US4645625A
Expired / Lapsed
US
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Decontamination of a radioactive waste liquid by electrodialysis
Assignee: Veolia WTS Systems USA Inc
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Filing: 1984-11-26
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Granted: 1987-02-24
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Expires: 2004-11-26
Abstract
Abstract This invention relates to apparatus and processes for the removal and recovery of concentrated acid such as HNO 3 and radioactive cations such as cesium (Cs + ) from a radioactive acidic waste stream resulting in the recovery of a decontaminated water product. The invention employs a combination of membrane electrodialysis stacks with each having its own specific cell configuration for performing a specific salt removal or salt concentrating step in the decontamination process.
Inventors
- 👤 Jerry E. Lundstrom
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 14:51
CPC Classifications
G; G21; G21F; G21F9/00; G21F9/04; G21F9/06
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
218 words
An apparatus for the removal and recovery of acidic and radioactive components of a liquid waste stream comprising in combination a series of at least two electrodialysis units or stacks, each stack comprised of a cathode chamber at one terminal end, an anode chamber at the opposite terminal end, said chambers containing respectively a cathode and anode electrode, a deacidification stack being the first stack in the series having all of its chambers being separated one from the other by separate anion selective membranes defining between said electrode chambers at least one neutral liquid chamber positioned adjacent to the cathode chamber, a primary desalting stack being the second stack in the series comprising a multi-chamber unit having a plurality of alternating salt diluting and salt concentrating chambers defined by alternating cation and anion selective membranes, means for introducing a liquid to be treated into the cathode chamber of said deacidification stack with exit means for withdrawal of said liquid, means for passing said withdrawn liquid into and out of the salt diluting chambers of said primary desalting stack, further means for introducing a liquid into and out of the concentrating and electrode chambers of said primary desalting stack and means for passing a direct electric current transversely across the membranes and chambers of each stack in the series.
Claim 2
Independent Claim
218 words
An apparatus for the removal and recovery of acidic and radioactive components of a liquid waste stream comprising in combination a series of at least two electrodialysis units or stacks, each stack comprised of a cathode chamber at one terminal end, an anode chamber at the opposite terminal end, said chambers containing respectively a cathode and anode electrode, a deacidification stack being the first stack in the series having all of its chambers being separated one from the other by separate anion selective membranes defining between said electrode chambers at least one neutral liquid chamber positioned adjacent to the cathode chamber, a primary desalting stack being the second stack in the series comprising a multi-chamber unit having a plurality of alternating salt diluting and salt concentrating chambers defined by alternating cation and anion selective membranes, means for introducing a liquid to be treated into the cathode chamber of said deacidification stack with exit means for withdrawal of said liquid, means for passing said withdrawn liquid into and out of the salt diluting chambers of said primary desalting stack, further means for introducing a liquid into and out of the concentrating and electrode chambers of said primary desalting stack and means for passing a direct electric current transversely across the membranes and chambers of each stack in the series.
Claim 3
Dependent Claim
62 words
The apparatus of claim 1 wherein additional multi-chamber units or secondary desalting stacks are located in series with said primary desalting stack with means for further passing said treated liquid successively into and out of the diluting chambers of each remaining stack and final means of withdrawal of a substantially deacidified and decontaminated product liquid stream from the last stack in series.
Claim 4
Dependent Claim
107 words
The apparatus of claim 1 wherein there is located in combination therewith a radioactive cation concentration stack of a similar configuration to said deacidification stack but having a cation selective membrane positioned facing the cathode chamber to define a single salt diluting chamber immediately adjacent thereto, said cation concentration stack having means for introducing at least a portion of the salt concentrated effluent stream of said primary desalting stack into said single salt diluting chamber with exit means for the withdrawal and the recycling of said resulting partially desalted stream from said single salt diluting chamber back to the salt concentrating chambers of said primary desalting stack.
Claim 5
Dependent Claim
76 words
The apparatus of claim 3 wherein said deacidification stack contains two neutral chambers between said electrode chambers and said radioactive cation concentration stack contains a neutral chamber adjacent the anode chamber and a salt diluting chamber adjacent the cathode chamber, means for passing a catholyte stream from the cathode chamber of said deacidification stack with further means for recycling the withdrawn liquid back as the influent stream to the said cathode chamber of said deacidification stack.
