Patent US4643764A successfully refreshed from Google Patents.
US4643764A
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Multiple types of microcapsules and their production
Assignee: Zeneca Inc
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Filing: 1985-01-31
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Granted: 1987-02-17
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Expires: 2005-01-31
Abstract
Abstract In a process of encapsulating water-immiscible material within discrete capsules of polyurea without addition of a second reactant, whereby hydrolysis of an isocyanate monomer to form an amine takes place which in turn reacts with another isocyanate monomer to form polyurea, which comprises the steps (a) providing at room temperature a dispersion of (i) a water-immiscible phase comprising the water-immiscible material to be encapsulated and organic polyisocyanates in (ii) an aqueous phase comprising a solution of water, a surfactant and a protective colloid; and (b) heating and maintaining said dispersion in a temperature range of about 40° C. to about 90° C., whereupon said water-immiscible material is encapsulated within discrete polyurea capsular enclosures directly usable without further separation or purification, the improvement comprising providing a plurality of water-immiscible phases each comprising at least one individually distinct wall-forming organic polyisocyanate monomer, and a water-immiscible material to be encapsulated in a polyurea wall formed from said polyisocyanate monomer, and sequentially or simultaneously dispersing each of said water-immiscible phases in said aqueous phase.
Inventors
- 👤 Herbert B. Scher
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 09:12
CPC Classifications
A; A01; A01N; A01N25/00; A01N25/26; A01N25/28; B; B01; B01J; B01J13/00; B01J13/02; B01J13/06; B01J13/14; B01J13/16; Y; Y10; Y10S; Y10S424/00; Y10S424/08; Y10T; Y10T428/00; Y10T428/29; Y10T428/2982; Y10T428/2984; Y10T428/2985
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
170 words
In a process of encapsulating water-immiscible material within discrete capsules of polyurea without addition of a second reactant, whereby hydrolysis of an isocyanate monomer to form an amine takes place which in turn reacts with another isocyanate monomer to form polyurea, which comprises the steps (a) providing at room temperature a dispersion of (i) a water-immiscible phase comprising the water-immiscible material to be encapsulated and organic polyisocyanates in (ii) an aqueous phase comprising a solution of water, a surfactant and a protective colloid; and (b) heating and maintaining said dispersion in a temperature range of about 40° C. to about 90° C., whereupon said water-immiscible material is encapsulated within discrete polyurea capsular enclosures directly usable without further separation or purification, the improvement comprising providing a plurality of water-immiscible phases each comprising at least one individually distinct wall-forming organic polyisocyanate monomer, and a water-immiscible material to be encapsulated in a polyurea wall formed from said polyisocyanate monomer, and sequentially or simultaneously dispersing each of said water-immiscible phases in said aqueous phase.
Claim 2
Dependent Claim
170 words
In a process of encapsulating water-immiscible material within discrete capsules of polyurea without addition of a second reactant, whereby hydrolysis of an isocyanate monomer to form an amine takes place which in turn reacts with another isocyanate monomer to form polyurea, which comprises the steps (a) providing at room temperature a dispersion of (i) a water-immiscible phase comprising the water-immiscible material to be encapsulated and organic polyisocyanates in (ii) an aqueous phase comprising a solution of water, a surfactant and a protective colloid; and (b) heating and maintaining said dispersion in a temperature range of about 40° C. to about 90° C., whereupon said water-immiscible material is encapsulated within discrete polyurea capsular enclosures directly usable without further separation or purification, the improvement comprising providing a plurality of water-immiscible phases each comprising at least one individually distinct wall-forming organic polyisocyanate monomer, and a water-immiscible material to be encapsulated in a polyurea wall formed from said polyisocyanate monomer, and sequentially or simultaneously dispersing each of said water-immiscible phases in said aqueous phase.
Claim 3
Dependent Claim
25 words
The process of claim 1 wherein the dispersed water-immiscible phase comprises droplets having a particle size of between about 0.5 microns to about 4000 microns.
Claim 4
Dependent Claim
13 words
The process of claim 2 wherein said dispersion is maintained by mild agitation.
Claim 5
Dependent Claim
68 words
The process of claim 3, wherein said water-immiscible phase contains a catalyst selected from the group consisting of (a) a basic organic tertiary amine catalyst in the amount of about 0.01 percent to about 10.0 percent by weight based on the organic phase and (b) an alkyl tin acetate catalyst in the amount of about 0.001 percent to about 1.0 percent by weight based on the organic phase.
Claim 6
Dependent Claim
26 words
The process of claim 3 wherein said dispersion includes a catalyst capable of increasing the rate of reaction of said organic polyisocyanates to form said polyurea.
Claim 7
Dependent Claim
27 words
The process of claim 5 wherein said catalyst is selected from the group consisting of a basic organic tertiary amine catalyst and an alkyl tin acetate catalyst.
Claim 8
Dependent Claim
26 words
The process of claim 1 wherein said dispersion includes a catalyst capable of increasing the rate of reaction of said organic polyisocyanates to form said polyurea.
Claim 9
Dependent Claim
27 words
The process of claim 7 wherein said catalyst is selected from the group consisting of a basic organic tertiary amine catalyst and an alkyl tin acetate catalyst.
Claim 10
Dependent Claim
68 words
The process of claim 1 wherein said water-immiscible phase contains a catalyst selected from the group consisting of (a) a basic organic tertiary amine catalyst in the amount of about 0.01 percent to about 10.0 percent by weight based on the organic phase and (b) an alkyl tin acetate catalyst in the amount of about 0.001 percent to about 1.0 percent by weight based on the organic phase.
Claim 11
Dependent Claim
25 words
Capsules capable of controlled release of encapsulated organic material comprising a thiocarbamate herbicide enclosed in a polyurea capsule produced by the process of claim 9.
Claim 12
Dependent Claim
25 words
Capsules capable of controlled release of encapsulated organic material comprising an organophosphorus insecticide enclosed in a polyurea capsule produced by the process of claim 9.
Claim 13
Dependent Claim
26 words
Capsules capable of controlled release of encapsulated organic material comprising an insect hormone mimic enclosed in a polyurea capsule produced by the process of claim 9.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-02-16 | 1990-08-18 | 1991-02-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-02-16 | 1994-08-18 | 1995-02-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-02-16 | 1998-08-18 | 1999-02-17 | $7700.00 | Window Closed / Lapsed |