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US4650849A Expired / Lapsed US ⏱️ 0.0 years remaining

Photosensitive curable resin composition

Assignee: Shin-Etsu Chemical Co Ltd
•
Filing: 1985-04-25
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Granted: 1987-03-17
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Expires: 2005-04-25
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Abstract

Abstract The organosilicon-containing polyamic acid of the invention is a reaction product of the reactants including (1) an organosilicon compound having ethylenic unsaturation and amino-substituted hydrocarbon group, (2) a tetracarboxylic acid dianhydride and (3) a polyamino compound in an organic solvent. The polyamic acid as such and a composition comprising the same in combination with a mercapto-containing compound and/or a photosensitizer are useful as a photosensitive precursor of a polyimide resin usable in photolithographic pattern reproduction.

Inventors

  • 👤 Yoshiaki Nishimura
  • 👤 Hiroshige Okinoshima
  • 👤 Seiya Yamada
  • 👤 Tsutomu Kashiwagi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 11:39
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/1057; C08G73/106; C08G77/00; C08G77/42; C08G77/452; C08G77/455

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 269 words
An organosilicon-containing polyamic acid which is a reaction product of the reactants: (a-1) an organosilicon compound represented by the general formula (CH.sub.2 ═CR--R.sup.2.sub.d --).sub.a (H.sub.2 N--R.sup.3 --).sub.b R.sup.1.sub.c SiO.sub.(4-a-b-c)/2, in which R is a hydrogen atom or a methyl group, R 1 is an unsubstituted monovalent hydrocarbon group selected from the class consisting of alkyl, aryl, and alkoxy, a monovalent hydrocarbon group selected from the class consisting of alkyl, aryl, and alkoxy substituted with halogen, glycidyloxy, and cyano, R 2 is a divalent organic group selected from the class consisting of polymethylene groups of the formula --CH 2 ) p , in which p is a positive integer, propylene group of the formula --CH 2 --CHMe--, in which Me is a methyl group, 1,4-phenylene group and an ester group of the formula --CO--O--C 3 H 6 --, R 3 is a divalent hydrocarbon group, a and b are each a positive number not exceeding 3 and c is zero or a positive number not exceeding 2 with the proviso that a+b+c is a positive number not exceeding 4 and d is zero or 1; (a-2) a tetracarboxylic acid dianhydride represented by the general formula ##STR5## in which R 4 is a tetravalent hydrocarbon group; and (a-3) a polyamino compound represented by the general formula H.sub.2 N--R.sup.5 --NH.sub.2, which is a diamino compounds, or (H.sub.2 N).sub.2 --R.sup.6 --R.sup.7 --NH.sub.2, which is a diaminoamide compound, in which R 5 is a divalent organic group, R 6 is a tervalent hydrocarbon group and R 7 is a sulfonyl group -- SO 2 -- or a carbonyl group --CO--; in an organic solvent.
Claim 2
Dependent Claim 269 words
An organosilicon-containing polyamic acid which is a reaction product of the reactants: (a-1) an organosilicon compound represented by the general formula (CH.sub.2 ═CR--R.sup.2.sub.d --).sub.a (H.sub.2 N--R.sup.3 --).sub.b R.sup.1.sub.c SiO.sub.(4-a-b-c)/2, in which R is a hydrogen atom or a methyl group, R 1 is an unsubstituted monovalent hydrocarbon group selected from the class consisting of alkyl, aryl, and alkoxy, a monovalent hydrocarbon group selected from the class consisting of alkyl, aryl, and alkoxy substituted with halogen, glycidyloxy, and cyano, R 2 is a divalent organic group selected from the class consisting of polymethylene groups of the formula --CH 2 ) p , in which p is a positive integer, propylene group of the formula --CH 2 --CHMe--, in which Me is a methyl group, 1,4-phenylene group and an ester group of the formula --CO--O--C 3 H 6 --, R 3 is a divalent hydrocarbon group, a and b are each a positive number not exceeding 3 and c is zero or a positive number not exceeding 2 with the proviso that a+b+c is a positive number not exceeding 4 and d is zero or 1; (a-2) a tetracarboxylic acid dianhydride represented by the general formula ##STR5## in which R 4 is a tetravalent hydrocarbon group; and (a-3) a polyamino compound represented by the general formula H.sub.2 N--R.sup.5 --NH.sub.2, which is a diamino compounds, or (H.sub.2 N).sub.2 --R.sup.6 --R.sup.7 --NH.sub.2, which is a diaminoamide compound, in which R 5 is a divalent organic group, R 6 is a tervalent hydrocarbon group and R 7 is a sulfonyl group -- SO 2 -- or a carbonyl group --CO--; in an organic solvent.
Claim 3
Dependent Claim 47 words
The organosilicon containing polyamic acid as claimed in claim 1 wherein the amount of the reactant (a-2) in the reaction with the reactants (a-1) and (a-3) is in the range from 0.4 to 0.6 mole per mole of the amino groups in the reactants (a-1) and (a-3).

References Cited (Backward Citations)

US4293397A Cited
US4338426A Cited
US4391963A Cited
US4558117A Cited
US4551522A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-03-16 1990-09-15 1991-03-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-03-16 1994-09-15 1995-03-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-03-16 1998-09-15 1999-03-17 $7700.00 Window Closed / Lapsed

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