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US4650737A
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Electrophotographic recording material containing benzimidazole derivative
Assignee: Hoechst AG
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Filing: 1986-01-24
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Granted: 1987-03-17
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Expires: 2006-01-24
Abstract
Abstract An electrophotographic recording material comprising an electrically conductive base material, an option insulating intermediate layer, and a photoconductive double layer comprised of a charge-generating and a charge-transporting layer employs a pyrimido[5' ,4':5,6]-pyrido-[1,2-a]-benzimidazole transport compound, along with a binder and a dye or pigment, in the charge transporting layer, which compound is represented by the formula I ##STR1## wherein R 1 and R 2 are identical or different and denote hydrogen or an R 3 R 4 N group; R 3 and R 4 are identical or different and denote (C 1 to C 4 )-alkyl, hydroxy-(C 1 to C 4 )-alkyl, optionally (C 1 to C 4 )-alkyl-substituted phenyl or benzyl, or, together with the nitrogen atoms to which they are bonded, an imidazolyl or a triazolyl group; and R 5 denotes a benzothiazole, a benzoxazole, a benzimidazole or a cyano group. Use of the transport compound makes it possible to adjust the photosensitivity of the recording material to different spectral regions when the material is subjected to electrostatic charging of different polarities.
Inventors
- 👤 Wolfgang Wiedemann
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 03:55
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/06; G03G5/0622; G03G5/0644; G03G5/0646; G03G5/0657; G03G5/0651; G03G5/0659; G03G5/0661
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
180 words
An electrophotographic recording material comprising an electically conductive support and a photoconductive double layer provided on said support, said photoconductive double layer comprising (i) a charge-generating and (ii) a charge-transporting layer containing a pyrimido-[5',4':5,6]-pyrido-[1,2-a]-benzimidazole transport compound, a binder and a dye or pigment sensitizer, said transport compound being present in an amount ranging from about 20 to 50% by weight, relative to the admixture of binder and transport compound, wherein said transport compound is represented by the formula I ##STR5## wherein R 1 and R 2 are identical or different and are each hydrogen or an R 3R4N group, R 3 and R 4 are identical or different and (1) are each (a) alkyl having 1 to 4 carbon atoms, (b) hydroxyl alkyl having 1 to 4 carbon atoms, or (c) phenyl or benzyl which is unsubstituted or substituted by an alkyl group having 1 to 4 carbon atoms, or (2) together with the nitrogen atom to which they are bonded, are an imidazolyl or a triazolyl group; and R 5 is benzothiazole, a benzoxazole, benzimidazole or a cyano group.
Claim 2
Dependent Claim
180 words
An electrophotographic recording material comprising an electically conductive support and a photoconductive double layer provided on said support, said photoconductive double layer comprising (i) a charge-generating and (ii) a charge-transporting layer containing a pyrimido-[5',4':5,6]-pyrido-[1,2-a]-benzimidazole transport compound, a binder and a dye or pigment sensitizer, said transport compound being present in an amount ranging from about 20 to 50% by weight, relative to the admixture of binder and transport compound, wherein said transport compound is represented by the formula I ##STR5## wherein R 1 and R 2 are identical or different and are each hydrogen or an R 3R4N group, R 3 and R 4 are identical or different and (1) are each (a) alkyl having 1 to 4 carbon atoms, (b) hydroxyl alkyl having 1 to 4 carbon atoms, or (c) phenyl or benzyl which is unsubstituted or substituted by an alkyl group having 1 to 4 carbon atoms, or (2) together with the nitrogen atom to which they are bonded, are an imidazolyl or a triazolyl group; and R 5 is benzothiazole, a benzoxazole, benzimidazole or a cyano group.
Claim 3
Dependent Claim
23 words
An electrophotographic recording material as claimed in claim 1, further comprising an insulating intermediate layer interposed said support and said photoconductive double layer.
Claim 4
Dependent Claim
36 words
A recording material as claimed in claim 1, wherein said transport compound is represented by the formula II ##STR6## wherein R 5 denotes a substituent selected from the group consisting of benzothiazole and a cyano group.
Claim 5
Dependent Claim
41 words
A recording material as claimed in claim 1, said material being photosensitive, upon positive electrostatic charging, in the spectral range between about 400 and 500 nm and, on negative electrostatic charging, in the spectral range between about 500 and 800 nm.
Claim 6
Dependent Claim
30 words
A recording material as claimed in claim 1, wherein said charge-generating layer contains at least one dye selected from the group consisting of a blue dye and a violet dye.
Claim 7
Dependent Claim
27 words
A recording material as claimed in claim 5, wherein said dye comprises a compound selected from the group consisting of a metal-containing phthalocyanine and a metal-free phthalocyanine.
Claim 8
Dependent Claim
21 words
A recording material as claimed in claim 5, wherein said dye comprise a condensation product of perylene-3,4,9,10-tetracarboxylicdianhydride and an aromatic diamine.
Claim 9
Dependent Claim
45 words
A recording material as claimed in claim 1, wherein said charge-generating layer comprises a dye layer which is the product of a process comprising the step of applying to one of said support and said charge-transport layer a homogeneous solution containing at least one dye.
Claim 10
Dependent Claim
16 words
A recording material as claimed in claim 1, wherein said charge-transporting layer contains an alkali-soluble binder.
Claim 11
Dependent Claim
16 words
A recording material as claimed in claim 9, wherein said charge-generating layer contains an alkali-soluble binder.
Claim 12
Dependent Claim
39 words
A recording material as claimed in claim 9, wherein said alkali-soluble binder comprises a copolymer of styrene with one selected from the group consisting of maleic anhydride, a copolymer of vinyl acetate with crotonic acid, and a phenolic resin.
Claim 13
Dependent Claim
39 words
A recording material as claimed in claim 10, wherein said alkali-soluble binder comprises a copolymer of styrene with one selected from the group consisting of maleic anhydride, a copolymer of vinyl acetate with crotonic acid, and a phenolic resin.
Claim 14
Dependent Claim
34 words
A recording material as claimed in claim 1, wherein said charge-generating layer has a thickness of about 0.05 to 3 μm and said charge-transporting layer has a thickness of about 4 to 20 μm.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-03-16 | 1990-09-15 | 1991-03-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-03-16 | 1994-09-15 | 1995-03-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-03-16 | 1998-09-15 | 1999-03-17 | $7700.00 | Window Closed / Lapsed |