Pressure swing adsorption process

Claim 1

In a pressure swing adsorption process for the separation and recovery of a less readily adsorbable component of a feed gas mixture in an adsorption system capable of selectively adsorbing a more readily adsorbable component from said gas mixture, the adsorption system containing at least three adsorbent beds, each of which undergoes, on a cyclic basis, a processing sequence that includes (1) adsorption with discharge of the less readily adsorbable component as product effluent from the product end of the bed, (2) cocurrent depressurization with release of void space gas from the product end of the bed and the passage of said gas to other beds in the system for pressure equalization and for provide purge purposes, (3) countercurrent depressurization to lower desorption pressure with release of said more readily adsorbable component from the feed end of the bed; (4) purge at said lower desorption pressure, (5) partial repressurization by pressure equalization with void space gas from other beds, and (6) further repressurization to upper adsorption pressure, the improvement comprising: (a) passing void space gas released from the bed during cocurrent depressurization thereof from said upper adsorption pressure to an upper intermediate pressure to another bed in the system, said other bed thereby being partially repressurized to said upper intermediate pressure; (b) passing additional void space gas released from the bed during further cocurrent depressurization thereof from said upper intermediate pressure to an intermediate level to a different bed in the system, said additional gas comprising a purge gas for said different bed; (c) passing additional void space gas released from the bed during still further cocurrent depressurization thereof from said intermediate pressure level to a lower intermediate pressure to another bed in the system initially at a lower pressure for pressure equalization therebetween at said lower intermediate pressure, while simultaneously countercurrently depressurizing said bed by the discharge of gas from the feed end of said bed being depressurized; (d) discontinuing the passage of said void space gas to said bed initially at lower pressure upon said bed being depressurized and said bed initially at lower pressure reaching said lower intermediate pressure; (e) further continuing to contercurrently depressurize said bed being depressurized, after completion of said step (c), down to the lower desorption pressure of said bed; and (f) discharing the less readily adsorbable component as product effluent from the product end of the bed simultaneously with the passage of the feed gas mixture to the feed end thereof for the repressurization of said partially repressurized bed to said upper adsorption pressure; and (g) repeating said steps (a)-(f) as the cyclic operation is continued with additional quantities of feed gas without passing feed gas to the bed for adsorption at the upper adsorption pressure for discharge of the less readily adsorbable component therefrom at constant upper adsorption pressure prior to commencing cocurrent depressurization to said upper intermediate pressure level.