US4640967A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Ultraviolet radiation-curable silicone release compositions with epoxy and/or acrylic functionality
Assignee: General Electric Co
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Filing: 1985-12-18
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Granted: 1987-02-03
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Expires: 2005-12-18
Abstract
Abstract Epoxy- and/or acrylic-functional polysiloxanes are disclosed which, when combined with onium salt photoinitiating catalysts or free-radical photoinitiating catalysts or both, form ultraviolet radiation-curable release coating compositions which render surfaces non-adherent to other surfaces which would normally adhere thereto. The compositions will cure to such an adhesive state upon brief exposure to ultraviolet radiation. Cure and substrate adhesion may be enhanced by the addition of epoxy monomers where onium salt photocatalysts are included. Preparation of the polymers, coating compositions, catalysts and catalyst blends are also disclosed.
Inventors
- 👤 Richard P. Eckberg
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 04:25
CPC Classifications
C; C08; C08L; C08L83/00; C08L83/04; C08L83/06; C08G; C08G77/00; C08G77/04; C08G77/38; C08G77/48; C08G77/50; C09; C09D; C09D183/00; C09D183/04; C09D183/06
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
63 words
An organopolysiloxane having both epoxy and acrylic functional units of the formula ##STR25## where R is hydrogen or C.sub.(1-3) alkyl and G is, independently, an epoxy-functional organic radical of from 2 to 20 carbon atoms, or an acrylic-functional organic radical of from 2 to 20 carbon atoms, with at least 1 polymer unit being epoxy-functional and at least 1 polymer unit being acrylic-functional.
Claim 2
Dependent Claim
63 words
An organopolysiloxane having both epoxy and acrylic functional units of the formula ##STR25## where R is hydrogen or C.sub.(1-3) alkyl and G is, independently, an epoxy-functional organic radical of from 2 to 20 carbon atoms, or an acrylic-functional organic radical of from 2 to 20 carbon atoms, with at least 1 polymer unit being epoxy-functional and at least 1 polymer unit being acrylic-functional.
Claim 3
Dependent Claim
27 words
A polysiloxane as defined in claim 1 wherein epoxy radicals represented by G are derived from compounds selected from the group consisting of limoneneoxide, 2,6-diemthyl-2,3-epoxy-7-octene and 1,4-dimethyl-4-vinylcyclohexeneoxide.
Claim 4
Dependent Claim
31 words
A polysiloxane as defined in claim 1 wherein the acrylic functionality is derived from hydroxy-functional acrylates selected from the group consisting of acrylic acid, methacrylic acid, 2-hydroxyethacrylate, 2-hydroxymethacrylate and pentaerythritol triacrylate.
Claim 5
Dependent Claim
25 words
A polysiloxane as defined in claim 1 having units of the formula: ##STR26## where E represents an epoxy-functional radical and A represents an acrylic-functional radical.
Claim 6
Dependent Claim
17 words
A polysiloxane as defined in claim 4 wherein the substituent E is ##STR27## and A is ##STR28##
Claim 7
Dependent Claim
64 words
An organopolysiloxane having epoxy and acrylic functionality prepared by (1) performing a hydrosilation addition of a hydrogen-functional polysiloxane and an epoxy olefin compound without reacting all of the hydrogen-silicon groups in said polysiloxane; (2) reacting the product of step (1) with an ω-halogen-containing olefin by hydrosilation addition; (3) reacting the product of step (2) with an hydroxy-functional acrylate compound in the presence of pyridine.
Claim 8
Dependent Claim
64 words
An organopolysiloxane having epoxy and acrylic functionality prepared by (1) performing a hydrosilation addition of a hydrogen-functional polysiloxane and an epoxy olefin compound without reacting all of the hydrogen-silicon groups in said polysiloxane; (2) reacting the product of step (1) with an ω-halogen-containing olefin by hydrosilation addition; (3) reacting the product of step (2) with an hydroxy-functional acrylate compound in the presence of pyridine.
Claim 9
Dependent Claim
26 words
A polysilocane as defined in claim 6 wherein the epoxy olefin is limoneneoxide, the ω-halogen-containing olefin is methallylchloride and the hydroxy-functional acrylate compound is acrylic acid.
Claim 10
Dependent Claim
100 words
A process for preparing an organopolysiloxane having epoxy and acrylic functionality comprising the steps: (1) reacting an epoxy olefin compound with a hydrogen-functional polysiloxane in the presence of a small amount of a precious metal catalyst for a period sufficient to react some but not all of the hydrogen-silicon groups; (2) recovering an epoxy-functional, hydrogen-functional polysiloxane product and reacting it with an ω-halogen-containing olefin in the presence of a precious metal catalyst; (3) recovering an epoxy-functional, halogenated polysiloxane and reacting it with a hydroxy-functional acrylate in the presence of pyridine; and (4) recovering a polysiloxane having epoxy and acrylic functionality.
Claim 11
Dependent Claim
100 words
A process for preparing an organopolysiloxane having epoxy and acrylic functionality comprising the steps: (1) reacting an epoxy olefin compound with a hydrogen-functional polysiloxane in the presence of a small amount of a precious metal catalyst for a period sufficient to react some but not all of the hydrogen-silicon groups; (2) recovering an epoxy-functional, hydrogen-functional polysiloxane product and reacting it with an ω-halogen-containing olefin in the presence of a precious metal catalyst; (3) recovering an epoxy-functional, halogenated polysiloxane and reacting it with a hydroxy-functional acrylate in the presence of pyridine; and (4) recovering a polysiloxane having epoxy and acrylic functionality.
Claim 12
Dependent Claim
25 words
A process as defined in claim 8 wherein the epoxy olefin compound is limoneneoxide, ω-halogen-containing olefin is methallylchloride and the hydroxy-functional acrylate is acrylic acid.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-02-02 | 1990-08-04 | 1991-02-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-02-02 | 1994-08-04 | 1995-02-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-02-02 | 1998-08-04 | 1999-02-03 | $7700.00 | Window Closed / Lapsed |