Claim 6
Dependent Claim
56 words
The apparatus of claim 4 wherein means are provided for recirculating a common anolyte stream through each of the anode chambers of said deacidification stack and said cation concentration stack with means for adding water to said common anolyte stream and further means for removing and recovering a concentrated acid solution from said recirculating anolyte stream.
Claim 7
Dependent Claim
200 words
A process for the removal and recovery of acidic and radioactive components of a liquid waste stream by the treatment of said waste stream through liquid treatment chambers of at least two electrodialysis stacks comprising the steps of first passing said waste solution through the cathode chamber of the first stack, a deacidification stack to reduce the acidity of said waste solution, said stack having terminally positioned anode and cathode chambers and at least one neutral liquid chamber therebetween, all chambers being separated one from the other by separate anion selective membranes, withdrawing catholyted solution from said cathode chamber and passing the same to the salt diluting chambers of the second stack, a multichamber primary desalting stack to reduce the salt content therein, said primary desalting stack having alternating cation and anion selective membranes defining alternating salt diluting and salt concentrating chambers, the terminal chambers of which contain cathode and anode electrodes, passing a direct electric current transversely through said membranes and chambers of said stacks and removing from the diluting chambers of said primary desalting stack a product water stream containing a substantially lessor amount of acid and radioactive cations than was originally present in said liquid waste system.
Claim 8
Dependent Claim
200 words
A process for the removal and recovery of acidic and radioactive components of a liquid waste stream by the treatment of said waste stream through liquid treatment chambers of at least two electrodialysis stacks comprising the steps of first passing said waste solution through the cathode chamber of the first stack, a deacidification stack to reduce the acidity of said waste solution, said stack having terminally positioned anode and cathode chambers and at least one neutral liquid chamber therebetween, all chambers being separated one from the other by separate anion selective membranes, withdrawing catholyted solution from said cathode chamber and passing the same to the salt diluting chambers of the second stack, a multichamber primary desalting stack to reduce the salt content therein, said primary desalting stack having alternating cation and anion selective membranes defining alternating salt diluting and salt concentrating chambers, the terminal chambers of which contain cathode and anode electrodes, passing a direct electric current transversely through said membranes and chambers of said stacks and removing from the diluting chambers of said primary desalting stack a product water stream containing a substantially lessor amount of acid and radioactive cations than was originally present in said liquid waste system.
Claim 9
Dependent Claim
41 words
The process of claim 6 wherein said product water stream withdrawn from the diluting chambers of said primary desalting stack is passed in series flow through at least one secondary desalting stack to further reduce the acid and radioactive cations therein.
Claim 10
Dependent Claim
103 words
The process of claim 6 wherein the effluent stream from the salt concentrating chambers of said primary desalting stack is passed into a single salt diluting chamber of a radioactive cation concentration stack, said single salt diluting chamber positioned immediately adjacent the cathode chamber of said concentration stack and separated on that one side by a cation selective membrane with an anion selective membrane separating the other side of a said single diluting chamber, withdrawing from said single diluting chamber an effluent stream which has been partially desalted and recycling the same back to the salt concentrating chambers of said primary desalting stack.
Claim 11
Dependent Claim
52 words
The process of claim 6 wherein a first portion of the catholyte effluent solution from the cathode chamber of said cation concentration stack is passed into and out of the neutral chamber located adjacent the cathode chamber of said deacidification stack and thereafter recycled back as influent to the said neutral chamber.
Claim 12
Dependent Claim
46 words
The process of claim 9 wherein a second portion of said catholyte effluent is recycled back as the influent stream to the cathode chamber of said concentration stack and a third portion of said catholyte effluent is removed and recovered as a concentrated radioactive cation solution.
Claim 13
Dependent Claim
55 words
The process of claim 9 wherein an anolyte stream is recirculated through each of the anode chambers of the deacidification and cation concentration stacks while adding water to said anolyte to maintain the acid concentration at a desired level and removing and recovering a portion of said concentrated acid solution from said recirculating anolyte stream.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-02-23 | 1990-08-25 | 1991-02-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-02-23 | 1994-08-25 | 1995-02-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-02-23 | 1998-08-25 | 1999-02-24 | $7700.00 | Window Closed / Lapsed |