Patent US4652391A successfully refreshed from Google Patents.
US4652391A
Expired / Lapsed
US
⏱️ 0.0 years remaining
High powder density free-flowing detergent
Assignee: Henkel AG and Co KGaA
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Filing: 1985-09-23
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Granted: 1987-03-24
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Expires: 2005-09-23
Abstract
Abstract A process for the production of a granular, free-flowing detergent composition which is rapidly soluble in water, and the product thereof which has a bulk density of at least 600 g/l and a particle size of 0.1-2 mm, wherein an aqueous slurry of the composition ingredients is continuously homogenized to yield a viscosity of 4,000 to 20,000 mPa.s and heated to a temperature of 85°-105° C. The homogenized heated slurry is then sprayed in a drying tower through nozzles having a bore diameter of 2.5-5 mm under a pressure of 20-45 bar. The slurry and resulting product contain 10-28% alkoxylated nonionic surfactant, 40-80% inorganic carrier and 0.5-10% organic washing auxiliary.
Inventors
- 👤 Manfred Balk
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 16:44
CPC Classifications
C; C11; C11D; C11D11/00; C11D11/02; C11D17/00; C11D17/06; C11D17/065
Claims Analysis
Total Claims: 36
Claim 1
Independent Claim
230 words
A process for the production of a granular detergent composition comprising: (A) mixing into an aqueous slurry (a) 10-28% of at least one alkoxylated nonionic surfactant, (b) 40-80% of at least one inorganic carrier, (c) 0.5-10% of at least one organic washing auxiliary and (d) 35-50% of a total quantity of water including 10-20% of water bound by adsorption and water of hydration, with the proviso that anionic surfactants are not present in an amount greater than 0.5%, all percentages being by weight and based upon the weight of the entire composition; (B) continuously and intensively homogenizing said slurry to adjust and maintain its viscosity at 4,000-20,000 mPa.s at a temperature of between 85° C. and 105° C.; (C) heating said slurry to maintain its temperature at 85°-105° C.; (D) feeding said heated, homogenized slurry to a high pressure pump from which said slurry is pumped to spray nozzles; (E) spraying said heated, homogenized slurry through said nozzles into a dynamic drying-gas flowing drying tower at a pressure of 20 to 45 bar, said nozzles having a bore diameter of 2.5 to 5 mm and the ratio of said pressure to said bore diameter being 4-18 bar/mm; and (F) removing the detergent composition thus formed, which formed composition is rapidly soluble in water, free-flowing, has a bulk density of at least 600 g/l, and a particle size of 0.1-2 mm.
Claim 2
Dependent Claim
230 words
A process for the production of a granular detergent composition comprising: (A) mixing into an aqueous slurry (a) 10-28% of at least one alkoxylated nonionic surfactant, (b) 40-80% of at least one inorganic carrier, (c) 0.5-10% of at least one organic washing auxiliary and (d) 35-50% of a total quantity of water including 10-20% of water bound by adsorption and water of hydration, with the proviso that anionic surfactants are not present in an amount greater than 0.5%, all percentages being by weight and based upon the weight of the entire composition; (B) continuously and intensively homogenizing said slurry to adjust and maintain its viscosity at 4,000-20,000 mPa.s at a temperature of between 85° C. and 105° C.; (C) heating said slurry to maintain its temperature at 85°-105° C.; (D) feeding said heated, homogenized slurry to a high pressure pump from which said slurry is pumped to spray nozzles; (E) spraying said heated, homogenized slurry through said nozzles into a dynamic drying-gas flowing drying tower at a pressure of 20 to 45 bar, said nozzles having a bore diameter of 2.5 to 5 mm and the ratio of said pressure to said bore diameter being 4-18 bar/mm; and (F) removing the detergent composition thus formed, which formed composition is rapidly soluble in water, free-flowing, has a bulk density of at least 600 g/l, and a particle size of 0.1-2 mm.
