Siloxane-containing polymers

Claim 2

A composition capable of being converted into a polyimide or poly(amide-imide) which, when present in the form of a shaped article, is relatively free of voids, pinholes, cracks and bubbles, said composition comprising a polyamic acid containing about 0.75 to about 5 mole percent of a polysiloxane incorporated in its backbone, dissolved in a solvent selected from the group consisting of tetrahydrofuran, m-dioxane, p-dioxane, monoglyme, diglyme, triglyme, tetraglyme and mixtures thereof.

Claim 3

The composition of claim 1 in which the polyamic acid is present in the solvent in an amount of about 5 to about 50 weight percent.

Claim 4

The composition of claim 2 in which the polyamic acid is present in the solvent in an amount of 20 to 40 weight percent.

Claim 5

The composition of claim 1 in which the polysiloxane is present in an amount of 1.5 to 2.5 mole percent.

Claim 6

The composition of claim 1 in which the polysiloxane has a monomeric unit formula of ##STR51## or of formula ##STR52## where Q is a substituted or unsubstituted aromatic group, Z is --O--, --S--, ##STR53## R and D is each unsubstituted or substituted hydrocarbylene; R 1 , R 2 , R 3 , R 4 , R 5 and R 6 each, independently, is unsubstituted or substituted hydrocarbyl; x, y and z each independently has a value from 0 to 100, and w has a value from 1 to 100.

Claim 7

The composition of claim 5 in which the polysiloxane has a monomeric unit formula of ##STR54## in which Q is substituted or unsubstituted carbocyclic aromatic of 6 to 18 ring carbon atoms or substituted or unsubstituted heterocyclic aromatic of 5 to 18 ring atoms where the hetero atoms are selected from the group consisting of N, O and S and where any substituents present are selected from the group consisting of alkyl of 1 to 12 carbon atoms, alkynyl of 2 to 12 carbon atoms, cycloalkyl of 4 to 8 carbon atoms, alkoxy of 1 to 12 carbon atoms, alkylthio of 1 to 12 carbon atoms, phenyl, alkylphenylene having 1 to 12 carbon atoms in the alkyl group, phenoxy, phenylthio, alkylcarbonyloxy of 2 to 12 carbon atoms, alkoxycarbonyl of 2 to 12 carbon atoms, bromo, chloro, fluoro, iodo, nitro, cyano, cyanothio, carbonyl, hydroxy, mercapto, formyl, thioformyl and mercaptocarbonyl; D is substituted or unsubstituted hydrocarbylene of 1 to 3 to 18 carbon atoms; R 1 , R 2 , R 3 , R 4 , R 5 and R 6 , each independently, is an unsubstituted or substituted alkyl of 1 to 12 carbon atoms, alkenyl of 2 to 12 carbon atoms, alkynyl of 2 to 12 carbon atoms, cycloalkyl of 4 to 8 carbon atoms, phenyl, alkylphenylene where the alkyl group contains 1 to 12 carbon atoms, phenylalkylene where the alkylene group contains 1 to 12 carbon atoms in the alkenyl group and when substituted, these hydrocarbyl groups are substituted by Br, Cl, I, R, --NC, --NO 2 , --OCN, alkoxy of 1 to 8 carbon atoms, --S--(C 1 -C 8 )alkyl, ##STR55## --S--S--(C 1 -C 8 )alkyl, --COOH, --COSH, --CSOH, --CONH 2 , --CN, --CHO, --CHS, --OH, --SH, --NCO and --NR 7 R 8 where R 7 and R 8 independently are hydrogen or lower alkyl.

Claim 8

The composition of claim 6 in which Q is unsubstituted or substituted carbocyclic aromatic of 6 to 18 carbon atoms; D is branched or linear alkylene of 1 or 3 to 12 carbon atoms; and x, y and z is each 0,

Claim 9

The composition of claim 7 in which the polysiloxane has a monomeric unit formula of ##STR56## where v is 0 or 4; R 9 is lower alkyl, lower alkenyl, lower alkynyl, cycloalkyl of 4 to 8 carbon atoms, lower alkoxy, lower alkylthio, phenyl, loweralkylphenylene, phenylloweralkylene, loweralkenylphenylene, phenoxy, phenylthio, loweralkylcarbonyl, loweralkylcarbonyloxy, loweralkoxycarbonyl, bromo, chloro, fluoro, iodo, nitro, cyano, cyanthio, carboxyl, carbonyl, hydroxyl, mercapto, or mercaptocarbonyl; Z is --O--, --S--, ##STR57## D 1 is methylene or alkylene of 3 to 8 carbon atoms; R 1 is lower alkyl, lower alkenyl, lower alkynyl, phenyl, loweralkylphenylene, phenylloweralkylene, or lower alkenylphenylene.

Claim 10

The composition of claim 5 in which the polysiloxane has a unit formula of ##STR58## wherein R" is alkylene or arylene and each R"' is independently C 1 -C 4 alkyl or phenyl.

Claim 11

The composition of claim 9 in which the polysiloxane has a monomeric unit formula of ##STR59## wherein n is an integer of 1 to 6, a has a value of 1 to 30 and each R"' is independently C 1 -C 4 alkyl or phenyl.

Claim 12

The composition of claim 10 in which the polysiloxane has the monomeric unit formula of ##STR60##

Claim 13

The composition of claim 11 in which the polysiloxane has the monomeric unit formula of ##STR61##

Claim 14

The composition of claim 1 in which the polyamic acid is prepared by reacting benzophenone tetracarboxylic acid dianhydride with 3,3' diaminodiphenyl sulfoxide in the presence of 1.5 to 2.5 mole percent of a bis(amino)polysiloxane having the formula ##STR62##

Claim 15

The composition of claim 1 in which the solvent is diglyme.