Abstract A novel organosilane coupling agent is disclosed and its use as an adhesion promoter in mineral-filled unsaturated polymer systems is described. Additionally, use of the organosilane as a primer for various substrates is presented. The coupling agent comprises the reaction product of an isocyanatoalkyl ester of acrylic or methacrylic acid with an aminoorganosilane. The organosilane so formed links the acryloxyalkyl or methacryloxyalkyl functionality to an alkylene, or aminoalkylene, group on the silicon atom through a urea group. Use of the organosilane as a coupling agent in a mineral-filled unsaturated polymer results in superior resistance to moisture, particularly when the polymer is selected from the group of corrosion resistant unsaturated polyesters.
An organosilane represented by the formula ##STR11## wherein R' is the group ##STR12## and wherein R is selected from the group consisting of acryloxy and methacryloxy radical; R" is a divalent hydrocarbon radical having 2 to 4 carbon atoms; R'" is a divalent hydrocarbon radical having 3 to 6 carbon atoms; R"" is selected from the group consisting of methyl, ethyl, propyl, butyl and phenyl; X is a hydrolyzable species selected from the group consisting of methoxy, ethoxy, acetoxy and chlorine; n is 0, 1 or 2; q is 2, 3 or 4; p is 0 or 1; and m has an average value from 0 to 1.0 when n is at least 1.
Claim 2
Dependent Claim
114 words
An organosilane represented by the formula ##STR11## wherein R' is the group ##STR12## and wherein R is selected from the group consisting of acryloxy and methacryloxy radical; R" is a divalent hydrocarbon radical having 2 to 4 carbon atoms; R'" is a divalent hydrocarbon radical having 3 to 6 carbon atoms; R"" is selected from the group consisting of methyl, ethyl, propyl, butyl and phenyl; X is a hydrolyzable species selected from the group consisting of methoxy, ethoxy, acetoxy and chlorine; n is 0, 1 or 2; q is 2, 3 or 4; p is 0 or 1; and m has an average value from 0 to 1.0 when n is at least 1.
Claim 3
Dependent Claim
13 words
The organosilane of claim 1, wherein R is methacrylate and q is two.
Claim 4
Dependent Claim
16 words
The organosilane of claim 2, wherein p is zero, R" is ethylene and R'" is trimethylene.
Claim 5
Dependent Claim
18 words
The organosilane of claim 3, wherein X is selected from the group consisting of methoxy and ethoxy radicals.
Claim 6
Dependent Claim
15 words
The organosilane of claim 4, wherein n is 1 and X is the methoxy radical.
Claim 7
Dependent Claim
15 words
The organosilane of claim 5, wherein m has an average value from 0 to 0.75.