Claim 3
Dependent Claim
184 words
The process of claim 1 wherein (a) said at least one alkoxylated nonionic surfactant comprises: ethoxylated C 12-24 -alcohol containing on average 3-20 glycol ether moieties, and which may be saturated or monosaturated, linear or methyl-branched in the 2-position, and is derived from naturally occuring fatty residues; alkoxylated C 12-24 -alcohol in which 1-3 mols of propylene oxide are first added to the alcohol and then 4-20 mols of ethylene oxide are added; ethoxylated C 8-12 -alkylphenol containing 4-14 mols of ethylene oxide; ethoxylated or propoxylated vicinal diol, fatty amine, fatty acid amide, or fatty acid; or amine oxide or amine oxide containing polyglycol ether moieties; (b) said at least one inorganic carrier comprises: polymer phosphate alkali metal or ammonium salt; alkali metal silicate; aluminosilicate which is zeolite A, zeolite X, or their mixture; or sodium carbonate, sodium sulfate, magnesium silicate, finely divided silica, clay, bentonite, or their mixtures; and (c) said at least one organic washing auxiliary comprises: a co-builder capable of enhancing the effect of any builder present as an inorganic carrier; a redeposition inhibitor; an optical brightener; or a viscosity regulator.
Claim 4
Dependent Claim
48 words
The process of claim 1 wherein ingredient (a) is present in 12-25%, ingredient (b) is present in 45-70%, ingredient (c) is present in 0.5-10%, ingredient (d) is present in 38-45% including 12-18% of water bound by adsorption and water of hydration, and substantially no anionic surfactants are present.
Claim 5
Dependent Claim
48 words
The process of claim 2 wherein ingredient (a) is present in 12-25%, ingredient (b) is present in 45-70%, ingredient (c) is present in 0.5-10%, ingredient (d) is present in 38-45% including 12-18% of water bound by adsorption and water of hydration, and substantially no anionic surfactants are present.
Claim 6
Dependent Claim
19 words
The process of claim 3 wherein ingredient (a) is present in 15-23%, and ingredient (c) is present in 1-5%.
Claim 7
Dependent Claim
19 words
The process of claim 4 wherein ingredient (a) is present in 15-23%, and ingredient (c) is present in 1-5%.
Claim 8
Dependent Claim
43 words
The process of claim 6 wherein in ingredient (b): alkali metal tripolyphosphate is present in 0 to 60%; alkali metal silicate is present in 5-20%; and alkali metal aluminosilicate is present in 0-40%; the total quantity of ingredient (b) being at least 45%.
Claim 9
Dependent Claim
29 words
The process of claim 7 wherein in ingredient (b): sodium tripolyphosphate is present in 10-50%; akali metal silicate is present in 6-15%; and sodium aluminosilicate is present in 3-30%.
Claim 10
Dependent Claim
32 words
The process of claim 8 wherein in ingredient (b); said sodium tripolyphosphate is present in 20-40%; said alkali metal silicate is present in 6.5-12%; and said sodium aluminosilicate is present in 5-25%.
Claim 11
Dependent Claim
22 words
The process of claim 8 wherein said alkali metal silicate has the composition Na 2 O:SiO 2 in a ratio of 1:1.5-3.5,
Claim 12
Dependent Claim
22 words
The process of claim 9 wherein said alkali metal silicate has the composition Na 2 O:SiO 2 in a ratio of 1:2-2.5.
Claim 13
Dependent Claim
32 words
The process of claim 1 wherein the viscosity of said aqueous slurry is adjusted to and maintained at 5,000 to 20,000 mPa.s at a temperature of between 85° C. and 105° C.
Claim 14
Dependent Claim
32 words
The process of claim 1 wherein the viscosity of said aqueous slurry is adjusted to and maintained at 5,000 to 15,000 mPa.s at a temperature of between 90° C. and 102° C.
Claim 15
Dependent Claim
22 words
The process of claim 1 wherein said aqueous slurry is heated to and maintained at a temperature of 90° to 102° C.
Claim 16
Dependent Claim
22 words
The process of claim 13 wherein said aqueous slurry is heated to and maintained at a temperature of 90° to 102° C.
