the REY-zeolite is a type Y synthetic faujasite.
Claim 11
Dependent Claim
14 words
The process according to claim 1 wherein the hydrocarbon feedstock is a gas oil.
Claim 12
Dependent Claim
24 words
The process of claim 1 wherein the hydrocarbon feedstock and catalyst are contacted at a molar ratio of from about 4:1 to about 12:1.
Claim 13
Dependent Claim
24 words
The process of claim 1 wherein the hydrocarbon feedstock and catalyst are contacted at a molar ratio of from about 6:1 to about 10:1.
Claim 14
Dependent Claim
26 words
The process according to claim 1 wherein the hydrocarbon feedstock and catalyst are contacted at a temperature of from about 400° C. to about 760° C.
Claim 15
Dependent Claim
26 words
The process according to claim 1 wherein the hydrocarbon feedstock and catalyst are contacted at a temperature of from about 475° C. to about 650° C.
Claim 16
Dependent Claim
16 words
The process of claim 1 wherein the hydrocarbon feedstock and catalyst are contacted at atmospheric pressure.
Claim 17
Dependent Claim
26 words
The process according to claim 1 wherein the hydrocarbon feedstock and catalyst are contacted at an hourly space velocity of from about 35 to about 500.
Claim 18
Dependent Claim
25 words
The process of claim 1 wherein the hydrocarbon feedstock and catalyst are contacted at an hourly space velocity of from about 50 to about 300.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-06-18 | 1982-12-18 | 1983-06-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-06-18 | 1986-12-18 | 1987-06-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-06-18 | 1990-12-18 | 1991-06-19 | $7700.00 | Window Closed / Lapsed |