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US4543404A Expired / Lapsed US ⏱️ 0.0 years remaining

Primer composition

Assignee: Negami Chemical Industrial Co Ltd
•
Filing: 1984-08-27
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Granted: 1985-09-24
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Expires: 2004-08-27
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Abstract

Abstract There is disclosed a primer composition comprising [A] a reaction product of: (1) a hydroxyl group-containing organic compound composed of; (a) an epoxy group-containing alcohol represented by the general formula [I]: <IMAGE> [I] wherein, R1 is a hydrocarbon group having 1 to 15 carbon atoms, or an organic group in which the same or different hydrocarbon groups are bonded to each other by an ether bond or an ester bond; and each of m and n is a value of 1 or more; and (b) a hydroxyl group-containing (meth)acrylate represented by the formula [II]: (CH2=CR2COO)aR3 [II] wherein R2 is a hydrogen atom or a methyl group; R3 is a substituted or unsubstituted hydrocarbon group, or a group in which the same or different hydrocarbon groups are bonded to each other by ether bond or the ester bond, the R3 being a-valent and having at least one hydroxyl group; and a is an integer of 1 to 3; an amount of active hydrogen atoms included in the aforesaid (a) being 25 to 75% with respect to the total amount of active hydrogen atoms included in the aforesaid (1), and (2) a polyisocyanate including 70 to 100% of the theoretical amount of isocyanato groups which will react with the total amount of the active hydrogen atoms included in the aforesaid (1); [B] an amino group-containing alkoxysilane or its partially hydrolyzed condensate having 0.5 to 1.5 amino active hydrogen atoms per epoxy group included in the aforesaid (1)(a); and [C] a diluent.

Inventors

  • 👤 Shunji Sugano
  • 👤 Koichi Hagiwara
  • 👤 Isao Miura
  • 👤 Akira Honto

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 00:54
CPC Classifications
C; C09; C09J; C09J5/00; C09J5/02; B; B32; B32B; B32B17/00; B32B17/06; B32B17/10; B32B17/10005; B32B17/1055; B32B17/10688; B32B17/10733; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/58; C08G18/67; C08G18/671; C08G18/672; C08G18/83; C08G18/837; C09J2400/00; C09J2400/10; C09J2400/14; C09J2400/146

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 253 words
A primer composition characterized by comprising: [A] a reaction product of: (1) a hydroxyl group-containing organic compound composed of; (a) an epoxy group-containing alcohol represented by the general formula [I]: ##STR6## wherein, R 1 is a hydrocarbon group having 1 to 15 carbon atoms, or an organic group in which the same or different hydrocarbon groups are bonded to each other by an ether bond or an ester bond; and each of m and n is a value of 1 or more; and (b) a hydroxyl group-containing (meth)acrylate represented by the formula [II]: (CH.sub.2 ═CR.sup.2 COO).sub.a R.sup.3 [II] wherein R 2 is a hydrogen atom or a methyl group; R 3 is a substituted or unsubstituted hydrocarbon group, or a group in which the same or different hydrocarbon groups are bonded to each other by ether bond or the ester bond, the R 3 being a-valent and having at least one hydroxyl group; and a is an integer of 1 to 3; an amount of active hydrogen atoms included in the aforesaid (a) being 25 to 75% with respect to the total amount of active hydrogen atoms included in the aforesaid (1), and (2) a polyisocyanate including 70 to 100% of the theoretical amount of isocyanato groups which will react with the total amount of the active hydrogen atoms included in the aforesaid (1); [B]an amino group-containing alkoxysilane or its partially hydrolyzed condensate having 0.5 to 1.5 amino active hydrogen atoms per epoxy group included in the aforesaid (1)(a); and [C] a diluent.
Claim 2
Dependent Claim 253 words
A primer composition characterized by comprising: [A] a reaction product of: (1) a hydroxyl group-containing organic compound composed of; (a) an epoxy group-containing alcohol represented by the general formula [I]: ##STR6## wherein, R 1 is a hydrocarbon group having 1 to 15 carbon atoms, or an organic group in which the same or different hydrocarbon groups are bonded to each other by an ether bond or an ester bond; and each of m and n is a value of 1 or more; and (b) a hydroxyl group-containing (meth)acrylate represented by the formula [II]: (CH.sub.2 ═CR.sup.2 COO).sub.a R.sup.3 [II] wherein R 2 is a hydrogen atom or a methyl group; R 3 is a substituted or unsubstituted hydrocarbon group, or a group in which the same or different hydrocarbon groups are bonded to each other by ether bond or the ester bond, the R 3 being a-valent and having at least one hydroxyl group; and a is an integer of 1 to 3; an amount of active hydrogen atoms included in the aforesaid (a) being 25 to 75% with respect to the total amount of active hydrogen atoms included in the aforesaid (1), and (2) a polyisocyanate including 70 to 100% of the theoretical amount of isocyanato groups which will react with the total amount of the active hydrogen atoms included in the aforesaid (1); [B]an amino group-containing alkoxysilane or its partially hydrolyzed condensate having 0.5 to 1.5 amino active hydrogen atoms per epoxy group included in the aforesaid (1)(a); and [C] a diluent.
Claim 3
Dependent Claim 12 words
The primer composition according to claim 1, wherein said (2) is glycidol.
Claim 4
Dependent Claim 19 words
The primer composition according to claim 1, wherein the R 1 in said (a) is an aliphatic hydrocarbon group.
Claim 5
Dependent Claim 20 words
The primer composition according to claim 1, wherein said (b) is a (meth)acrylate having one hydroxyl group in its molecule.
Claim 6
Dependent Claim 15 words
The primer composition according to claim 1, wherein said [B] is an amino group-containing alkoxysilane.
Claim 7
Dependent Claim 12 words
The primer composition according to claim 5, wherein said [B] is N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane.
Claim 8
Dependent Claim 24 words
The primer composition according to claim 1, wherein said composition has a viscosity of 10,000 cP or less at a temperature of 25° C.
Claim 9
Dependent Claim 24 words
The primer composition according to claim 7, wherein said composition has a viscosity of 1,000 cP or less at a temperature of 25° C.

References Cited (Backward Citations)

US4478990A Cited
US4499150A Cited
US4499151A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-09-23 1989-03-25 1989-09-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-09-23 1993-03-25 1993-09-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-09-23 1997-03-25 1997-09-24 $7700.00 Window Closed / Lapsed

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