Claim 17
Dependent Claim
37 words
The process of claim 1 wherein the continuous homogenization is carried out in a cascade of at least two successive mixers in which the average total residence time of said slurry is no longer than 10 minutes.
Claim 18
Dependent Claim
37 words
The process of claim 1 wherein the continuous homogenization is carried out in a cascade of at least two successive mixers in which the average total residence time of said slurry is no longer than 5 minutes.
Claim 19
Dependent Claim
37 words
The process of claim 15 wherein the continuous homogenization is carried out in a cascade of at least two successive mixers in which the average total residence time of said slurry is no longer than 5 minutes.
Claim 20
Dependent Claim
75 words
The process of claim 18 wherein a fraction comprising 50-90% by weight of said at least one alkoxylated nonionic surfactant is introduced after the remaining slurry ingredients have been homogenized in said cascade by feeding said fraction and said slurry through a further homogenizing unit prior to feeding the homogenized combined slurry to said high pressure pump, so that the slurry resident time of said alkoxylated nonionic surfactant fraction is not more than 3 minutes.
Claim 21
Dependent Claim
20 words
The process of claim 19 wherein the slurry residence time of said alkoxylated surfactant fraction is less than 1 minute.
Claim 22
Dependent Claim
40 words
The process of claim 1 wherein said slurry is sprayed at a pressure of 30-40 bar, said nozzles have a bore diameter of 3.0 to 4.0 mm, and the ratio of said pressure to said bore diameter is 7.5-13.33 bar/mm.
Claim 23
Dependent Claim
40 words
The process of claim 18 wherein said slurry is sprayed at a pressure of 30-40 bar, said nozzles have a bore diameter of 3.0 to 4.0 mm, and the ratio of said pressure to said bore diameter is 7.5-13.33 bar/mm.
Claim 24
Dependent Claim
26 words
The process of claim 1 wherein said drying-gas enters said drying tower at a temperature of 180°-240° C. and flows countercurrent to the material being sprayed.
Claim 25
Dependent Claim
26 words
The process of claim 22 wherein said drying-gas enters said drying tower at a temperature of 200°-240° C. and flows countercurrent to the material being sprayed.
Claim 26
Dependent Claim
26 words
The process of claim 1 wherein said drying gas is introduced into said drying tower tangentially, so that it imparts spin to the material being dried.
Claim 27
Dependent Claim
26 words
The process of claim 24 wherein said drying gas is introduced into said drying tower tangentially, so that it imparts spin to the material being dried.
Claim 28
Dependent Claim
38 words
The process of claim 1 wherein the spray-dried detergent composition is cooled to a temperature below 35° C. starting immediately it is removed from said drying tower, so that it is sufficiently cooled within less than 5 minutes.
Claim 29
Dependent Claim
36 words
The process of claim 26 wherein the spray-dried detergent composition is cooled to a temperature below 35° C. starting immediately it is removed from said drying tower, so that it is sufficiently cooled within 2 minutes.
Claim 30
Dependent Claim
37 words
The process of claim 1 wherein in a further step, said formed detergent composition is dusted with a fluidizing agent used in an amount of 0.01-3% by weight based on the weight of said formed detergent composition.
Claim 31
Dependent Claim
37 words
The process of claim 28 wherein in a further step, said formed detergent composition is dusted with a fluidizing agent used in an amount of 0.01-3% by weight based on the weight of said formed detergent composition.
Claim 32
Dependent Claim
8 words
The product of the process of claim 1.
Claim 33
Dependent Claim
8 words
The product of the process of claim 2.
Claim 34
Dependent Claim
8 words
The product of the process of claim 10.
Claim 35
Dependent Claim
8 words
The product of the process of claim 28.
Claim 36
Dependent Claim
8 words
The product of the process of claim 30.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-03-23 | 1990-09-22 | 1991-03-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-03-23 | 1994-09-22 | 1995-03-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-03-23 | 1998-09-22 | 1999-03-24 | $7700.00 | Window Closed / Lapsed |